Luminescent MOF-based sensors engineered for monitoring ROS and RNS: recent advances and perspective [0.03%]
用于监测ROS和RNS的发光MOF基传感器的设计原理：最近进展与展望
Subhrajyoti Ghosh,Soutick Nandi,Srijan Mukherjee et al.
Subhrajyoti Ghosh et al.
Oxidative metabolism generates various reactive oxygen species (ROS) and reactive nitrogen species (RNS), which play crucial roles in both physiological and pathological processes. At optimal levels, these species regulate essential functio...
Bipolaron hopping conduction in vacancy-ordered Cs2PtI6 perovskites [0.03%]
具有空位有序结构的Cs2PtI6钙钛矿中的双极子导电机制研究
Vidya Raj,Abhishek Anand,Manasa Manoj et al.
Vidya Raj et al.
Among vacancy-ordered perovskites, Cs2PtI6 exhibits remarkable efficiency and stability, making it a promising material for photovoltaic and photoelectrochemical applications. However, further advancements require a comprehensive understand...
Amplification of luminescence intensity by ytterbium(III) dopant in upconversion nanoparticles integrated with carbon dots for NIR-responsive targeted photodynamic therapy [0.03%]
一种掺杂ytterbium(III)以增强发光强度的近红外响应上转换碳点纳米颗粒及其在靶向光动力治疗中的应用
Bijay Saha,Antara Ghosh,Archana Singh et al.
Bijay Saha et al.
Photodynamic therapy (PDT) is one of the promising fields for cancer treatment, demonstrating precise and significant therapeutic outcomes. Despite their widespread use, conventional photosensitizers show significant limitations and subopti...
Water-stable Ni(II)-MOFs as ratiometric fluorescent probes for the detection of perfluorocarboxylic acids [0.03%]
水稳定的镍金属有机骨架比率荧光探针用于全氟羧酸的检测
Kai-Yang Zhang,Zhao-Feng Qiu,Fang-Fang Wang et al.
Kai-Yang Zhang et al.
Ratiometric fluorescent probes can be used as efficient and stable means of detection, but they usually require rare earth metals. Thus, it is necessary to develop proportional fluorescent probes with earth-abundant metals rather than rare ...
An in situ dual modification strategy for enhancing the electrocatalytic oxygen evolution performance of ZIF-67 [0.03%]
一种原位双修饰策略增强ZIF-67电催化析氧反应性能
Rajesha Kumar Swain,Aranya Kar,Aditi Halder et al.
Rajesha Kumar Swain et al.
Enhancing the electrocatalytic performance of metal-organic frameworks (MOFs) remains a key challenge in energy materials research. In this study, the cobalt-based zeolitic imidazolate framework ZIF-67 (Z67) was modified using an all-inorga...
Deciphering the mechanistic landscape of formic acid dehydrogenation with the heterobimetallic Ir(III)-Ni(II) catalyst [0.03%]
异金属Ir(III)-Ni(II)催化剂催化甲酸脱氢反应机理研究
Lan-Yu Li,Hui-Qi Mo,Pan Chen et al.
Lan-Yu Li et al.
Heterobimetallic catalysts have garnered significant attention due to their potential to achieve synergistic effects in catalytic transformations. However, the mechanistic complexity arising from the interactions between distinct metal cent...
Yulia S Gokhfeld,Natalia V Kazak,Anastasia S Tarasova et al.
Yulia S Gokhfeld et al.
A novel oxyborate, NiCr(BO3)O, is synthesized using a flux method. The material crystallizes in an orthorhombic warwickite structure, space group Pbnm(62), with lattice parameters a = 9.3438(13) Å, b = 9.0908(13) Å, and c = 3.0507(4) Å. ...
Short but promising - how nature modulates the antimicrobial activity of proline-rich fragment of salivary MUC-7 [0.03%]
简短但前景广阔——揭秘自然如何调节唾液黏蛋白MUC-7富含脯氨酸片段的抗菌活性
Jakub Gawłowski,Anna Ślusarczyk,Klaudia Szarszoń et al.
Jakub Gawłowski et al.
Antimicrobial peptides (AMPs), including mucin-derived sequences, play a vital role in host defense at mucosal surfaces by modulating microbial interactions and supporting innate immunity. However, their susceptibility to proteolytic cleava...
Dynamic processes of the first NHC-substituted rhenium heptahydrides [ReH7(NHC)2] [0.03%]
第一个NHC取代的七氢合铼化合物[NHC-ReH7]的动力学过程研究
G Grieco,A Pierini,M Pierini
G Grieco
In this paper are presented possible geometries and fluxional mechanisms of three [ReH7(NHC)2] complexes (NHC = IMes (1) (1,3-bis(2,4,6-trimethyl phenyl) imidazol-2-ylidene), IMesCl2 (2) (4,5-dichloro-1,3-dihydro-1,3-bis(2,4,6-trimethylphen...
Thio-iso-phthalamide pincer ligand-driven oxidative addition of a C-Br bond to gold(I): synthesis and studies of SCS-gold(III) pincer complexes [0.03%]
硫异酞胺钳形配体催化的金(i)对C-Br键的氧化加成反应：SCS-金(iii)钳形配合物的合成与研究
Saravanan Raju,Sanhati Sharangi,Harkesh B Singh et al.
Saravanan Raju et al.
The chelating effect of thio-iso-phthalamides was utilized to facilitate the oxidative addition of an aryl Csp2-Br bond into the SMe2Au(I)Cl salt, leading to the isolation of stable SCS·Au(III)X (X = Br and Cl) complexes. The subsequent di...