Photochemical Reaction Mechanism of Phosphapropyne to Ethynylphosphinidene via Sequential Hydrogen Atom Transfers and Dehydrogenation
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Phosphinidenes are transient species that have contributed significantly to synthetic chemistry, coordination chemistry, and astrochemistry. Herein, the multistate complete active space second-order perturbation theory (MS-CASPT2) method has been employed to i... ...