Dual-control adsorption in hierarchical USY zeolites: orchestrating porosity and hydrophobicity [0.03%]
分层USY分子筛的双控吸附：调节孔隙率和疏水性
Jingxuan Wang,Li Li,Lin Li et al.
Jingxuan Wang et al.
USY zeolites with tailored silica-to-alumina ratios (SAR = 5-120) were prepared via steam-acid leaching. Increasing the SAR concurrently generates hierarchical mesoporosity and shifts the framework from hydrophilic to hydrophobic. This work...
Non-topotactic transformation pathway in electrochemical Li+/Na+ ion-exchanged Na-Mn-Fe phosphates for sodium-ion batteries [0.03%]
用于钠离子电池的电化学Li+/Na+交换的Na-Mn-Fe磷化物中的非拓扑转化途径
Peiyao Li,Kunmei Yang,Yingde Huang et al.
Peiyao Li et al.
Herein, olivine-LiMn0.6Fe0.4PO4 is converted to triphylite-NaMn0.6Fe0.4PO4via electrochemical ion-exchange, exhibiting unexpected non-topotactic phase transformation behavior. This cathode material demonstrates an energy density exceeding 4...
Stable organic radical luminescent groups and their applications in nano-diagnosis and therapy [0.03%]
稳定的有机自由基发光单元及其在纳米诊疗中的应用
Congyan An,Lifeng Yan
Congyan An
The unique singlet-state luminescence mechanism of stable organic radicals avoids the energy loss caused by inter-system crossing in traditional closed-shell molecules, providing a new approach for achieving efficient luminescence. This rev...
Chanyu Li,Jiayi Lu,Juan Xiang et al.
Chanyu Li et al.
We systematically investigate the coordination preference of three pyridine-based organic ligands with linear, tripod and X-type skeletons and coordination sites on Ag(111) under different stoichiometric ratios. Distinct coordination prefer...
A universal solution-phase strategy for bright lanthanide(III) emission: aggregation-induced emission via electronic-vibrational decoupling [0.03%]
一种通用的溶液相策略实现明亮的稀土发光：通过电子-振动解偶合实现聚集增强发射
Yifan Wang,Jinjin Wang,Siwei Zhang et al.
Yifan Wang et al.
To expand inorganic aggregation-induced emission systems, we demonstrate a universal solution-phase strategy for lanthanide(III) ions (Tb3+, Sm3+ and Dy3+) via electronic-vibrational decoupling: concentration-driven ligand-sphere reorganiza...
Optimizing the chloroallene pathway toward the one-pot synthesis of rubrene [0.03%]
优化氯代烯烃途径以实现一次合成rubyrene
Alberto Ongaro,Matteo Benetazzo,Giulia Tecchio et al.
Alberto Ongaro et al.
Rubrene, a benchmark organic semiconductor, is commonly synthesised from 1,1,3-triphenylpropargyl alcohol (TPPA) via the key chloroallene intermediate (TPCA) through a one-pot protocol whose efficiency is highly sensitive to the TPPA-TPCA c...
Cu-Co synergy enabling efficient tandem nitrate reduction to ammonia on engineered TiO2 nanofibers [0.03%]
铜-钴协同作用使钛纳米纤维上高效串联硝酸盐还原制氨成为可能
Bingyan Shi,Haoxin Cai,Xin Wen et al.
Bingyan Shi et al.
This study constructs a Cu1-Co1/TiO2 catalyst featuring diatomic sites anchored on TiO2 nanofibers. This architecture synergistically enables nitrate activation, reactive hydrogen species generation, and protonation of reaction intermediate...
Thionaphthalimide-based photosensitizer for efficient photodynamic therapy [0.03%]
基于噻吩萘酰亚胺的光敏剂用于高效光动力疗法
Qian Chen,Lingyu Jin,Jia Hong et al.
Qian Chen et al.
A novel amphiphilic thionaphthalimide-based photosensitizer with enhanced ROS generation in the aggregation state has been developed for efficient photodynamic therapy.
Mariangela Novello,Raffaella Mancuso,Bartolo Gabriele et al.
Mariangela Novello et al.
Carbonylation reactions, which rely on the controlled incorporation of carbon monoxide into organic substrates, represent a key tool in both organic and industrial chemistry. Carbonylation offers an efficient route to carbonyl-containing co...
Hyper-crosslinked polymeric ionic liquid (HCPIL)-based chainmail adsorbents for highly efficient gaseous toluene capture under high humidity [0.03%]
基于超交联聚合物离子液体的链甲基吸附剂在高湿度下高效捕获气态甲苯
Xiongfei Nie,Lei Zhang,Tao Jiang et al.
Xiongfei Nie et al.
A kind of hydrophobic chainmail adsorbent, Cu-BTC@HCPIL (water contact angle up to 109.6°), was developed through ionic liquid-based hyper-crosslinked polymer surface engineering of a metal-organic framework (MOF). Under 80% relative humid...