Molecular Extraction and Release of an Ionic Liquid Microdroplet With Dynamic Tunability Under Optical Trapping [0.03%]
光学操控下带微液滴离子液体的分子提取与释放研究
Kosuke Nakatsu,Rai Kobayashi,Moe Akazawa et al.
Kosuke Nakatsu et al.
Ionic liquids (ILs) exhibiting temperature-responsive phase separation offer promising opportunities for microscale extraction when combined with optical tweezers. Here, we induce local phase separation to generate a single IL-rich microdro...
Dual Functional Potential of Poly(ADP-Ribose) Polymerase Inhibitor VIII: A Promising G-Quadruplex Stabilizer Targeting the Promoter of Oncogenes [0.03%]
聚(腺苷二磷酸核糖)聚合酶抑制剂VIII的双重功能潜力：一种有望稳定致癌基因启动子G-四链体的稳定剂
Asim Bisoi,Prashant Chandra Singh
Asim Bisoi
Poly(ADP-ribose) polymerases (PARPs) have emerged as pivotal therapeutic targets due to their essential function in DNA single-strand break repair, particularly in cancers with BRCA1/2 mutations. Although PARP inhibitors show promising clin...
The Nature of One-Electron σ-Bonds Probed by X-Ray Quantum Crystallography [0.03%]
X射线量子晶体学探测的一电子σ键的本质
Ashi Singh,Amit Kumar Pradhan,Sajesh P Thomas
Ashi Singh
Two-center one-electron (2c-1e) σ bond is a unique class of bonding that departs from the century-old shared electron-pair model of covalent bonds. To resolve their bonding features, it is essential to capture the subtle features of electr...
Anthracene-Based Bipolar Emitter for High-Performance Deep-Blue Organic Light-Emitting Diodes [0.03%]
用于高性能深蓝色有机电致发光二极管的苊烯基 bipolar 发射体
Meng Zhao,Tongbo Wang,Lin Fu et al.
Meng Zhao et al.
Developing high-efficiency deep-blue emitters with exceptional color purity remains a critical challenge for organic light-emitting diodes (OLEDs). In this work, we report the strategic design and synthesis of a novel fluorescent emitter, C...
Interplay of Hybridization and Magnetization in Structural Stability of 3d Transition-Metal-Doped Ag13 and Au13 Clusters [0.03%]
3d过渡金属掺杂的Ag13和Au13簇中杂化与磁化对结构稳定性的相互作用关系研究
Prosanta Sarkar,Soumendu Datta,Tanusri Saha-Dasgupta
Prosanta Sarkar
Using the first-principles density functional theory, we perform a systematic investigation of preference between compact and open structures in 3d transition-metal-doped Ag 13 and Au13 clusters, considering two extreme geometrical structur...
An Implementation of General Polarization-Resolved Two-Dimensional Electronic Spectroscopy [0.03%]
二维电子光谱一般偏振分辨实现
Hoang Long Nguyen,Nelson Kim Soon Ong,Sanjib Jana et al.
Hoang Long Nguyen et al.
Two-dimensional electronic spectroscopy (2DES) is a powerful tool to study the dynamics of complex molecular systems. Polarization control in 2DES allows enhancement of selective signals, providing information about the transition dipole or...
Carbon-Supported NiZnO Nanoparticles for Electrochemical Reduction of CO2 to Hydrocarbons [0.03%]
碳支撑的NiZnO纳米粒子用于电催化CO2还原制备烃类燃料
Matt L J Peerlings,Floris S J van Seters,Nienke L Visser et al.
Matt L J Peerlings et al.
A compelling approach to close the carbon cycle is electrochemical CO2 reduction. Recently, it was demonstrated that polarized Ni catalysts can form value-added hydrocarbon products like ethylene in this reaction. However, the competing hyd...
DNA-Binding Properties of Iridium(III) Complexes Encompassing Design, Function and Biophysical Assessments [0.03%]
基于设计、功能和生物物理评估的含铱(III)配合物的DNA结合性质研究
Ibrahim S Alkhaibari,Niklaas J Buurma,Simon J A Pope
Ibrahim S Alkhaibari
The increasingly diverse biological applications of iridium(III) complexes, from luminescent cellular imaging agents to therapeutic and prospective theranostics, has been enabled by a combination of imaginative ligand design and tunable (ph...
Real-Time Monitoring of Excited-State Ring-Puckering Process in BODIPY Molecule Using Ultrafast Spectroscopy [0.03%]
利用超快光谱技术实时监测BODIPY分子激发态环皱缩过程
Ayentika Sen,Aruna K Mora,Sukhendu Nath
Ayentika Sen
Pyrromethene 597 (PM597), a widely utilized commercial laser dye, is known to exhibit a comparatively lower fluorescence quantum yield than its structural analogs such as PM546 and PM560. To elucidate the underlying mechanism for this lower...
Cooperation of Intermolecular Forces in Model Peptide-Poloxamer Fragment Binding [0.03%]
模型肽-聚氧乙烯嵌段聚合物片段结合的分子间作用力的合作关系研究
Upendra Adhikari,Leann Saura,Steve Scheiner
Upendra Adhikari
A quantum chemical study of the interactions between N-methylacetamide (NMA), which serves as a peptide model, and poloxamer building blocks made up of polyethylene oxide (PEO) and polypropylene oxide (PPO) dimers shows a range of noncovale...