Cytotoxic effect of ruthenium-arene complexes containing tetrazolo[1,5- a] quinoline derivatives on cervical (HeLa), lung (A549), and colon (HCT116) cancer cell lines [0.03%]
含四氮唑基喹啉衍生物的钌芳烃复合物对宫颈(hepg2)、肺(a549)和结肠(hct116)癌细胞系的细胞毒性作用
S Navitha,A S W Wilfred Raj,S Sree Brindha et al.
S Navitha et al.
On a global scale, cancer ranks as the second most common disease. Lung cancer continues to be a leading cause of cancer-related deaths in men, while cervical cancer remains the fourth most prevalent cancer among women worldwide. In the des...
The behavior of potassium follows that of calcium in heterobimetallic 'K-H-Al' hydrides on a picolyl-derived chemically non-innocent triaza ligand [0.03%]
钾的行为遵循异二金属“K-H-Al”氢化物上源自ピ考基的化学非良态三氮杂配体的钙行为
Chhotan Mandal,Abhishek Kundu,Sourav Panda et al.
Chhotan Mandal et al.
Heterobimetallic hydrides pairing s- and p-block metals on a single ligand are rare, but likely to be promising for synergistic chemistry. We report a series of K-H-Al heterobimetallic hydrides on a chemically non-innocent picolyl-based eth...
Long-term stability and antibacterial efficiency of Cu-Zn co-doped cobalt ferrite-based composites [0.03%]
长期稳定的铜锌共掺钴铁磁体复合材料的抗菌效率
S Kalia,P K Prabhakar,V Dhiman et al.
S Kalia et al.
A series of copper-zinc co-doped cobalt ferrite nanoparticles (CF-NPs) were prepared successfully using the sol-gel auto-combustion method. The XRD results revealed the formation of cubic crystals. FTIR studies suggested that doping and co-...
Synthesis, structures and catalytic properties of two organic-inorganic hybrid polyoxometalates built from {Ni6PW9} units [0.03%]
由{Ni6PW9}构建的两种有机-无机杂化聚氧钛酸的合成、结构和催化性能研究
Shuang Gao,Zhen-Wen Wang,Guo-Yu Yang
Shuang Gao
Two new Ni6-added organic-inorganic hybrid polyoxometalates, {[Ni(en)2][Ni6(μ3-OH)3(H2O)3(Hen)(en)3(3,5-DDB)(B-α-PW9O34)][Ni6(μ3-OH)3(H2O)2(en)3(Ac)(3,5-DDB)(B-α-PW9O34)]}·8H2O (1, en = ethylenediamine, 3,5-DDB = 3,5-dihydroxybenzoic a...
Synthesis, crystal growth, and optical and magnetic properties of three bimetallic thiocyanates TBi(SCN)5 (T = Mn, Cd) and FeBi(SCN)6 [0.03%]
三种双金属硫氰酸盐TBi(SCN)₅(T=Mn,Cd)和FeBi(SCN)₆的合成、晶体生长及其光学磁学性能研究
David Rich,Khusbu Rai,Dinesh Upreti et al.
David Rich et al.
In this work, we report the synthesis, crystal growth, and optical and magnetic properties of two new isotypic bimetallic thiocyanates, MnBi(SCN)5 and CdBi(SCN)5. The crystal structure of MnBi(SCN)5 and CdBi(SCN)5 was determined by single-c...
Stratified sulfatometallates: unlocking a new dimension in sulfatomolybdates [0.03%]
分层硫代金属酸盐：在硫代钼酸盐中开启一个新的维度
Vivien Wessels,Jasper Arne Baldauf,Rainer Pöttgen et al.
Vivien Wessels et al.
Thus far, only a few sulfatomolybdates are known. Their anions feature mainly low dimensionalities. By choosing appropriate reaction conditions, new compounds, namely, β-K2[MoO2(SO4)2] and Na2[MoO2(SO4)2], are synthesised, which revealed l...
Quantum chemical insights into reactivity trends of half-sandwich Os(II), Ru(II), Ir(III) and Rh(III) complexes: hydrolysis, cysteine binding, and NADH oxidation from DFT analysis [0.03%]
基于DFT计算的半夹层锇(II)、钌(II)、铱(III)和Rh(III)配合物反应活性趋势的量子化学见解：水解、半胱氨酸结合及NADH氧化
Wanrong Song,Hui Li,Na Xu et al.
Wanrong Song et al.
Half-sandwich transition-metal complexes of Ru(II), Os(II), Ir(III) and Rh(III) represent versatile scaffolds in inorganic and bioinorganic chemistry due to their tunable coordination environments and potential as redox-active anticancer ag...
NIR-responsive upconversion nanoplatforms: an anionic drug carrier for ROS amplification induced by β-amyloid fibrils [0.03%]
近红外响应上转换纳米平台：一种用于β淀粉样蛋白纤维诱导的ROS放大的阴离子药物载体
Xiaofeng Jia,Yijia Guan,Weijie Cao et al.
Xiaofeng Jia et al.
Alzheimer's disease (AD), marked by the misfolding/aggregation of β-amyloid (Aβ), is a major global health challenge. Polyoxometalates (POMs), as anionic therapeutic agents, exhibit potential in depolymerizing Aβ fibrils, inhibiting Aβ ...
Stability vs. activity in electrocatalytic hydrogen production and magnetic studies of mononuclear labile Cu(II) and Ni(II) complexes [0.03%]
电催化制氢中的稳定性和活性以及单核易位Cu(II)和Ni(II)配合物的磁学研究
Maria A Bhatti,Luca M Carrella,Carsten Streb et al.
Maria A Bhatti et al.
In this study, two new mononuclear Schiff base salen-derived complexes, [CuII(H2LMe)]·1.5H2O (C1) and [NiII(H2LMe)]·3H2O (C2), were prepared from 2,6-bis(hydroxymethyl)-4-methylphenol H4L and characterised by single crystal X-ray diffract...
Rational design and applications of artificial metalloenzymes based on neuroglobin [0.03%]
基于神经球蛋白的人工金属酶的理性设计与应用研究
Li-Juan Sun,Ying-Wu Lin
Li-Juan Sun
The rational design of artificial metalloenzymes enables the expansion of the functionalities of natural metalloenzymes, which has become a research hotspot in biocatalysis. As a member of the globin family, neuroglobin (Ngb) has a stable s...