Structural tuning of tetrazole-BODIPY Ag(i) coordination compounds via co-ligand addition and counterion variation [0.03%]
通过共配体添加和反离子变化调节四氮唑-BODIPY银(i)配合物的结构
Matthias Schöbinger,Martin Huber,Berthold Stöger et al.
Matthias Schöbinger et al.
The coordination properties of a previously described fluorescence active ligand (L), consisting of a coordinating unit (1H-tetrazol-1-yl) and a fluorophore (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) derivative) towards Ag(i) were...
Dries Vandenabeele,Anjul Rais,Christine Kirschhock et al.
Dries Vandenabeele et al.
Discovery of their commercial potential gave rise to a massive implementation of zeolites in industrial (petro-)chemical processes. Their robustness and molecular scale porosity in combination with acidic and/or ion exchange properties make...
Joseph C Bear,Alexander Rosu-Finsen,Jeremy K Cockcroft
Joseph C Bear
This study investigates the crystal structure and phase behaviour of two organofluorine aromatic compounds, para-dichlorotetrafluorobenzene (p-C6F4Cl2) and chloropentafluorobenzene (C6F5Cl), with a focus on solid-state phase transitions and...
Hopping intermittent contact-scanning electrochemical microscopy (HIC-SECM) as a new local dissolution kinetic probe: application to salicylic acid dissolution in aqueous solution [0.03%]
一种新的局域溶解动力学探针 hopping 间歇式接触扫描电化学显微镜(HIC-SECM)：水溶液中水杨酸的局部溶解研究
Amelia R Perry,Robert A Lazenby,Maria Adobes-Vidal et al.
Amelia R Perry et al.
Dissolution kinetics of the (110) face of salicylic acid in aqueous solution is determined by hopping intermittent contact-scanning electrochemical microscopy (HIC-SECM) using a 2.5 μm diameter platinum ultramicroelectrode (UME). The metho...
An unusual ionic cocrystal of ponatinib hydrochloride: characterization by single-crystal X-ray diffraction and ultra-high field NMR spectroscopy [0.03%]
一种 Ponatinib盐酸盐的离子型共晶：通过单晶X-射线衍射和超高压核磁共振光谱表征
Alexander J Stirk,Sean T Holmes,Fabio E S Souza et al.
Alexander J Stirk et al.
This study describes the discovery of a unique ionic cocrystal of the active pharmaceutical ingredient (API) ponatinib hydrochloride (pon·HCl), and characterization using single-crystal X-ray diffraction (SCXRD) and solid-state NMR (SSNMR)...
Polymorphism and orientation control of copper-dicarboxylate metal-organic framework thin films through vapour- and liquid-phase growth [0.03%]
通过气相和液相生长控制铜二羧酸盐金属有机框架薄膜的多态性和取向
Víctor Rubio-Giménez,Francesco Carraro,Sebastian Hofer et al.
Víctor Rubio-Giménez et al.
Precise control over the crystalline phase and crystallographic orientation within thin films of metal-organic frameworks (MOFs) is highly desirable. Here, we report a comparison of the liquid- and vapour-phase film deposition of two copper...
Torsional flexibility in zinc-benzenedicarboxylate metal-organic frameworks [0.03%]
锌-苯二羧酸金属有机框架中的扭转变形性
Emily G Meekel,Thomas C Nicholas,Ben Slater et al.
Emily G Meekel et al.
We explore the role and nature of torsional flexibility of carboxylate-benzene links in the structural chemistry of metal-organic frameworks (MOFs) based on Zn and benzenedicarboxlyate (bdc) linkers. A particular motivation is to understand...
Computation meets experiment: identification of highly efficient fibrillating peptides [0.03%]
计算与实验的结合：高效聚集体形成的多肽序列设计与筛选
Lorenzo Sori,Andrea Pizzi,Greta Bergamaschi et al.
Lorenzo Sori et al.
Self-assembling peptides are of huge interest for biological, medical and nanotechnological applications. The enormous chemical variety that is available from the 20 amino acids offers potentially unlimited peptide sequences, but it is curr...
Supramolecular isomerism and structural flexibility in coordination networks sustained by cadmium rod building blocks [0.03%]
基于镉杆构建模块的配位网络的超分子异构体和结构灵活性
Yassin H Andaloussi,Andrey A Bezrukov,Debobroto Sensharma et al.
Yassin H Andaloussi et al.
Bifunctional N-donor carboxylate linkers generally afford dia and sql topology coordination networks of general formula ML2 that are based upon the MN2(CO2)2 molecular building block (MBB). Herein, we report on a new N-donor carboxylate lin...
Evaluating Solvothermal and Mechanochemical Routes towards the Metal-Organic Framework Mg2(m-dobdc) [0.03%]
评估溶热和机械化学方法制备金属有机框架材料Mg₂(m-DOBDC)的路线
Elena Y Chen,Ruth M Mandel,Phillip J Milner
Elena Y Chen
Metal-organic frameworks bearing coordinatively unsaturated Mg(II) sites are promising materials for gas storage, chemical separations, and drug delivery due to their low molecular weights and lack of toxicity. However, there remains a limi...