Developing a Zn(II)-metallovesicle for loading and delivering doxorubicin to kill cancer cells-a multi-drug delivery system [0.03%]
开发用于负载和递送多西环素以杀死癌细胞的锌(ii)金属囊泡-一种多重药物输送系统
Abhishek Dutta,Subhajit Ghosh,Parthasarathi Dastidar
Abhishek Dutta
An amphiphilic Zn(II)-coordination polymer (CP3) was rationally designed, successfully synthesised, and crystallographically characterized. It was derived from the non-steroidal anti-inflammatory drug (NSAID) flurbiprofen, as well as isopht...
Generation of alkyl radicals via C(sp3)-C(sp3) bond cleavage of xanthene-based precursors for photocatalytic Giese-type reaction [0.03%]
基于联苯化合物前体的C(sp³)-C(sp³)键裂解生成烷基自由基用于光催化吉塞反应
Shuta Horiuchi,Masato Oishi,Asuka Mizutani et al.
Shuta Horiuchi et al.
Novel xanthene-based alkyl radical precursors were developed and subjected to photocatalytic C(sp3)-C(sp3) bond cleavage for the efficient generation of alkyl radicals, which were subsequently reacted with various alkenes to afford the corr...
Electrochemical reductive coupling of terminal acetylenes and aldehydes to access propargylic alcohols [0.03%]
电化学还原偶联末端炔烃和醛合成官能团化丙炔醇化合物
Anil Balajirao Dapkekar,Satyanarayana Gedu
Anil Balajirao Dapkekar
Herein, we present an efficient and environmentally benign electrochemical strategy that enables the construction of propargylic alcohols through the cathodic reductive coupling of acetylenes and aldehydes under ambient conditions. Notably,...
Mechanochemical grafting enables fluorescein-sensitized cobalt-based MOF for visible-light-driven hydrogen evolution [0.03%]
机械化学接枝使荧光素敏化的钴基MOF用于可见光驱动的氢气演化反应
Taya Ko Saothayanun,Phirom Boun,Yollada Inchongkol et al.
Taya Ko Saothayanun et al.
A rapid mechanochemical approach was developed to covalently graft an isothiocyanate dye onto an amino-functionalized metal-organic framework (MOF), enabling visible-light-driven hydrogen production via dye sensitization. This method offers...
Glycosyl thiosulfonate: a stable electrophilic reagent for the synthesis of thioglycosylated indoles and total synthesis of isatindigotindolosides [0.03%]
用于合成硫糖基吲哚和异丝氨茋双吲哚生物碱的全合成的稳定的亲电试剂糖基硫素硫酸酯
Zanjila Azeem,Sunny Maurya,Abhishek Kumar Gupta et al.
Zanjila Azeem et al.
We disclose a copper-catalyzed C2- or C3-thioglycosylation of indole with a shelf-stable and odorless glycosyl thiosulfonate to assemble indole alkaloid glucoside frameworks. This straightforward catalytic system exhibits the features of br...
The role of main group elements in shaping the properties of linearly-fused heterohexaarenes [0.03%]
主族元素在调控杂环化合物性质中的作用研究——以共轭苯并二噻吩衍生物为例
Adrian Espineira-Gutierrez,Ines Caro-Noakes,Min Zhang et al.
Adrian Espineira-Gutierrez et al.
Embedding main group elements into the π-scaffold of linearly-fused hexaarenes enables fine-tuning of their optoelectronic properties in solution and in the solid state. Phosphorus leads to the best electron-accepting properties and increa...
Enhanced photocatalytic H2 production of CdS by the introduction of Cd vacancies [0.03%]
通过引入Cd空位提升CdS光催化产氢性能
Bihan Li,Yongpeng Xiao,Zheng Qi et al.
Bihan Li et al.
CdS nanoparticles with engineered Cd vacancies were synthesized by adjusting the starting materials of CdCl2·2.5H2O and Na2S·9H2O. Optimal performance was achieved at a Cd : S ratio of 1 : 2, yielding a 3.4-fold increase in hydrogen produ...
Enhancing deep chemical reaction prediction with advanced chirality and fragment representation [0.03%]
基于先进手性和片段表示的深度化学反应预测增强方法
Fabrizio Mastrolorito,Fulvio Ciriaco,Orazio Nicolotti et al.
Fabrizio Mastrolorito et al.
This work focuses on organic reaction prediction with deep learning, with the recently introduced fragSMILES representation - which encodes molecular substructures and chirality, enabling compact and expressive molecular representation in a...
Carbon aerogels and xerogels: next-generation materials for sustainable energy and environmental solutions [0.03%]
碳气凝胶和干凝胶：可持续能源和环境解决方案的下一代材料
David Tomić,Kristina Radinović,Dušan Mladenović et al.
David Tomić et al.
Carbon aerogels and xerogels, with their 3D porous architectures, ultralow density, high surface area, and excellent conductivity, have emerged as multifunctional materials for energy and environmental applications. This review highlights r...
Photocatalytic cyclization reaction of 2-vinylarylamines with CF3SO2Na and arylaldehydes to access 3-(2,2,2-trifluoroethyl)-3 H-indoles [0.03%]
2-乙烯基芳胺与CF3SO2Na和芳香醛的光催化环化反应以获得3-（2,2,2-三氟乙基）-3H吲哚类化合物
Mengda Song,Yuting Leng,Zhiwei Xu et al.
Mengda Song et al.
A visible-light-catalyzed three-component cyclization reaction of 2-vinylarylamines with CF3SO2Na and arylaldehydes is developed to build a series of 3-(2,2,2-trifluoroethyl)-3H-indoles. This protocol features mild reaction conditions using...