Plant-derived chelators and ionophores as potential therapeutics for metabolic diseases [0.03%]
植物衍生螯合剂和离子载体作为代谢性疾病潜在治疗药物的潜力
Vanessa J Lee,Samuel E Janisse,Marie C Heffern
Vanessa J Lee
Transition metal dysregulation is associated with a host of pathologies, many of which are therapeutically targeted using chelators and ionophores. Chelators and ionophores are used as therapeutic metal-binding compounds which impart biolog...
Recent progress in the development of fluorescent probes for imaging pathological oxidative stress [0.03%]
病理氧化应激荧光成像探针研究进展
Yujie Geng,Zhuo Wang,Jiaying Zhou et al.
Yujie Geng et al.
Oxidative stress is closely related to the physiopathology of numerous diseases. Reactive oxygen species (ROS), reactive nitrogen species (RNS), and reactive sulfur species (RSS) are direct participants and important biomarkers of oxidative...
Tiefan Huang,Zhixin Su,Kun Hou et al.
Tiefan Huang et al.
Membranes have been extensively studied and applied in various fields owing to their high energy efficiency and small environmental impact. Further conferring membranes with stimuli responsiveness can allow them to dynamically tune their po...
Dafei Yuan,Wuyue Liu,Xiaozhang Zhu
Dafei Yuan
Chemical doping of organic semiconductors (OSCs) enables feasible tuning of carrier concentration, charge mobility, and energy levels, which is critical for the applications of OSCs in organic electronic devices. However, in comparison with...
Divalent metallocenes of the lanthanides - a guideline to properties and reactivity [0.03%]
配位聚合催化剂杂环卡宾
Sebastian Schäfer,Sebastian Kaufmann,Esther S Rösch et al.
Sebastian Schäfer et al.
Since the discovery in the early 1980s, the soluble divalent metallocenes of lanthanides have become a steadily growing field in organometallic chemistry. The predominant part of the investigation has been performed with samarium, europium,...
Fluorinated carbohydrates for 18F-positron emission tomography (PET) [0.03%]
用于氟-18正电子发射断层扫描(PET)的含氟碳水化合物
Emma Campbell,Christina Jordan,Ryan Gilmour
Emma Campbell
Carbohydrate diversity is foundational in the molecular literacy that regulates cellular function and communication. Consequently, delineating and leveraging this structure-function interplay continues to be a core research objective in the...
Probing the binding and activation of small molecules by gas-phase transition metal clusters via IR spectroscopy [0.03%]
红外光谱研究小分子在气相过渡金属团簇中的吸附和活化
André Fielicke
André Fielicke
Isolated transition metal clusters have been established as useful models for extended metal surfaces or deposited metal particles, to improve the understanding of their surface chemistry and of catalytic reactions. For this objective, an i...
Lyndon A Hall,Deanna M D&#x;Alessandro,Girish Lakhwani
Lyndon A Hall
Recently, there has been significant interest in the use of chiral metal-organic frameworks (MOFs) and coordination polymers (CPs) for photonics applications. The promise of these materials lies in the ability to tune their properties throu...
Understanding the complexity in bridging thermal and electrocatalytic methanation of CO2 [0.03%]
理解CO2热催化和电催甲烷化的复杂性关系
Hui Kang,Jun Ma,Siglinda Perathoner et al.
Hui Kang et al.
The selective methanation of CO2 is an important research area to meet the net-zero emission targets. Furthermore, it is crucial to develop solutions to achieve carbon neutrality, hydrogen utilization, carbon circularity, and chemical-energ...
(P,C)-cyclometalated complexes derived from naphthyl phosphines: versatile and powerful tools in organometallic chemistry [0.03%]
萘基膦的(P,C)型环金属配合物：有机金属化学中多功能且强大的工具
Julien Monot,Enrico Marelli,Blanca Martin-Vaca et al.
Julien Monot et al.
The chemistry of (P,C)-cyclometalated complexes derived from naphthyl phosphines [Np(P,C)M] is presented and analysed in this review. The three main synthetic approaches, namely P-chelation assisted C-H activation, oxidative addition and tr...