Ultralow-Temperature Magnetic Refrigeration Inorganic Materials: From Designed Synthesis to Adiabatic Demagnetization Refrigeration [0.03%]
超低温磁制冷无机材料：从设计合成到绝热去磁制冷
Qiao-Fei Xu,Ruo-Tong Wu,La-Sheng Long et al.
Qiao-Fei Xu et al.
ConspectusAdiabatic demagnetization refrigeration (ADR), which exploits the magnetocaloric effect (MCE), remains the only helium-free refrigeration technology capable of reaching temperatures below 1 K. With the rapid growth of quantum comp...
From Mono- N-Protected Amino Acids to Pyridones: A Decade of Evolution of Bifunctional Ligands for Pd(II)-Catalyzed C-H Activation [0.03%]
从单保护氨基酸到吡啶酮：Pd(II)催化下双功能配体十年发展历程
Yi-Hao Li,Yuxin Ouyang,Jie-Lun Yan et al.
Yi-Hao Li et al.
ConspectusFunctionalization of carbon-hydrogen (C-H) bonds has emerged as a powerful strategy in modern organic synthesis, offering efficient routes to build molecular complexity from simple and abundant substrates. Among various transition...
Recent Advances in Bioinspired Cu-Directed C-H Hydroxylation Reactions [0.03%]
近年来铜催化的生物启发型C-H羟基化反应研究进展
Sunipa Goswami,Isaac Garcia-Bosch
Sunipa Goswami
ConspectusCu-dependent metalloenzymes catalyze a wide array of oxidative transformations using O2 as an oxidant under mild conditions. These include the hydroxylation of challenging organic substrates (e.g., oxidation of methane to methanol...
Shaping Oxidation Catalysis of Multivalent Mixed Oxides by Dedicated Hydrogen Pretreatment [0.03%]
专用氢气预处理调节多元金属氧化物的氧化反应催化性能
Herbert Over
Herbert Over
ConspectusSupported metal nanoparticles used in heterogeneous catalysis can be prepared by using various methods, including deposition-precipitation and wet-chemical impregnation. The formed metal particles oxidize during the calcination st...
Designing Interactions between Molecular Catalysts and Light Absorbers for Fine-Tuned Performances and Electron-Transfer Mechanisms in CO2 Photoreduction [0.03%]
用于调节性能和电子转移机制的二氧化碳光还原分子催化剂与光吸收剂之间的相互作用设计
Jia-Wei Wang,Gangfeng Ouyang
Jia-Wei Wang
ConspectusThe conversion of CO2 into reduced carbon products by valorizing sunlight as the energy source is a highly attractive strategy to simultaneously mitigate CO2 emissions and generate renewable fuels. Metal complexes can serve as ver...
Plasmonic Scattering Interferometric Microscopy: Decoding the Dynamic Interfacial Chemistry of Single Nanoparticles [0.03%]
等离激元散射干涉显微镜：单个纳米颗粒动态界面化学的解码
Gang Wu,Jun-Hao Wan,Chen Qian et al.
Gang Wu et al.
ConspectusThe ability to detect and image nanomaterials at interfaces is crucial for a wide range of applications, from the engineering and characterization of nanocomposites to enabling label-free detection for biomedical diagnostics and t...
Overcoming the Hydration and Solvation Problem in Ion Recognition and Binding: The Biomimetic Approach [0.03%]
从仿生学角度克服离子识别和结合中的溶剂化和水合作用问题
Pavel Anzenbacher Jr,Anjusha Prakash,Sandra M George et al.
Pavel Anzenbacher Jr et al.
ConspectusArtificial receptors for cations and anions utilizing noncovalent binding, transport, sequestration, or sensing in aqueous media must address enthalpic factors such as electrostatic attraction, hydrogen bonding, van der Waals forc...
Divergent Synthesis of Kopsia and Structurally Related Monoterpenoid Indole Alkaloids: A Non-biomimetic Strategy [0.03%]
拟色酮烷型单萜吲哚生物碱发散式合成及其非仿生策略研究
Hui Wang,Zhiqiang Ma
Hui Wang
ConspectusMonoterpenoid indole alkaloids constitute one of the largest natural product families, with over 3000 members reported to date. Kopsia, a genus of about 30 species, is notable for its rich alkaloid diversity. These plants produce ...
From Molecules to Modules: Pathways toward Scalable Electrochemical CO2 Reduction [0.03%]
从分子到模块：电化学CO2还原的途径及规模化展望
Gong Zhang,Shuying Li,Xiaowei Du et al.
Gong Zhang et al.
ConspectusAchieving carbon neutrality requires the development of robust carbon capture, utilization, and storage (CCUS) technologies. Among the various carbon utilization pathways, the electrochemical carbon dioxide (CO2) reduction reactio...
Federico Calle-Vallejo
Federico Calle-Vallejo
ConspectusThe oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are key in numerous electrochemical technologies, such as water electrolyzers, CO2 electrolyzers, low-temperature fuel cells, regenerative fuel cells and some...