Size-controlled synthesis of ultrasmall Cu3VS4 nanocrystals via direct ternary nucleation [0.03%]
通过直接三元成核可控合成超小Cu3VS4纳米晶
Zhaohong Sun,Brendan Ward-O&#x;Brien,Yizhen Chen et al.
Zhaohong Sun et al.
We report the size-controlled synthesis of ultrasmall (3-8 nm), phase-pure, and stoichiometric Cu3VS4 nanocrystals via direct nucleation of the ternary sulvanite phase. An unusual redshift in optical absorption is observed with decreasing s...
Wenhui Chen,Lile Dong,Xiulin Xiao
Wenhui Chen
Hepatocellular carcinoma (HCC) is characterized by high malignancy, high recurrence rate and poor prognosis. Existing treatment still faces challenges such as insufficient precision, limited efficacy, and significant side effects, and there...
Synthesis and reactivity of a strongly pyramidalized P(III)-compound embedded into a pyrrolide (ONO)3- pincer ligand [0.03%]
封闭于吡咯𬭩盐(pyrrolium)(ONO)3-卡宾配体中的超强扭曲P(III)化合物的合成与反应性研究
Malte Kaste,Tobias Heilmann,Johannes Kircher et al.
Malte Kaste et al.
A Cs-symmetric P(III) complex bearing a pyrrolide-centered trianionic pincer ligand is reported and its reactivity explored. This compound reacts with alcohols and amines via oxidative addition of their respective O-H and N-H bonds at the P...
Solvent-induced structural transformation in luminescence-enhanced polymorphic ionic HOFs [0.03%]
溶剂诱导的发光增强型离子HOF多晶型物结构转变
Yi Yang,Bin Zhou,Yu-Ying Dai et al.
Yi Yang et al.
Solvent regulation achieves structure and luminescence switching between two polymorphic ionic hydrogen-bonded organic frameworks (iHOFs) and induces conjugation changes that create a pronounced emission difference-the emission intensity of...
Shortening the intramolecular Pd-Pd distances for photoactive dinuclear Pd(II) complexes [0.03%]
缩短双核Pd(II)复合物内的Pd-Pd距离以用于光活性复合物
Weixue Fan,Hua-Chao Liu,Yi Zhang et al.
Weixue Fan et al.
A series of dinuclear double-decker Pd(II) complexes exhibiting short Pd-Pd distances (ca. 2.78 Å) and red photoluminescence (λem = 600-625 nm in films) are described. Density functional theory calculations reveal the mixed ligand-to-liga...
Amorphization and defect engineering of Nb2O5 within a graphitic nanocage array for catalytic polysulfide conversion in lithium-sulfur batteries [0.03%]
用于锂硫电池催化多硫化物转化的石墨纳米笼阵列中的Nb2O5非晶化和缺陷工程
Yifan Gao,Hao Wang,Dong Yang et al.
Yifan Gao et al.
Lithium-sulfur batteries (LSBs) are limited by lithium polysulfide (LiPS) shuttling and sluggish redox kinetics. To address this challenge, we design an amorphous, oxygen-deficient Nb2O5 embedded in a mesoporous graphitic framework (Nb2O5@M...
Ye Peng,Lu Gao,Pengkun Yin et al.
Ye Peng et al.
We report a LEGO-inspired multipiece chip (LIM-Chip), a modular microfluidic system capable of streamlining multiple nucleic acid amplification and detection steps through on-demand chip assembly via universal 3D-printed side release buckle...
A hollow microporous organic network-based nanoprobe for imaging tumor-associated mRNA in living cells [0.03%]
一种基于中空微孔有机网络的纳米探针用于活细胞内肿瘤相关mRNA的成像
Zhi Yan,Yi-Wen Li,Rui-Jia Yang et al.
Zhi Yan et al.
A novel hollow-shaped microporous organic network (H-MON)-based nanoprobe was rationally designed and synthesized for survivin mRNA imaging. This work presents a promising strategy for the development of novel MON-based cancer-associated bi...
Upcycling waste plastic and spent batteries into hierarchical Co/carbon nanocomposites for high-performance electromagnetic wave absorption [0.03%]
基于废物塑料和废电池的协同热解制备高性能吸波剂分级Co/碳纳米复合材料
Binghong Lin,Kun Zuo,Yihong Zheng et al.
Binghong Lin et al.
Here we upcycle waste polyethylene terephthalate (PET) plastics and spent LiCoO2 batteries to synthesize hierarchical Co/C nanocomposites. Recovered terephthalic acid (R-TPA) and cobalt ions are used to fabricate a Co-based metal organic fr...
A new atom-transfer radical cyclization (ATRC) mediated by photocatalytically-generated aminyl radicals that do not have an α-C-H bond [0.03%]
一种光催化生成的非α-碳氢自由基参与的新型原子转移自由基环化反应（ATRC）
Ioannis Zachilas,Tamsyn Montagnon,Ioanna Pytikaki et al.
Ioannis Zachilas et al.
A photocatalytic method for the synthesis of sp3-rich bicyclic O,O- and N,O-iodoacetals from enol ethers and Boc-protected enamines has been developed. The simple procedure uses catalytic eosin (EY·Na2), a green solvent system (EtOH/water)...