Supramolecular network-based artificial light-harvesting system employing an AIE-active metallacycle for aqueous-phase photocatalytic oxidation [0.03%]
Ni Mao,Ponmani Jeyakkumar,Qian Liu et al.
Ni Mao et al.
A supramolecular network has been successfully constructed via synergistic coordination and host-guest interactions, achieving an efficient two-step FRET cascade.
Hydroxyl proton transfer for the deoxygenative reduction of alcohols mediated by Ph3P/ICH2CH2I [0.03%]
Zheng-Hong Liu,Mu-Xian Fu,Jin-Hong Lin et al.
Zheng-Hong Liu et al.
The reductive deoxygenation of alcohols is a valuable transformation for molecular simplification, yet it typically requires external hydrogen donors. We report a hydroxyl proton transfer strategy for the deoxygenative reduction of triarylm...
Epitaxial growth of rutile-type noble metal oxides layers on rutile TiO2 for heterogeneous catalysis [0.03%]
Xuan Tang,Anwen Yu,Shoujie Zhang et al.
Xuan Tang et al.
The construction of coherent oxide-oxide interfaces provides an effective route to modulate metal-support interactions and bridge atomic-level structure with catalytic function. This Feature Article summarises recent advances in the epitaxi...
Single-atom nanozymes for antitumor catalytic therapy: structural engineering, catalytic mechanism, and advanced therapeutic strategies [0.03%]
Zhangsibo Yu,Wanli Ma,Xue Wei et al.
Zhangsibo Yu et al.
Single-atom nanozymes (SAzymes) have emerged as a transformative platform for antitumor catalytic therapy, uniquely combining the catalytic efficiency of natural enzymes with the structural robustness of conventional nanozymes. Their atomic...
2,7-Diazatriptycene: acid-responsive ternary fluorescence switching via modulation of through-space conjugation [0.03%]
Ryo Inoue,Yusuke Hashimoto,Atsushi Aoki et al.
Ryo Inoue et al.
An unexplored 2,7-diazatriptycene exhibits protonation-controlled ternary fluorescence switching (on/off, cyan/violet) through modulation of through-space conjugation. Theoretical calculations clarified the origin of the contrasting fluores...
Nor Izzati Nordin,Khai Chen Tan,Teng He et al.
Nor Izzati Nordin et al.
Complex formation in monometal organic compounds remains largely unexplored. Here, we report the first experimental investigation of complex formation in lithium phenoxide, Li(C6H5O). Varying the LiOH/phenol ratio yields lithium-rich and ph...
Hikaru Nakahara,Junichiro Yamaguchi
Hikaru Nakahara
Direct conversion of aromatic rings into heteroaromatic frameworks represents an attractive strategy for tuning molecular properties in pharmaceuticals and functional materials. In recent years, the concept of molecular editing has emerged ...
Ionic polymer with cooperative CO2 adsorption and catalytic sites for efficient CO2 cycloaddition [0.03%]
Qi Cheng,Tong Liu,Chunliang Yang et al.
Qi Cheng et al.
A series of bifunctional ionic polymers were prepared, integrating spatially proximal CO2 adsorption sites (protonic ionic moieties) and catalytic sites (Br-) thereby enabling simultaneous CO2 enrichment and activation. This structural syne...
Squaramide-functionalized coordination capsule as hydrogen-bond-donor catalyst for efficient Friedel-Crafts alkylation [0.03%]
Song Zhao,Zhong Wei,Yao Wang et al.
Song Zhao et al.
A squaramide-functionalized tetranuclear coordination capsule was constructed as an efficient catalyst for Friedel-Crafts alkylation. The supramolecular architecture suppresses self-association and creates a confined cavity enriched with di...
Synergizing NiOOH formation and proton conduction via oxygen vacancy-induced dual regulation for 1,5-glutaric acid synthesis [0.03%]
Hao Chen,Zhixiang Yuan,Xinyu Sheng et al.
Hao Chen et al.
VO-CeO2-Ni(OH)2 electrocatalyst enables efficient electrooxidation of 1,5-pentanediol to 1,5-glutaric acid. Oxygen vacancies provide dual regulation: accelerating NiOOH reconstruction and increasing the proportion of 2-coordinated hydrogen-...