Konstantinos D Vogiatzis
Konstantinos D Vogiatzis
The integration of large language models (LLMs) into chemical sciences presents a transformative approach for molecular design. In this study, we explore the capabilities of LLMs for generating novel molecular structures with enhanced CO2 a...
Divergent [3+2] annulations of oxime acetates with thioaurones/aurones leading to benzothiazino-/benzoyl-pyrroles [0.03%]
肟乙酸酯与噻鸟喃酮/鸟喃酮的[3+2]环加成反应构建苯并噻嗪酮/-苯酰基吡咯类化合物
Chada Raji Reddy,Damodar Enagandhula,Andhavaram Ramaraju et al.
Chada Raji Reddy et al.
Herein, we report the development of unprecedented copper-catalyzed intramolecular annulations of oxime acetates with thioaurones/aurones (different reactivity observed) providing benzothiazino-/benzoyl-pyrroles in high yield. The key steps...
Comparing electrocatalytic and chemical oxygen reduction reaction by a molecular copper complex [0.03%]
一个分子铜配合物用于比较电催化和化学氧气还原反应
Lesa Dutta,Avijit Das,Babar Hasan et al.
Lesa Dutta et al.
Inspired by the CuB site in CcO, a molecular CuII complex (1) featuring a mixed pyridine-phenol ligand has been designed and synthesized. Electrocatalytic and chemical oxygen reduction reactions in the presence of 1 demonstrate a 4e-/4H+ re...
Umatai A Hale,Anil K Yadav,Nandita Madhavan
Umatai A Hale
Simple peptide derived anion-transporters are desirable for therapeutic use and as model systems to study natural proteins. Herein, acyclic dipeptides rich in aromatic units transport anions across lipid bilayers. The NH groups bind to anio...
Shape-dependent force constant dynamics in anatase TiO2 nanocrystals during lithium-ion insertion [0.03%]
锂离子嵌入时金红石型TiO2纳米晶中的形状依赖力常数动力学
Yuchuan Sun,Shichen Wang,Faysal M D et al.
Yuchuan Sun et al.
Operando Raman spectroscopy analyzed morphology-dependent force constants in anatase TiO2 nanocrystals under electrochemical lithiation. Pristine rhombic nanocrystals, nanospheres, and nanosheets exhibited ascending Eg band positions. Real-...
Continuous selective oxidation of methane to methanol on H+-ferrierite having a sheet-like morphology [0.03%]
具有片状形态的H+-ferrierite催化剂上甲烷选择氧化制甲醇研究
A Yilmaz,M O Ozbek,F Al et al.
A Yilmaz et al.
This study reports continuous and selective catalytic methanol production from methane on H+-FER with a sheet-like morphology using N2O as an oxidant. At 325 °C, total selectivity for methanol and dimethyl ether reaches up to 97% via trace...
A linear non-halogenated polymer donor via Suzuki-Miyaura coupling for organic solar cells [0.03%]
一种用于有机太阳能电池的线性非卤素聚合物受体通过苏扎- miyaura偶联反应合成
Zhili Chen,Bingyan Yin,Baoqi Wu et al.
Zhili Chen et al.
A novel linear non-halogenated polymer donor, PTTzP, with a simple structure was synthesized via Suzuki-Miyaura coupling. PTTzP exhibits comparable device performance (>12%) in organic solar cells (OSCs) when processed with halogenated and ...
Sn4P3-decorated 2D N-doped carbon nanosheets as efficient polysulfide barriers for Li-S batteries [0.03%]
Sn4P3修饰的二维N掺杂碳纳米片作为锂硫电池高效多硫化物阻隔层
Yawen Feng,Shunxian Yu,Xiaoxian Zhao et al.
Yawen Feng et al.
The Sn4P3@NCS multifunctional separator suppresses polysulfide shuttling via van der Waals physical adsorption and Sn4P3/N-polar chemical anchoring, delivering a high discharge capacity of 1250 mA h g-1 at 0.2C, and of 753 mA h g-1 at 4C, a...
Naoyuki Nishimura
Naoyuki Nishimura
Perovskite solar cells (PSCs) have attracted significant attention owing to their prominent photovoltaic (PV) performance. Their multi-layered structure facilitates efficient charge separation in i-type-like perovskite photoabsorbers when s...
Development of a near-infrared fluorescence probe for hypochlorous acid based on the phenyl-induced twisted intramolecular charge transfer (p-TICT) mechanism [0.03%]
基于联苯扭曲分子内电荷转移机制的次氯酸近红外荧光探针的研究与发展
Hisashi Ohno,Shun Sumitani,Ariunbold Chuluun-Erdene et al.
Hisashi Ohno et al.
Near-infrared (NIR) fluorescence probes for hypochlorous acid (HClO) are powerful tools for investigating various biological phenomena because of their low autofluorescence, high tissue penetration and usefulness for multicolour imaging. He...