Investigations of Co(II) to Co(III) oxidation mechanisms at Fe3- δO4 nanoparticle surfaces [0.03%]
研究Fe3-δO4纳米颗粒表面的Co(II)至Co(III)氧化机理
Laura Fablet,Mathieu Pédrot,Fadi Choueikani et al.
Laura Fablet et al.
Understanding and predicting the interaction mechanisms between Co and spinel iron oxides (Fe3-δO4), including magnetite, maghemite and their solid solutions, is of major interest in both the environmental and industrial contexts. While th...
Electrodeposited polyoxometalate-Cu2+1O hybrid on copper foam: synergistic electron transfer for efficient nitrate electroreduction to ammonia [0.03%]
泡沫铜上电沉积的聚氧杂环金属酸-二价铜杂化物：协同电子转移高效还原硝酸根离子制氨
Kaiqun Bai,Xinming Wang,Gang Li et al.
Kaiqun Bai et al.
Electrocatalytic nitrate reduction (NO3RR) is a sustainable strategy to address nitrate pollution and replace the energy-intensive Haber-Bosch process for ammonia synthesis, but it is hindered by complex multi-electron transfer pathways and...
Phenoxido-bridged open-cubane [Cu4(μ3-OH)2] and stepped-cubane [Cu4(μ3-OMe)2] complexes from a semicarbazone Schiff base: synthesis, anion-coordination-tunable structures, biomimicking functions, DNA binding, magnetic behavior and theoretical support [0.03%]
基于半карбазон希夫碱的开放式立方烷[Cu4(μ3-OH)2]和阶梯状立方烷[Cu4(μ3-OMe)2]配合物：合成、结构调节、模拟酶功能、DNA结合行为以及理论计算研究
Anupama Manna,Mohammad Fawad Ansari,Farukh Arjmand et al.
Anupama Manna et al.
The bridging nature of in situ solvent-generated hydroxido (HO-) and methoxido (MeO-) groups has been utilized to obtain tetranuclear open-cubane and stepped-cubane [Cu4] complexes: [Cu4(L)2(H2O)2(μ3-OH)2](ClO4)4·3H2O (1) and [Cu4(L)2(μ-...
Temperature-driven phase transformations and microstructure evolution in the thermoelectric colusite Cu26V2Sn6S32. An in situ synchrotron diffraction study [0.03%]
基于同步辐射的Cu₂₆V₂Sn₆S₃₂温差电材料的原位结构演变和相变研究
F Guiot,G Guélou,C Dejoie et al.
F Guiot et al.
Understanding the structural stability and thermal behavior of thermoelectric materials is crucial for optimizing their long-term performance under operating conditions. In this work, we present an in situ high-resolution synchrotron X-ray ...
Infection microenvironment-responsive composites based on a Ag(I) complex for targeted antimicrobial treatment [0.03%]
一种基于Ag(I)配合物的感染微环境响应复合材料用于靶向抗菌治疗
Jing Han,Yue Hou,Zhong Yu et al.
Jing Han et al.
To address always-on Ag+ release of Ag(I) complexes for antimicrobial treatment, infection microenvironment-responsive composites with high antimicrobial efficiency and on-demand Ag+ release were constructed by coating hyaluronic acid (HA) ...
Novel bismuth-selone molecular precursor based selective synthesis of Bi2Se3 nanoplates and nanosheets: a promising electrocatalyst for hydrogen evolution in a neutral medium [0.03%]
一种新型含硒分子配合物的铋前驱体的选择性合成Bi2Se3纳米片及纳米薄片：中性介质中析氢反应的电催化剂
Atharva Yeshwant Kulkarni,Dwaipayan Majumder,Sandeep Nigam et al.
Atharva Yeshwant Kulkarni et al.
Designing molecular precursors for the controlled synthesis of functional nanomaterials holds immense promise for advancing sustainable energy technologies. Herein, we report the synthesis and structural characterization of an air-stable bi...
Remediation of thiophenes from liquid fuel via ultrasound-assisted oxidative desulfurization using a magnetic MgFe2O4@CQD nanocatalyst [0.03%]
超声辅助磁性MgFe₂O₄@CQD纳米催化剂氧化脱硫研究
Rogayeh Tutunfrush,Seyed Ali Hosseini,Aligholi Niaei et al.
Rogayeh Tutunfrush et al.
Magnetic MgFe2O4@CQD was developed as a novel nanocatalyst for ultrasound-assisted oxidative desulfurization (UAOD) of thiophenes from fuel. The nanocatalyst was synthesized using an oxidative co-precipitation method and characterized. XRD ...
Inter-ligand cross-links determine secondary building unit formation in oligoMOFs [0.03%]
配体间的交联决定寡聚MOF的二级构建单元的形成
Debobroto Sensharma,Victor B de Sousa,Seth M Cohen
Debobroto Sensharma
OligoMOFs are a class of metal-organic frameworks (MOFs) that feature ligands covalently cross-linked into oligomers as intrinsic structural components. A recent study has demonstrated that the size and flexibility of the tether moieties ca...
Flexible steric bulk of sugar wingtip substituents on bis(N-heterocyclic carbene) ligands of diplatinum complexes via chair-twist-boat conformational changes [0.03%]
二铂配合物中通过椅式扭船式构象变化的糖翼取代基的柔性立体位阻研究
Shuhei Nomura,Itsuki Kobayashi,Matsumi Doe et al.
Shuhei Nomura et al.
In the p-toluenethiolate-bridged diplatinum complex bearing ethylene-bridged bis(N-heterocyclic carbene) ligands, all four acetyl-protected glucopyranosyl wingtip substituents adopt the chair conformation, giving rise to an open structure a...
Tailoring porphyrinic MOF-545 performances for CO2 photocatalytic reduction through linker chlorination [0.03%]
通过连接体氯化调节MOF-545性能用于CO2光催化还原反应
Amanda Lyn Robinson,Sadiya Sadiya,Sandeep Kumar et al.
Amanda Lyn Robinson et al.
The development of technologies for CO2 sequestration and its conversion into value-added chemicals has received considerable and growing attention. However, achieving high conversion efficiency and product selectivity under mild conditions...