Multicomponent Metallacages via the Integrative Self-Assembly of Pt(II) Nodes with Multiple Pyridyl and Carboxylate Ligands [0.03%]
基于含吡啶和羧酸配体的Pt(II)节点整合自组装构筑多组分金属笼
Yali Hou,Zeyuan Zhang,Mingming Zhang
Yali Hou
ConspectusIn recent years, multicomponent self-assembly has emerged as a pivotal strategy in supramolecular chemistry, enabling the construction of artificial systems with enhanced functionalities that surpass those of individual molecular ...
Zhe Zhao,Han Fu,Li Ling et al.
Zhe Zhao et al.
ConspectusThe challenge of optimizing decentralized water, wastewater, and reuse treatment systems calls for innovative, efficient technologies. One advancement involves surface-modified side-emitting optical fibers (SEOFs), which enhance b...
Organic Photocatalyst Utilizing Triplet Excited States for Highly Efficient Visible-Light-Driven Polymerizations [0.03%]
一种利用三重激发态的有机光催化剂用于高效可见光驱动聚合反应
Yonghwan Kwon,Woojin Jeon,Johannes Gierschner et al.
Yonghwan Kwon et al.
ConspectusUltraviolet (UV) light has traditionally been used to drive photochemical organic transformations, mainly due to the limited visible-light absorption of most organic molecules. However, the high energy associated with UV light oft...
Enantioselective Photocatalysis Using a Privileged Al-Salen Complex [0.03%]
一种优先的Al-萨伦配合物的手性光催化选择性合成
Julia Soika,Carina Onneken,Tobias Morack et al.
Julia Soika et al.
ConspectusEnantioselective catalysts that exhibit broad generality are disruptive innovators in contemporary synthesis and are considered to be "privileged" on account of their expansive reactivity/selectivity profiles. Operating in the gro...
Electrospray Ionization Mass Spectrometry Insights into the Assembly of Lanthanide-Containing Clusters [0.03%]
含镧系金属簇的组装过程中的电喷雾离子化质谱研究
Ming-Qiang Qi,Ming-Hao Du,Xiang-Jian Kong et al.
Ming-Qiang Qi et al.
ConspectusAtomically precise metal clusters with well-defined crystal structures have emerged as a rapidly growing field within coordination and materials chemistry. Among them, lanthanide-containing clusters (LCCs) are particularly notable...
Fluoroalkylacylsilanes as Novel Ambiphilic Donor-Acceptor Carbene Precursors [0.03%]
新型 ambiphilic donor-acceptor carbenes 前体：氟烷基酰基硅烷
Xiao Shen
Xiao Shen
ConspectusCarbenes, as highly reactive intermediates, have emerged as pivotal tools in organic synthesis, catalysis, and materials science due to their versatile reactivity and broad applicability. Among the diverse classes of carbenes, don...
Ze-Fan Yao,Jie-Yu Wang,Jian Pei
Ze-Fan Yao
ConspectusSolution-processable conjugated polymers are typically composed of two distinct structural components: rigid conjugated backbones and flexible side chains, each with unique roles and properties. The conjugated backbone forms the c...
Carbenoid Reactions Promoted by Solids: From Lewis to Brønsted Catalysts [0.03%]
固相促进的卡宾类反应：从路易斯到布朗斯特催化剂
Antonio Leyva-Pérez,Marta Mon,Yongkun Zheng
Antonio Leyva-Pérez
ConspectusDiazocarbonyl compounds have become essential tools in organic synthesis, due to their ability to in situ generate reactive carbenes and be inserted in a variety of otherwise stable bonds, such as C-H, C-C, H-O, and so on. However...
Let There Be Heat: Silica-Coated Gold Nanoparticles as Photothermal Reactors for Chemical Synthesis [0.03%]
金纳米粒子 silica 包衣：用于化学合成的光热反应器
Aritra Biswas,Nir Lemcoff,Yossi Weizmann
Aritra Biswas
ConspectusThe heating of matter upon interacting with light is a fundamental process ubiquitous in the natural world. With the rise of nanotechnology over the past decades, a variety of nanomaterials capable of converting light into heat ha...
Tuning 3-D Nanomaterial Architectures Using Atomic Layer Deposition to Direct Solution Synthesis [0.03%]
利用原子层沉积调控纳米材料三维结构以导向溶液合成
Alondra M Ortiz-Ortiz,Daniel O Delgado Cornejo,Ashley R Bielinski et al.
Alondra M Ortiz-Ortiz et al.
ConspectusThe ability to synthesize nanoarchitected materials with tunable geometries provides a means to control their functional properties, with applications in biological, environmental, and energy fields. To this end, various bottom-up...