Infrared Photodissociation Spectroscopy of Be(N2)n + and Be(CO)n + (n = 3-4): Charge Effects on Bonding and Coordination [0.03%]
带电效应的 bonding 和 coordination: 从 Be(N2)n+ 和 Be(CO)n+ (n = 3-4) 的红外光解离光谱中获得的数据
Yangyu Zhou,Guanjun Wang,Jiaye Jin et al.
Yangyu Zhou et al.
Beryllium dinitrogen and carbonyl cation complexes, Be(N2)n + and Be(CO)n + (n = 3-4), were produced in the gas phase by a laser vaporization-supersonic expansion ion source and investigated by infrared photodissociation spectroscopy in con...
Polyhalogenated 2,1,3-Benzochalcogenadiazoles: A Small-Molecule Platform for Multicentered Spin-Orbit Coupling Affecting Optical Properties (Chalcogens = S, Se, Te; Halogens = F, Cl, Br, I) [0.03%]
多卤化2,1,3-苯并灸圣噁二唑：影响光学特性的多重自旋轨道耦合小分子平台（灸圣元素=S，Se，Te；卤素=F，Cl，Br，I）
Ekaterina A Radiush,Taisiya S Sukhikh,Yulia S Kosenkova et al.
Ekaterina A Radiush et al.
2,1,3-Benzochalcogenadiazoles and their halogen derivatives (chalcogen = S, Se, Te; halogen = F, Cl, Br, I) are widely employed in organic optoelectronics as chromophoric/fluorophoric electron-acceptor building blocks. In this work they are...
Interfacial Stabilization of Li1.3Al0.3Ti1.7(PO4)3 Solid Electrolytes Enabled by a Sulfone-Based Crystalline Organic Interlayer [0.03%]
基于硫ones的结晶有机夹层稳定锂离子电池固态电解质界面副反应
Songyi Han,Lei Zhu,Muran Yu et al.
Songyi Han et al.
NASICON-structured Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolyte (SE) exhibits satisfactory ionic conductivity and robust mechanical strength, but it suffers from interfacial instability against lithium metal anodes due to Ti4+ reduction, ...
Sasank Pattnaik,Shruti Singh,Arindam Chowdhury
Sasank Pattnaik
All-inorganic halide perovskites, especially CsPbBr3 microrods, are often considered to be optically stable and less defect-prone compared to their organometallic counterparts. Nevertheless, reports of photoluminescence (PL) blinking in bul...
Transient Absorption Spectroscopy Probes Ultrafast Excited-State Dynamics in D-π-D Chalcone Derivatives [0.03%]
瞬态吸收光谱探测D-π-D chalcone衍生物中的超快激发态动力学
Suman Dhami,Yogesh Kumar,Panaha et al.
Suman Dhami et al.
Chalcone-based π-conjugated systems have attracted significant attention due to their tunable electronic properties and well-defined structure-property relationships. In this work, we have designed, synthesized, and characterized three D-...
Photochemical Reaction Mechanism of Phosphapropyne to Ethynylphosphinidene via Sequential Hydrogen Atom Transfers and Dehydrogenation [0.03%]
经连续氢原子转移和脱氢反应生成乙炔基磷化亚胺的磷丙二烯光化学反应机制研究
Di Mu,Quan-Song Li
Di Mu
Phosphinidenes are transient species that have contributed significantly to synthetic chemistry, coordination chemistry, and astrochemistry. Herein, the multistate complete active space second-order perturbation theory (MS-CASPT2) method ha...
Contribution of One-Electron Oxidation of Purine and Pyrimidine Bases to the Photo- and Radiation-Induced Damage to Cellular DNA [0.03%]
嘌呤和嘧啶碱基的一电子氧化对细胞DNA光致和辐射致损伤的贡献
Jean Cadet,Dimitar Angelov,Paolo DI Mascio et al.
Jean Cadet et al.
One-electron oxidants that include type I photosensitizers, biologically relevant carbonate anion radical generators, and high intensity UVC nanosecond lasers are able to ionize in aqueous solution purine and pyrimidine nucleobases. The sur...
Kritika Mahajan,Rama Kant
Kritika Mahajan
We develop a theory for the maximum (Young's) contact angle of wetting ( Θ m ) for metals based on the electrochemical work function (E-WF) and interfacial interactions at the droplet surface. In our theory, cos Θ m is the dif...
Strategies Enhancing the Efficiency of CoFe-Based Electrocatalysts for Oxygen Evolution Reaction in Alkaline [0.03%]
用于碱性析氧反应的CoFe基电催化剂效率提升策略
Jinpeng Fan,Yunshuo Wang,Liping Ren et al.
Jinpeng Fan et al.
The oxygen evolution reaction (OER), a critical process in energy conversion and storage technologies, necessitates highly efficient electrocatalysts to address its inherently sluggish kinetics. In recent years, cobalt-iron (CoFe) composite...
2D Transition Metal Carbo-Chalcogenides: An Emerging Family of Layered Materials [0.03%]
二维金属碳杂族化物：一种新型层状材料家族
Yu Wang,Mian Li,Xiaoping Ouyang et al.
Yu Wang et al.
Transition metal carbo-chalcogenides (TMCCs) represent an emerging class of 2D materials that combine the structural and functional features of 2D transition-metal carbides/nitrides (MXenes) and transition-metal dichalcogenides (TMDs). TMCC...