Dihalogen-substituted [MnIII(3,5-diHal-sal2323)]BPh4 salts: so similar but so different [0.03%]
二卤素取代的[MnIII(3,5-二卤素-水杨酰胺)2]BPh4盐：如此相似，却又如此不同
D V Korchagin,G V Shilov,M V Zhidkov et al.
D V Korchagin et al.
Three novel tetraphenylborate salts of Mn(III) complexes with the Schiff base ligands 3,5-diHal-sal2323 are synthesized and structurally and magnetically characterized: [Mn(3,5-Br,F-sal2323)]BPh4 (1), [Mn(3,5-diI-sal2323)]BPh4 (2) and [Mn(3...
Fixing CO2 from the air to assemble Dy8 zero-field single-molecule magnets and Gd8 magnetocaloric molecular materials [0.03%]
从空气中固定CO2构筑Dy8零场单分子磁体和Gd8磁致冷分子材料
Cai-Ming Liu,Xiang Hao
Cai-Ming Liu
Assembling Ln(III) clusters by capturing and fixing CO2 from the air is a unique and eco-friendly approach to yielding multinuclear single-molecule magnets and magnetocaloric molecular materials. However, the conditions or factors required ...
Deciphering cation-driven structure-property correlations in 0D hybrid ruthenium halide perovskites [0.03%]
解密阳离子调控的零维有机无机混合卤化钌钙钛矿结构-性质关联规律
Himangshu Pratim Saikia,Ankita Likson,Khyati Anand et al.
Himangshu Pratim Saikia et al.
Hybrid organic-inorganic halides have emerged as a structurally tunable class of materials that allow simultaneous modulation of optical properties and magnetic interactions. By varying the A-site cation with organic amines of different car...
Combining gold(I/III) complexes and the ferrociphenol scaffold for the generation of bimetallic complexes with anticancer activity [0.03%]
结合金(I/III)配合物和铁氰菲 Scaffold 生成具有抗癌活性的双金属配合物
Magda Křelinová,Jérémy Forté,Tom Lacoma et al.
Magda Křelinová et al.
A series of eleven heterobimetallic Au/Fe complexes featuring [Au(I)-thioglucose tetraacetate], [Au(I)-NHC], [(C^N)Au(III)Cl], [(C^N^C)Au(III)] or [(C^C)Au(III)Cl] fragments and (diphenylphosphino)ferrociphenol or (diphenylphosphino)ferroce...
Water-soluble silver nanoparticles stabilized by amino acid-derived N-heterocyclic carbenes: synthesis, properties and theoretical study of the nucleation process [0.03%]
由氨基酸衍生物N-杂环卡宾稳定水溶性银纳米粒子：合成、性质及成核过程的理论研究
Carlos J Carrasco,Regla Ayala,Sara Garrido et al.
Carlos J Carrasco et al.
Silver nanoparticles stabilized by amino acid-derived N-heterocyclic carbenes, denoted as Ag(NHCR)-NPs (R = H, 3a; Me, 3b; iPr, 3c; and iBu, 3d), were synthesized by reducing the parent complexes Na3[Ag(NHCR)2] (2a-d) with NaBH4 under appro...
Developing Ni3N/NiO heterostructure catalysts to enhance the hydrogen evolution reaction in an alkaline medium via a surface-dependent mechanism [0.03%]
通过表面依赖机制开发Ni3N/NiO异质结构催化剂以在碱性介质中增强氢气演化反应
Fangfang Liu,Shan Ji,Yongwei Li et al.
Fangfang Liu et al.
In the construction of sustainable energy systems, the development of efficient and stable electrocatalysts for the hydrogen evolution reaction (HER) is of crucial significance. This study adopts an in situ oxidation-nitridation strategy to...
Magnetically recoverable swellable magnetite/SOMS hybrid nanocomposites for rapid adsorption of organic dyes from water [0.03%]
磁性可回收的磁铁矿/超分子聚合物纳米复合材料快速吸附水中的有机染料
Lorenzo Maccarino,Ibtissame Sidane,Gianni Barucca et al.
Lorenzo Maccarino et al.
Hybrid magnetic adsorbents based on magnetite nanoparticles and Swellable Organically Modified Silica (Mag-SOMS) are reported for the first time to address the limited recoverability of powdered adsorbents from aqueous media. The materials ...
Tailoring in-gap states for optimizing the band gap in mixed-valent bromometallates, towards lead-free photovoltaics [0.03%]
通过调整能隙态来优化混价溴金属卤化合物的禁带宽度，以实现无铅光伏材料性能的提升
Tatiana A Shestimerova,Angelina P Klykova,Alexey V Medved&#x;ko et al.
Tatiana A Shestimerova et al.
Motivated by the task to replace toxic lead halide perovskites with lead-free environmentally benign light-harvesting materials for photovoltaics, we have synthesized two new hybrid bromometallates, (AH2)4[Sb2Br10(SbBr6)2(Br)2] (1) and (AH2...
Aswin Chandran,Simon Edin,Mattias Tan et al.
Aswin Chandran et al.
The viability of a main-group triple bond depends critically on the strength of its π-manifold. Among the 15 possible diatomic homo- and interpnictogens, EE', (E, E' = group 15 element), the NN linkage of dinitrogen stands out as one o...
Single-site hydrogen-bond modulation enhances catalytic ester hydrolysis in a Zn(II)-TPA scaffold [0.03%]
单位点氢键调节增强锌-TPA框架催化酯水解性能
Han Sol Kim,Soo Suk Lee
Han Sol Kim
Zinc(II)-dependent metalloenzymes rely heavily on secondary-sphere interactions to modulate reactivity, inspiring the design of biomimetic Zn(II) catalysts that incorporate analogous features. Here, we introduce a hydroxymethyl-functionaliz...