Fluoroalkyl-based near-infrared acceptors for morphology control enabling high-efficiency additive-free organic solar cells [0.03%]
含氟烷基近红外受体调控形态助力高效率无添加剂有机太阳电池
Wei Liu,Yijie Nai,Yitong Ji et al.
Wei Liu et al.
Herein, a fluoroalkyl side chain modified A-DA'D-A small molecule acceptor, Y18-F9, was developed to optimize the bulk heterojunction morphology in organic solar cells. The introduction of fluorocarbon chains promotes self-assembly into nan...
Photoredox mediated one-step syntheses of aryl C-glycosides from unprotected glycosyl sulfinates [0.03%]
无保护糖基硫𬭩盐与芳卤的光氧化还原偶联生成C-糖苷式产物
Ranadeep Talukdar,Antony J Fairbanks
Ranadeep Talukdar
Unprotected glycosyl sulfinates undergo Ni-mediated cross coupling with a range of aryl iodides and bromides under photoredox conditions to yield aryl C-glycosides, predominantly as the β-anomers. Thioglycoside formation is occasionally ob...
Synergistic effects of combining phototherapeutics with traditional treatment modalities in oncology [0.03%]
光疗与传统治疗方式联合使用在肿瘤学中的协同作用
Flavia Kradolfer,Caroline Maake,Bernhard Spingler
Flavia Kradolfer
Phototherapeutic methods like photodynamic therapy (PDT), photothermal therapy (PTT) and photodecaging have emerged as promising modalities for cancer treatment. Phototherapeutics are activated by light and thereby generate reactive oxygen ...
Efficient catalytic sulfur conversion in aqueous zinc-sulfur batteries mediated by iodide-coupled ether groups [0.03%]
碘介导的醚基团催化水系锌硫电池中高效硫转化性能研究
Shan Wang,Yuanze Chen,Jingxuan Gu et al.
Shan Wang et al.
A novel aqueous electrolyte incorporating tetraethylene glycol dimethyl ether (G4) and trace amounts of ZnI2 (HSG-I) is presented to enhance the sulfur conversion reversibility. G4 improves kinetics, stabilizes the interfaces, and enables u...
Solution polarity modulated electrochromic devices with tunable colored states [0.03%]
可调着色状态的溶液介电常数可控的电致变色器件
Junjie Chen,Wanli Li,Ke Li et al.
Junjie Chen et al.
Electrochromic devices (ECDs) hold great promise for applications in displays and smart military camouflage. However, achieving different electrochromic colored states with compatible integration into a monolithic device remains a significa...
Cobalt-catalyzed regio- and stereoselective synthesis of atropisomers with vicinal C-C and C-N diaxes [0.03%]
cobalt催化合成相邻C-C和C-N对映轴的异构体的区域和立体选择性反应
Suman Ghosh,Partha Sarathi Saha,Shib Nath Saha et al.
Suman Ghosh et al.
A regio-, diastereo-, and enantioselective cobalt-catalyzed C-H activation/annulation of aromatic and alkenyl amides has been developed to access heterocycles featuring vicinal C-C and C-N diaxes. This strategy uniquely harnesses previously...
The role of quantum dots in enhancing the therapeutic targeting of cancer stem cells [0.03%]
量子点在增强癌症干细胞治疗靶向中的作用
Malefo Tshepiso Mofokeng,Onyisi Christiana Didamson,Heidi Abrahamse
Malefo Tshepiso Mofokeng
In recent years, cancer stem cells have emerged as an interesting field in oncology due to their metastatic and resistance potential to chemotherapy and radiation therapy, thus resulting in the resurfacing of cancer even after multiple trea...
Creating skeletal complexity through an interrupted Corey-Chaykovsky reaction of activated alkynes [0.03%]
通过活化炔烃的中断Corey-Chaykovsky反应构建骨架复杂性
Nisha Yadav,S S V Ramasastry
Nisha Yadav
We present the first interrupted Corey-Chaykovsky reaction of α,β-ynones by intercepting the zwitterionic intermediates that prevail during the addition of the Corey-Chaykovsky reagent to activated alkynes. This cascade transformation unc...
Dynamic membranization results in core-shell coacervates that selectively localize particles and small molecules [0.03%]
动态界面聚合产生能够选择性局域粒子和小分子的核壳型共聚滴液
Tsvetomir Ivanov,Shoupeng Cao,Maximilian Schaaf et al.
Tsvetomir Ivanov et al.
We present a dynamic multiphase coacervate system that enables selective molecular partitioning, mimicking cellular compartmentalization. This pH-responsive platform separates enzymatic products based on polarity and exhibits enhanced collo...
Emerging role of aqueous batteries in next generation energy-dense sustainable storage [0.03%]
新一代高能量密度可持续储能中的水系电池的新兴角色
Aayushi Prakash Sinha,Tino S Thomas,Debaprasad Mandal
Aayushi Prakash Sinha
Aqueous metal batteries are emerging as promising candidates for next-generation energy storage, offering safer, more sustainable, and cost-effective alternatives to lithium-ion batteries (LIBs). Leveraging earth-abundant metals such as zin...