Multitopic 3,2':6',3''-terpyridine ligands as 4-connecting nodes in two-dimensional 4,4-networks [0.03%]
多重主题3,2′:6′,3″-三联吡啶配体作为二维4,4拓扑网络中的4连接节点
Giacomo Manfroni,Bernhard Spingler,Alessandro Prescimone et al.
Giacomo Manfroni et al.
The tetratopic 1,4-bis(2-phenylethoxy)-2,5-bis(3,2':6',3''-terpyridin-4'-yl)benzene (1) and 1,4-bis(3-phenylpropoxy)-2,5-bis(3,2':6',3''-terpyridin-4'-yl)benzene (2) ligands have been prepared and fully characterised. Combination of ligand ...
Synthesis and characterization of homogeneous (U,Am)O2 and (U,Pu,Am)O2 nanopowders [0.03%]
均相(U,Am)O2和(U,Pu,Am)O2纳米粉体的制备及表征
Jean-François Vigier,Daniel Freis,Olaf Walter et al.
Jean-François Vigier et al.
This paper details the first dedicated production of homogeneous nanocrystalline particles of mixed actinide oxide solid solutions containing americium. The target compositions were U0.75Pu0.20Am0.05O2, U0.90Am0.10O2 and U0.80Am0.20O2. Afte...
Correction: A 3-dimensional {42·84} lvt net built from a ditopic bis(3,2':6',3''-terpyridine) tecton bearing long alkyl tails [0.03%]
纠错：由带有长烷基尾的双三齿配体柱芳烃构筑块构建的{42·84} lvt网络三维结构补充说明
Y Maximilian Klein,Edwin C Constable,Catherine E Housecroft et al.
Y Maximilian Klein et al.
[This corrects the article DOI: 10.1039/C4CE02347A.]. This journal is © The Royal Society of Chemistry.
Published Erratum
CrystEngComm. 2022 Jul 7;24(28):5170. DOI:10.1039/d2ce90094g 2022
Self-flux-grown Ba4Fe4ClO9.5- x crystals exhibiting structures with tunable modulation [0.03%]
具有可调调节结构的自通式Ba4Fe4ClO9.5- x晶体的生长
Alla Arakcheeva,Wen Hua Bi,Priya Ranjan Baral et al.
Alla Arakcheeva et al.
The synthesis and X-ray structural study of the new family of compounds Ba4Fe4ClO9.5-x with tunable structural modulation are reported. The framework of the structure has the Ba2Fe4O9.5-x composition, with open hexagonal channels extending ...
In situ Bragg coherent X-ray diffraction imaging of corrosion in a Co-Fe alloy microcrystal [0.03%]
Co-Fe合金微晶腐蚀的原位Bragg相干X射线衍射成像研究
David Yang,Nicholas W Phillips,Kay Song et al.
David Yang et al.
Corrosion is a major concern for many industries, as corrosive environments can induce structural and morphological changes that lead to material dissolution and accelerate material failure. The progression of corrosion depends on nanoscale...
Bernette M Oosterlaken,Mark M J van Rijt,Heiner Friedrich et al.
Bernette M Oosterlaken et al.
The mineralization of collagen in vitro has been extensively investigated for hydroxyapatite, silica, calcium carbonate and lepidocrocite (γ-FeOOH). Henceforth, it is interesting to investigate whether collagen also could serve as a generi...
Stars and stripes: hexatopic tris(3,2':6',3''-terpyridine) ligands that unexpectedly form one-dimensional coordination polymers [0.03%]
带条纹的星形体：意外形成一维配位聚合物的六顶点三（3,2 ': 6'，3″-联吡啶）配体
Giacomo Manfroni,Alessandro Prescimone,Edwin C Constable et al.
Giacomo Manfroni et al.
The hexatopic ligands 1,3,5-tris(4,2':6',4''-terpyridin-4'-yl)benzene (1), 1,3,5-tris(3,2':6',3''-terpyridin-4'-yl)benzene (2), 1,3,5-tris{4-(4,2':6',4''-terpyridin-4'-yl)phenyl}benzene (3), 1,3,5-tris{4-(3,2':6',3''-terpyridin-4'-yl)phenyl...
Cubic, hexagonal and tetragonal FeGe x phases (x = 1, 1.5, 2): Raman spectroscopy and magnetic properties [0.03%]
立方、六方和四方FeGe x阶段(x=1,1.5,2)：拉曼光谱和磁性
A Kúkoľová,M Dimitrievska,A P Litvinchuk et al.
A Kúkoľová et al.
There is currently an emerging drive towards computational materials design and fabrication of predicted novel materials. One of the keys to developing appropriate fabrication methods is determination of the composition and phase. Here we e...
How the in situ monitoring of bulk crystalline phases during catalyst activation results in a better understanding of heterogeneous catalysis [0.03%]
对催化剂活化过程中大规模结晶相的原位监测有助于更好地理解多相催化过程
Simon Penner
Simon Penner
The present Highlight article shows the importance of the in situ monitoring of bulk crystalline compounds for a more thorough understanding of heterogeneous catalysts at the intersection of catalysis, materials science, crystallography and...
Lucy K Saunders,Anuradha R Pallipurath,Matthias J Gutmann et al.
Lucy K Saunders et al.
In this work we use high-resolution synchrotron X-ray diffraction for electron density mapping, in conjunction with ab initio modelling, to study short O-H⋯O and O+-H⋯O- hydrogen bonds whose behaviour is known to be tuneable by temperatur...