Ru and Rh binding sites in the structure of human serum transferrin with Fe3+ bound at the C-lobe [0.03%]
人血清转铁蛋白C-lobe结合Fe3+后的Ru和Rh结合位点的结构研究
Anne-Sophie Banneville,Giarita Ferraro,Rossella DElia et al.
Anne-Sophie Banneville et al.
Ru and Rh binding sites in the structure of human serum transferrin with Fe3+ bound at the C-lobe were identified by X-ray crystallography. Several His side chains and one Met are involved in the recognition of the metal ions by the protein...
Cyclam-based Cu(II) and Fe(III) complexes for antifouling coating development [0.03%]
基于环己二胺四乙酸的铜(ii)和铁(iii)配合物的防污涂层研究
Inês M Nunes,Bruno J C Vieira,João C Waerenborgh et al.
Inês M Nunes et al.
Biofouling, the accumulation of microorganisms and macroorganisms on submerged surfaces, is responsible for equipment degradation and increased maintenance costs. Several efforts have been made for the development of efficient antifouling s...
Uranium tetrafluoride via direct conversion of uranium dioxide using silver bifluoride in an ionic liquid medium [0.03%]
以银氟化物为介质的二氧化铀一步法直接制取四氟化铀
Parveen Kumar Verma,Frederic Poineau,Jason Victor et al.
Parveen Kumar Verma et al.
Conventional methods to prepare crystalline uranium tetrafluoride (UF4) involve the fluorination of uranium fluoride (UO2) with corrosive chemicals (i.e., HF(g)) at elevated temperatures. Here, a novel method for producing UF4 in a room tem...
Structural features and antibacterial activity of Ni(II) thiosemicarbazones in a zirconium metal-organic framework composite [0.03%]
含镍(II)半碳酰二肼配位化合物的锆基金属有机骨架复合材料的结构及抗菌性能研究
Edward Loukopoulos,David Fabra,Jorge Melones-Herrero et al.
Edward Loukopoulos et al.
Metal-Organic Frameworks for Biological Applications (BioMOFs) are materials that incorporate therapeutically active ligands into the framework that offer an alternative strategy which combines the structural advantages of MOFs with enhance...
A bismuth-based metal-organic framework with potential application in organic pollutant removal [0.03%]
一种具有有机污染物去除潜在应用的含铋金属有机框架材料
Ai Yang,Hong Cao,Jie Lyu et al.
Ai Yang et al.
Metal-organic frameworks (MOFs) with structural diversity and functional versatility have shown great potential in many fields. In this work, we proposed the utilization of the good biocompatibility and photoactivity of bismuth to construct...
Comparative solution study of imidazole-derived thiosemicarbazone complexes: effects of methylation and aromatic conjugation on the redox properties, anticancer, and antibacterial activity [0.03%]
咪唑衍生物半碳二亚胺类螯合物的比较研究:甲基化和芳香共轭对氧化还原性质、抗肿瘤及抗菌活性的影响
Tatsiana V Petrasheuskaya,Márton A Kiss,Peter Rapta et al.
Tatsiana V Petrasheuskaya et al.
A series of imidazole-based thiosemicarbazones (TSCs) was developed, and their metal complexation behavior was comprehensively investigated in solution. In addition, the structures of four ligands and four corresponding complexes were deter...
Halide exchange in (ClEA)2PbI4 and its effect on the structural and electronic properties of perovskite layers [0.03%]
(ClEA)₂PbI₄中的卤素交换及其对钙钛矿层结构和电子特性的影响
Linfei Yang,Xiaoyan Gan,Gang Zhao et al.
Linfei Yang et al.
Two-dimensional organic-inorganic hybrid perovskites exhibit significant application potential in the field of optoelectronic devices owing to their excellent optoelectronic properties and structural tunability. This study for the first tim...
In medio stat virtus: asymmetric Salphen metal complexes with improved biological properties [0.03%]
兼收并蓄:具有更好的生物性能的不对称Salphen金属配合物
Luisa DAnna,Aurane Froux,Riccardo Bonsignore et al.
Luisa DAnna et al.
We have synthesized and characterized three Zn(II) Salphen complexes with different ligand modifications to evaluate their biological properties in terms of DNA binding, cellular uptake and anticancer activity. Particular attention was give...
A low-spin manganese(II) complex with an emissive charge-transfer excited state [0.03%]
一种具有发光电荷转移激发态的低自旋锰(II)配合物
Maxwell C Rhames,Nora L Burnett,Annemarie A Lee et al.
Maxwell C Rhames et al.
Manganese is an attractive earth-abundant metal for chromophores because it has multiple oxidation states, making it well-suited for photochemical applications involving electron transfer reactivity. Unfortunately, the tendency of manganese...
Lucas G Foglia,Ryan M Kirk,Anthony F Hill
Lucas G Foglia
The first phosphaniminocarbyne complexes [W(CNPPh3)(CO)2(Tp*)] (Tp* = tris(dimethylpyrazolyl)borate) and trans-[W(CNPPh3)Br(CO)4] arise from the reactions of the fluorocarbyne [W(CF)(CO)2(Tp*)] with Me3SiNPPh3 and of Na[W(CN)(CO...