Understanding the complexity in bridging thermal and electrocatalytic methanation of CO2 [0.03%]
理解CO2热催化和电催甲烷化的复杂性关系
Hui Kang,Jun Ma,Siglinda Perathoner et al.
Hui Kang et al.
The selective methanation of CO2 is an important research area to meet the net-zero emission targets. Furthermore, it is crucial to develop solutions to achieve carbon neutrality, hydrogen utilization, carbon circularity, and chemical-energ...
(P,C)-cyclometalated complexes derived from naphthyl phosphines: versatile and powerful tools in organometallic chemistry [0.03%]
萘基膦的(P,C)型环金属配合物：有机金属化学中多功能且强大的工具
Julien Monot,Enrico Marelli,Blanca Martin-Vaca et al.
Julien Monot et al.
The chemistry of (P,C)-cyclometalated complexes derived from naphthyl phosphines [Np(P,C)M] is presented and analysed in this review. The three main synthetic approaches, namely P-chelation assisted C-H activation, oxidative addition and tr...
CO2-responsive gels [0.03%]
响应二氧化碳的凝胶
Ross D Jansen-van Vuuren,Sina Naficy,Maedeh Ramezani et al.
Ross D Jansen-van Vuuren et al.
CO2-responsive materials undergo a change in chemical or physical properties in response to the introduction or removal of CO2. The use of CO2 as a stimulus is advantageous as it is abundant, benign, inexpensive, and it does not accumulate ...
Glenn K K Clothier,Thiago R Guimarães,Steven W Thompson et al.
Glenn K K Clothier et al.
A multiblock copolymer is a polymer of a specific structure that consists of multiple covalently linked segments, each comprising a different monomer type. The control of the monomer sequence has often been described as the "holy grail" of ...
Raman spectroscopy, an ideal tool for studying the physical properties and applications of metal-organic frameworks (MOFs) [0.03%]
拉曼光谱在金属有机框架（MOF）物理性质及其应用研究中的理想工具属性
Janaky Sunil,Chandrabhas Narayana,Gayatri Kumari et al.
Janaky Sunil et al.
Metal-organic frameworks (MOFs) are a unique family of materials constructed by coordinating metal ions or clusters to bridging organic ligands. Many of these materials are well known for their intricate structures, and exceptional gas adso...
Xiaozhou Ma,Jelco Albertsma,Dieke Gabriels et al.
Xiaozhou Ma et al.
Large amounts of carbon monoxide are produced by industrial processes such as biomass gasification and steel manufacturing. The CO present in vent streams is often burnt, this produces a large amount of CO2, e.g., oxidation of CO from metal...
Xiao-Ni Han,Ying Han,Chuan-Feng Chen
Xiao-Ni Han
Macrocyclic arenes including calixarenes, resorcinarenes, cyclotriveratrylene, pillararenes and so on have emerged as highly attractive synthetic macrocyclic hosts due to their unique structures, facile functionalization, and broad range of...
Engineering strategies and active site identification of MXene-based catalysts for electrochemical conversion reactions [0.03%]
用于电化学转化反应的MXenes基催化剂的工程策略和活性位点识别
Yufei Zhao,Jinqiang Zhang,Xin Guo et al.
Yufei Zhao et al.
MXenes have been extensively studied due to their high metallic conductivity, hydrophilic properties, tunable layer structure and attractive surface chemistry, making them highly desirable for energy-related applications. However, slow cata...
Di-Chang Zhong,Yun-Nan Gong,Chao Zhang et al.
Di-Chang Zhong et al.
Catalysts featuring dinuclear metal sites are regarded as superior systems compared with their counterparts with mononuclear metal sites. The dinuclear metal sites in catalysts with appropriate spatial separations and geometric configuratio...
Wegood M Awad,Daniel W Davies,Daichi Kitagawa et al.
Wegood M Awad et al.
In the last century, molecular crystals functioned predominantly as a means for determining the molecular structures via X-ray diffraction, albeit as the century came to a close the response of molecular crystals to electric, magnetic, and ...