How to Achieve Hydrogenation/Hydrofunctionalization via Metal Hydride Complexes [0.03%]
金属氢化物配合物催化加氢/官能团化反应的研究进展与发展机遇
Ju Peng,Ruopeng Bai,Yu Lan
Ju Peng
ConspectusMetal hydride (M-H) complexes have garnered widespread attention in the synthesis of fine chemicals, materials, agrochemicals, and pharmaceuticals owing to the remarkable reactivity of the M-H bonds. Specifically, M-H complexes ar...
Weiqing Xu,Yu Wu,Wenling Gu et al.
Weiqing Xu et al.
ConspectusEngineering sensing interfaces with functional nanomaterials have aroused great interest in constructing novel analytical platforms. The good catalytic abilities and physicochemical properties allow functional nanomaterials to per...
D Antypov,A Vasylenko,C M Collins et al.
D Antypov et al.
ConspectusThis Account considers how the discovery of crystalline inorganic materials, defined as their experimental realization in the laboratory, can benefit from computation: computational predictions afford candidates for laboratory exp...
Synthesis through C(sp3)-C(sp2) Bond Scission in Alkenes and Ketones [0.03%]
通过烯烃和酮的C(sp3)-C(sp2)键断裂合成
Michal Šimek,Jeremy H Dworkin,Ohyun Kwon
Michal Šimek
ConspectusThe homolytic cleavage of C-C bonds adjacent to functional groups has recently become a popular strategy for restructuring the skeletons of complex organic molecules. In contrast to the traditional reactivity profiles of polar bon...
Arpan Choudhury,Debashree Ghosh
Arpan Choudhury
ConspectusMelanin, specifically eumelanin, is a brownish-black pigment abundant in nature. It is a heterogeneous biopolymer known most commonly for its spectacular photoprotection property in humans, animals, and plants. Numerous other prop...
Photon Management Through Energy Transfer in Halide Perovskite Nanocrystal-Dye Hybrids: Singlet vs Triplet Tuning [0.03%]
卤化物钙钛矿纳米晶-染料杂化材料中的光子管理：单重态与三重态调控下的能量转移研究
Jishnudas Chakkamalayath,Akshaya Chemmangat,Jeffrey T DuBose et al.
Jishnudas Chakkamalayath et al.
ConspectusPhotoinduced energy and electron transfer processes offer a convenient way to convert light energy into electrical or chemical energy. These processes remain the basis of operation of thin film solar cells, light emitting and opto...
Synthesis of Axially Chiral Compounds via Transition Metal-Catalyzed Atroposelective C-H Functionalization [0.03%]
手性金属催化轴手性C-H功能化反应合成轴向手性化合物
Gang Liao,Bing-Feng Shi
Gang Liao
ConspectusAxially chiral skeletons are prevalent in natural products and biologically important compounds, and they are widely utilized as privileged scaffolds in enantioselective catalysis. Consequently, the catalytic atroposelective synth...
Identifying Lanthanide Energy Levels in Semiconductor Nanoparticles Enables Tailored Multicolor Emission through Rational Dopant Combinations [0.03%]
识别半导体纳米粒子中的稀土能级并通过合理掺杂实现多色发射
Gouranga H Debnath,Prasun Mukherjee,David H Waldeck
Gouranga H Debnath
ConspectusThe unique photon emission signatures of trivalent lanthanide cations (Ln3+, where Ln = Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb) enables multicolor emission from semiconductor nanoparticles (NPs) either through doping m...
Jianwei Yang,Bo Wang,Xiao Feng
Jianwei Yang
ConspectusMass transport is fundamental to biological systems and industrial processes, governing chemical reactions, substance exchange, and energy conversion across various material scales. In biological systems, ion transport, such as pr...
Reem Al-Ahmad,Mingji Dai
Reem Al-Ahmad
ConspectusTotal synthesis has long been a proving ground for advancing chemical thought, pushing chemists to develop strategies that not only replicate nature's complexity but often surpass it. The pursuit of efficiency, practicality, and e...