Comparison of catalytic activities of aluminum complexes with sulfur and oxygen containing ligands for the ring-opening polymerization of ε-caprolactone [0.03%]
硫和氧含氮配体修饰的铝配合物开环聚合ε-己内酯催化性能研究
Tzu-Yu Lin,Yu-Chi Liou,Taoufik Ben Halima et al.
Tzu-Yu Lin et al.
A series of aluminum complexes bearing various ligands, including tert-butanolate, tert-butyl thiolate, 2,6-dimethylphenolate, 2,6-dimethylbenzenethiolate, 2,6-di-tert-butyl-4-methylphenolate, 2,6-di-trimethylsilylbenzenethiolate, furan-2-y...
Recent advances in polyoxometalate-based catalysts for light-driven valorization of biomass derivatives [0.03%]
基于多金属氧酸盐的光驱动生物质衍生物高值化催化剂研究进展
Zheng Li,Xiaoyi Liu,Mengyun Zhao et al.
Zheng Li et al.
Photocatalytic organic transformation has been emerging as a promising approach for achieving value-added conversion of biomass derivatives due to its environmentally benign nature and high efficiency. Polyoxometalates (POMs), a class of at...
Modulation of the electronic structure of NiS2/NiS via Fe and Mn dual-doping to boost the oxygen evolution reaction [0.03%]
通过Fe和Mn共掺杂调控NiS2/NiS的电子结构以提升其析氧反应性能
Lu Wang,Shuo Wang,Bin Luo
Lu Wang
Doping in transition metal sulfides can effectively induce lattice distortion and introduce asymmetry, thereby lowering the energy required to overcome the rate-controlling step in the oxygen evolution reaction (OER). This work presents a s...
Robust copper-based cationic metal-organic frameworks for efficient sequestration of perrhenate/pertechnetate [0.03%]
一种高效的高效Capture和回收封存氯酸盐/氯酸盐的铜基阳离子金属有机骨架材料
Wenchang Wang,Lei Li,Meiyu Zhang et al.
Wenchang Wang et al.
Recent studies have extensively reported the use of cationic metal-organic frameworks (MOFs) for capturing perrhenate/pertechnetate (ReO4-/99TcO4-) from waste water. Despite the high sorption efficiency of some materials, their stability in...
Justyna Łosiewicz,Milan Kumar Bisai,Gary S Nichol et al.
Justyna Łosiewicz et al.
C-H zincation is an efficient route to useful organozinc compounds. To date, most approaches effect aryl C-H zincation with selectivity controlled by substrate pKa. Herein, we report a heteroaryl C-H zincation method that uses an easy to ac...
Homochiral Dy2Zn2 zero-field single-molecule magnets derived from (R)/(S)-2-methoxy-2-phenylacetic acids [0.03%]
以(R)/(S)-2-甲氧基-2-苯乙酸为原料的Dy2Zn2手性单分子磁体
Cai-Ming Liu,Xiang Hao,Yi-Quan Zhang
Cai-Ming Liu
Despite the unique advantages of multifunctional integration at the nanoscale, chiral zero-field single-molecule magnets (SMMs), especially those based on homochiral carboxylic acids, are still difficult to obtain. Herein, homochiral (R)/(S...
Theoretical study of the mechanisms of activation/deactivation of luminescence in a UiO-66 type sensor modified with Ln3+ (Eu and Tb) as dopant ions [0.03%]
UiO-66型传感器掺入Ln3+(Eu和Tb)离子后发光激活/去活化机理的理论研究
Yoslainy Echevarria-Valdés,Yoan Hidalgo-Rosa,Eduardo Schott et al.
Yoslainy Echevarria-Valdés et al.
The luminescence properties of MOF-based materials have been improved by incorporating lanthanide ions (Ln3+) via post-synthetic modifications (PSM). In this report, a quantum chemical theoretical protocol was carried out to elucidate the d...
Synthesis and characterisation of MoIV-oxo dithiolenes: formate dehydrogenase active site mimetics [0.03%]
钼IV-氧化物二硫烯的合成与表征：甲酸脱氢酶活性位点模拟物
Isaac J Furney,Joseph A Wright
Isaac J Furney
The active sites of metalloenzymes continue to inspire synthetic chemists to create structural models of the intricate structures seen in biology. As well as the fundamental intellectual challenge, this is driven by the potential societal i...
Advances in nano-drug delivery systems for metallic compounds in cancer therapy: challenges and future perspectives [0.03%]
用于癌症治疗的金属化合物纳米给药系统进展：挑战与未来前景
Subin Joseph,Rinku Chakrabarty,Priyankar Paira
Subin Joseph
Metallic compounds have shown great promise as anticancer treatments because of their varied mechanisms of action, decreased side effects, and ability to overcome drug resistance. The search for alternative metal-based therapies has been dr...
Lantern-like Cu8 cluster for high-efficiency electrically driven light-emitting diodes [0.03%]
灯笼状Cu8簇用于高效率电致发光二极管中
Yan-Yan Lin,Jian Luo,Bo-Wen Dai et al.
Yan-Yan Lin et al.
A novel lantern-like Cu(I) cluster [Cu8(2-pyCC)6(N-triphosPh)2](PF6)2 (Cu8) was synthesized with high yield via ligand engineering, featuring mixed multidentate ligands of tris(diphenylphosphinomethyl)amine (N-triphosPh) and 2-pyridylethy...