Recent advances in catalytic asymmetric metalloid-hydrogen bond insertion of transition-metal carbenes [0.03%]
过渡金属卡宾在催化的非对称金属氢键插入的研究新进展
Shuyue Zhang,Ming-Hua Xu
Shuyue Zhang
Over recent decades, transition-metal-catalyzed asymmetric carbene insertion into metalloid-hydrogen bonds (B-H/Si-H/Ge-H) has become a prominent research area. This review summarizes recent enantioselective strategies for constructing chir...
Kai Schwennicke,Arghadip Koner,Juan B Pérez-Sánchez et al.
Kai Schwennicke et al.
This review outlines several linear optical effects featured by molecular polaritons arising in the collective strong light-matter coupling regime. Under weak laser irradiation and when the single-molecule light-matter coupling can be negle...
Tzu-Sen Su,Anurag Krishna,Chenxu Zhao et al.
Tzu-Sen Su et al.
This review explores the emerging field of supramolecular engineering in hybrid organic-inorganic perovskite optoelectronics. The incorporation of supramolecular agents has shown transformative effects on the crystallization, morphology, st...
Intracellular aggregation of exogenous molecules for biomedical applications [0.03%]
用于生物医学应用的细胞内外来分子聚集效应
Da-Yong Hou,Haoran Wang,Yue-Ze Wang et al.
Da-Yong Hou et al.
Most biomolecules play important roles in aggregated states, as exemplified by proteins and DNA. Inspired by biomacromolecule formation, the exploration of intracellular bioactive materials derived from exogenous molecules has drawn conside...
Computational insights on the role of structure-directing agents (SDAs) in the synthesis of zeolites [0.03%]
结构导向剂(SDAS)在分子筛合成中的作用的计算分析
Xiaomin Tang,Omer F Altundal,Frits Daeyaert et al.
Xiaomin Tang et al.
Most of the zeolites synthesised in the last 3 or 4 decades employ organic structure-directing agents (OSDAs) in their synthesis. The synthesis or test of new OSDAs is a major driving force in order to achieve the goal of synthesising a new...
Correction: DNA-mediated precise regulation of SERS hotspots for biosensing and bioimaging [0.03%]
DNA介导的SERS热点精准调控用于生物传感和生物影像技术中的错误更正
Jingjing Zhang,Chunyuan Song,Xiyu He et al.
Jingjing Zhang et al.
Correction for 'DNA-mediated precise regulation of SERS hotspots for biosensing and bioimaging' by Jingjing Zhang et al., Chem. Soc. Rev., 2025, https://doi.org/10.1039/d5cs00124b.
Published Erratum
Chemical Society reviews. 2025 Jun 2. DOI:10.1039/d5cs90048d 2025
Nitrogen-centered radicals driving unusual enzyme reactions in biosynthetic pathways [0.03%]
生物合成途径中氮为中心的自由基驱动异常酶反应
Richiro Ushimaru,Ikuro Abe
Richiro Ushimaru
Nitrogen-centered radicals have emerged as versatile intermediates in natural product biosynthesis, playing pivotal roles in complex bond-forming and rearrangement reactions-including fragmentations, cyclizations, and dimerizations. These t...
Chemical engineering of zeolites: alleviating transport limitations through hierarchical design and shaping [0.03%]
介孔调控和成型工程助力分子筛材料传质性能提升
Nibras Hijazi,Anastasiya Bavykina,Irina Yarulina et al.
Nibras Hijazi et al.
Zeolites are indispensable catalysts in a wide range of industrial applications due to their well-defined microporous structures and exceptional shape-selective properties. However, their practical use is often constrained by diffusion limi...
Cuproptosis: mechanisms and nanotherapeutic strategies in cancer and beyond [0.03%]
铜死亡：癌症及其他疾病的机制和纳米治疗策略
Lijie Mao,Ji Lu,Xinyu Wen et al.
Lijie Mao et al.
Cuproptosis, a novel form of copper (Cu)-dependent programmed cell death, is induced by directly binding Cu species to lipoylated components of the tricarboxylic acid (TCA) cycle. Since its discovery in 2022, cuproptosis has been closely li...
Synthesis of lactones and lactams via C(sp3)-H bond functionalization [0.03%]
通过C(sp3)氢键官能团化合成内酯和内酰胺
Egambaram Premkumar,Ramdas Sreedharan,Premananda Ghosh et al.
Egambaram Premkumar et al.
The field of directing group-assisted, transition-metal-catalyzed functionalization has undergone a significant transformation, evolving from the use of auxiliary group attachment for the exploitation of native functional groups in novel or...