Linear trinuclear and tetranuclear Ln(III) compounds aggregated by multidentate Schiff base ligands: insights into the magnetocaloric effect, slow magnetic relaxation behavior and catalytic CO2 conversion [0.03%]
通过多齿席夫碱配体聚集的Ln(III)三核和四核线性化合物：磁热效应、缓慢磁弛豫行为及催化CO2转化的见解
Xiao-Fen Guan,Na Qiao,Zhi-Lei Wu et al.
Xiao-Fen Guan et al.
Ln-derived complexes have been intensively studied owing to their broad application scope in many fields (like magnetism, light, electricity, catalytic and biological activity, etc.). In this work, two new linear Ln3 compounds 1 and 2 ([Ln3...
Post-synthetic modification approach for tandem functionalization of a 2D-layered Zn-coordination polymer: from exfoliated nanosheets to a 3D supramolecular structure with enhanced dye adsorption efficiency [0.03%]
二维层状Zn配位聚合物的 postsynthetic修饰法：从剥落的纳米片到具有增强染料吸附效率的三维超分子结构
Qasem Maleki,Valiollah Nobakht,Sepideh Samiee
Qasem Maleki
Post-synthetic modification (PSM) represents a promising approach for enhancing the properties of coordination polymers (CPs) and MOFs by introducing new functional groups and tailored surface chemistry. This study details a tandem PSM of a...
From antiferromagnetism to field-induced ferromagnetism: A Cu2+-governed metamagnetic landscape in RFeCuGe4O12 (R = Tm-Lu) [0.03%]
从反铁磁性到磁场诱导铁磁性：RFeCuGe4O12（R=Tm-Lu）中Cu2+调控的金属玻璃态景观
Diming Xu,Zhibo Liu,Xiao Li et al.
Diming Xu et al.
Metamagnetism represents a distinctive subclass within the antiferromagnetic (AFM) regime, exhibiting significant potential for diverse technological applications, particularly in magnetocaloric effects. In this paper, we systematically inv...
Structure, magnetism and thermal stability of the n = 3 Ruddlesden-Popper oxyfluoride La4Ni3O8.4F3.5 [0.03%]
La4Ni3O8.4F3.5 Ruddlesden-Popper 氧氟化物的结构、磁性和热稳定性
Jakob Geßner,Stefan G Ebbinghaus,Jonas Jacobs
Jakob Geßner
Oxides of the Ruddlesden-Popper (RP) series An+1BnO3n+1 are ideal candidates for the incorporation of additional anions like F-, H-, or N3- in the crystal lattice. The resulting mixed anionic compounds usually exhibit clearly different phys...
Charge compensation endows K0.16Na0.05(NH4)0.71V4O10- x·0.63H2O cathode with tunable lattice strain for efficient Zn2+ storage [0.03%]
钾钠铵复合补偿阴离子缺陷实现钒基正极材料晶格应变的动态可调用于高效锌离子存储
Xueke Zhu,Dong Fang,Lang Zhang et al.
Xueke Zhu et al.
The major challenges in using NH4V4O10 as a cathode for aqueous zinc-ion batteries (AZIBs) are its unsatisfactory structural stability and carrier migration coefficient due to the accumulated lattice strain during cycling. Herein, we develo...
Developing selective access to P(V)/(V) and a heteroatom-bridged P(III)P(V) 1,4-diphosphabarrelene(s) using a 1,4-diphosphinine [0.03%]
开发选择性获得P(III)/P(V)和杂原子桥连的P(III)P(V)1,4-二磷环丁烷的方法并使用1,4-二磷基萘inium盐对其进行修饰
Tim Kalisch,Rainer Streubel
Tim Kalisch
1,4-Diphosphabarrelene dioxides and disulfides have been directly synthesized from C-functional 1,4-diphosphabarrelenes. Additionally, a tricyclic 1,4-diphosphinine enabled access to both a P(V)/(V) derivative using cyclohexene sulfide and ...
Clicking [Mo(CO)3(triphos)] to an azide-terminated alkylthiol SAM: structural, spectroscopic and electrochemical investigations [0.03%]
[钼(CO)3(triphos)]点击到叠氮端辛烷硫醇自组装单分子膜的结构、谱学及电化学研究
Niels Michaelis,Tobias A Engesser,Jan Krahmer et al.
Niels Michaelis et al.
The synthesis and characterization of a new, linear triphos-type pincer ligand furnished with an ethynyl moiety in the ligand backbone (etPPPhTMSP) and the derived tricarbonyl complex [Mo(CO)3(etPPPhTMSP)] are described. Deprotection of the...
Analyzing the photophysics and photochemistry of [UO2(acetylacetonate)2(L)] complexes [0.03%]
[UO2(acetylacetonate)2(L)]复合物的光物理和光化学性质研究
Colin B Clark,Nora L Burnett,Alexander N Ruhren et al.
Colin B Clark et al.
Photocatalysis using the uranyl cation, UO22+, is underdeveloped. Under visible light illumination, uranyl photocatalysts generate potent excited state oxidants (>2.6 V vs. SHE), though the impact of the equatorial ligand environment on the...
Tuning the visible circularly polarized luminescence in highly emissive chiral terbium and europium chlorides [0.03%]
在高度发光的手性氯化铽和氯化铕中调节可见圆偏振光发光
Congcong Chen,Zhongshiqi Luo,Mengke Zhang et al.
Congcong Chen et al.
Chiral hybrid metal halides have become increasingly popular due to their high structural tunability and exceptional optoelectronic properties. Incorporating rare-earth (RE) metals into the structural units and inheriting their pure emissio...
Zhen Shao,Yin-Shan Meng,Yuan-Yuan Zhu et al.
Zhen Shao et al.
Spin-crossover (SCO) materials, as stimulus-responsive molecular switches, have garnered significant attention for applications in information storage, biomimetic sensing, and molecular devices due to their unique ability to couple magnetic...