Zhixin Wang,Hanxiao Xu,Xuanzhen Han et al.
Zhixin Wang et al.
Reactivity adaptation speciation perceives reactants as a dynamic supply pool of shifting reactive units for opportunistic reactivity-matching diverse-manifold pathways to varied reactivity patterns, revealing the title C2C3-CCl/CBr inser...
Water uptake behaviour of semiconducting glasses formed from hybrid organic-inorganic perovskites [0.03%]
由混合有机-无机钙钛矿形成的半导体玻璃的吸水行为
Jay McCarron,Libbie Hardy,Olivia Dunlop et al.
Jay McCarron et al.
Here we present the uptake behaviour of mechanochemically synthesised crystalline HOIPs, of the form [TAlA][M(dca)3] (TAlA = tetraalkylammonium, M = Mn2+ and Fe2+, dca = [C2N3-] (dicyanamide)), and their melt-quenched glassy derivatives. Th...
A sensitive 2D Cu-TCPP-based respiratory ammonia sensor for non-invasive and more accessible detection of Helicobacter pylori infection [0.03%]
一种灵敏的二维Cu-TCPP基呼吸氨传感器用于非侵入性和更易于获取的幽门螺旋杆菌感染检测方法
Yiran Wang,Mingwan Su,Lei Li et al.
Yiran Wang et al.
This study created a sensitive Raman ammonia sensor using 2D Cu-TCPP nanosheets for noninvasive H. pylori detection. Leveraging multiple ammonia-binding sites and Au nanoparticle signal enhancement, it achieved a 1 ppm detection limit. Test...
Direct and affordable alcohol phosphorylation through ambient electrochemical oxidation of phosphorous acid [0.03%]
基于磷酸的酒精直接电氧化膦化反应研究
Cham Wah Cheung,Edmund C M Tse
Cham Wah Cheung
Alcohol phosphorylation is a key reaction for producing phosphate monoester and is traditionally performed under harsh conditions using hazardous reagents. Here, we developed a one-step electrochemical alcohol phosphorylation to synthesize ...
Epitope bias in antibody affinity assays arising from charge-dependent orientation in carbodiimide-mediated protein immobilization using β2-microglobulin as a model antigen [0.03%]
碳二亚胺介导的蛋白质固定化过程中由于电荷依赖性取向导致抗原表位偏向：以β₂-微球蛋白为模型抗原的抗体亲和力测定中的表位偏向研究
Xiaolan Mai,Linlin Xu,Fang Cheng et al.
Xiaolan Mai et al.
Carbodiimide reactions are widely employed for protein immobilization. Although coupling to primary amines is theoretically random, the charge on carbodiimide reactive intermediates can induce a preferential orientation of proteins during i...
Does more carbon deposition necessarily lead to worse catalytic performance? [0.03%]
更多的碳沉积一定意味着更差的催化性能吗？
Hui Wang,Xuerong Zhu
Hui Wang
Conventional wisdom holds that higher carbon accumulation during reaction invariably deteriorates catalytic activity, yet emerging high-performance catalysts have demonstrated remarkable activity despite severe coke encapsulation, suggestin...
Spatially resolved operando X-ray diffraction for mapping heterogeneities in Li-ion single-layer pouch cells [0.03%]
空间解析原位X射线衍射技术用于绘制锂离子单层软包电池的不均匀性地图
Ashok S Menon,Stephen W T Price,Muhammad Ans et al.
Ashok S Menon et al.
The electrochemical degradation of Li-ion batteries occurs over different spatial and temporal scales. This work demonstrates how operando synchrotron X-ray diffraction can be used to study degradation in Li-ion battery materials by mapping...
The photoluminescence behaviour of monosubstituted non-benzenoid polycyclic-aromatic-substituted ortho-carboranes [0.03%]
单取代非苯型多环芳烃正交碳硼烷的光致发光行为研究
Adam V Marsh,Andrew J P White,Martin Heeney
Adam V Marsh
Ortho-Carborane is a cluster compound known for its ability to exhibit stimuli-responsive optical behaviour when substituted with aromatic fluorophores. Here, we describe the synthesis of two such compounds: 1-(4'-naphtho[2,3-b]thiophenyl)-...
An EDA complex-driven multicomponent reaction of Br-Rf with alkenes via radical-polar crossover [0.03%]
基于EDA复分解的自由基/极性转换溴代Rf与烯烃多组分反应研究
Zhen Chen,Jin-Xin Lan,Shu-Peng Zhang et al.
Zhen Chen et al.
We herein describe a general photo-induced EDA-enabled multicomponent reaction between alkenes, nitrogen heterocycles and Br-Rf, offering a mild, operationally simple, and broadly applicable alternative to traditional post modification of n...
Alkyl-chain-grafted 13X zeolite for steady CO2 capture from humid flue gas [0.03%]
用于潮湿烟气中稳定捕集二氧化碳的烷基接枝13X分子筛
Beining Cao,Qian Jia,Guoqiang Li et al.
Beining Cao et al.
13X zeolite shows potential for CO2 capture, but its performance is diminished by the steam present in real-world flue gas. To overcome this limitation, a facile and efficient approach is to graft straight-chain alkyl groups to the 13X stru...