Growth of large crystals of Janus phase RhSeCl using self-selecting vapour growth [0.03%]
利用自我选择气相生长法生长Janus相RhSeCl大单晶
Anastasiia Lukovkina,Maria A Herz,Xiaohanwen Lin et al.
Anastasiia Lukovkina et al.
In recent years, interest in 2D Janus materials has grown exponentially, particularly with regard to their applications in spintronics and optoelectronic devices. The defining feature of Janus materials is the ordered arrangement of differe...
Patrick C Hillesheim,Arsalan Mirjafari
Patrick C Hillesheim
Crystallography provides a powerful framework for identifying, characterizing, and designing new ionic liquids (ILs) with targeted thermal and structural properties. While the design of imidazolium-based ILs has historically relied on empir...
Review
CrystEngComm. 2025 Dec 3. DOI:10.1039/d5ce00872g 2025
Joseph C Bear,Jeremy K Cockcroft,Alexander Rosu-Finsen et al.
Joseph C Bear et al.
Crystal structure prediction for systems governed by weak non-covalent interactions remain a significant challenge due to the complex energy landscapes involved. Herein, we have experimentally investigated the impact of systematic halogen s...
Hydrogen-bonded salt cocrystals of xenon difluoride and protonated perfluoroamides [0.03%]
氟化氙与质子化全氟酰胺的氢键盐共晶化合物
Erik Uran,Matic Lozinšek
Erik Uran
The hydrogen-bonding ability of XeF2 is an important factor influencing its chemical properties and reactivity, yet structurally characterised examples of hydrogen-bonded xenon fluorides remain rare. In this work, three salt cocrystals cont...
Crystal engineering of nickel(ii) coordination networks sustained by aliphatic dicarboxylate linker ligands [0.03%]
由脂肪族二羧酸配体连接的镍(II)配位网络的晶体工程学研究
Bharti Singh,Tao He,Michael J Zaworotko
Bharti Singh
Aliphatic dicarboxylate linker ligands are relatively understudied in the field of coordination networks (CNs) compared to their aromatic counterparts. Herein, we report the synthesis and characterisation of three nickel(ii) CNs comprised o...
Link between graphene features and the resulting functionality of quasi-van der Waals Zn3P2 [0.03%]
石墨烯结构特征与准范德华Zn3P2特性之间的关联关系研究
Thomas Hagger,Helena Rabelo Freitas,Chiara Mastropasqua et al.
Thomas Hagger et al.
Zn3P2, made from earth-abundant elements, is a promising candidate for thin-film solar cells but faces limitations due to difficulties in achieving n-type doping and its large lattice mismatch with commercial substrates and a high thermal e...
Versatility of the methyl-bipyrimidine- N-oxide ligand for the design of lanthanide single-molecule magnets [0.03%]
甲基-双嘧啶-N-氧化物配体在镧系单分子磁体设计中的多功能性
Haiet Douib,Bertrand Lefeuvre,Jessica Flores Gonzalez et al.
Haiet Douib et al.
A library of ten complexes, [Yb2(hfac)6(L)] (1), [Yb6(hfac)14(OH)4(L)2] (2), [Dy(hfac)3(L)]2·C2H4Cl2 ((3)·C2H4Cl2), [Dy(hfac)3(L)]2[Dy(hfac)3(H2O)2] (4), [Dy6(hfac)14(OH)4(L)2] (5), [Yb(tta)3(L)] (6) and [Ln2(hfc)6(L)] (Ln = Dy ((-)7, (+)...
Water vapour sorption properties of a family of square lattice topology porous coordination networks [0.03%]
一类平方格子拓扑结构多孔配位网络的水蒸气吸附性能研究
Samuel M Shabangu,Alan C Eaby,Lilia Croitor et al.
Samuel M Shabangu et al.
Porous coordination networks (PCNs) such as metal-organic frameworks are of topical interest thanks to their potential utility as sorbents for gas and vapour separations and/or storage. Interpenetrated PCNs, some of which offer promise for ...
Structural tuning of tetrazole-BODIPY Ag(i) coordination compounds via co-ligand addition and counterion variation [0.03%]
通过共配体添加和反离子变化调节四氮唑-BODIPY银(i)配合物的结构
Matthias Schöbinger,Martin Huber,Berthold Stöger et al.
Matthias Schöbinger et al.
The coordination properties of a previously described fluorescence active ligand (L), consisting of a coordinating unit (1H-tetrazol-1-yl) and a fluorophore (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) derivative) towards Ag(i) were...
Dries Vandenabeele,Anjul Rais,Christine Kirschhock et al.
Dries Vandenabeele et al.
Discovery of their commercial potential gave rise to a massive implementation of zeolites in industrial (petro-)chemical processes. Their robustness and molecular scale porosity in combination with acidic and/or ion exchange properties make...