Pyrochlore Bi2Sn2O7 photocatalysts: a systematic review on performance tuning and multifunctional applications [0.03%]
Bi2Sn2O7钙钛矿型光催化剂研究：综述性能调控及多功能应用方面的工作
Zhiwei Shao,Xiaojiao Du,Wei Jiang et al.
Zhiwei Shao et al.
Given the limitations of traditional photocatalysts in terms of the light absorption range and carrier recombination rate, Bi2Sn2O7 (BSO) has attracted widespread attention due to its unique crystal structure, tunable band characteristics, ...
Lei Li,Bingjie Fu,Yue Zhao et al.
Lei Li et al.
Metallaaromatics are attractive due to their special structures and properties. In this work, the first metalla-phenalenyl complexes containing CReC units were obtained from ReCl3(PMePh2)3 and 1,8-diethynylnaphthalene compounds. The del...
A direct comparison of lithium tetra(n-butyl) manganate(II) and magnesiate: structural insights and catalytic hydroamination of styrenes [0.03%]
乙基丁基锰酸锂和镁化物的直接比较：结构见解及茋的催化氢胺化反应
Rebecca S Jones,Tobias Krämer,Gary S Nichol et al.
Rebecca S Jones et al.
Previous studies have hinted at the similarities of Mn(II) and Mg alkyl complexes. Advancing this field, here we present a comparative study of tetra(n-butyl)lithium manganate(II) and magnesiate. Combining X-ray crystallographic studies, NM...
High-performance ceria via supramolecular metal-organic gel precursors for visible-light-driven hydrogen evolution from aqueous glucose [0.03%]
通过超分子金属有机凝胶前驱体获得高性能的氧化铈用于可见光驱动葡萄糖水溶液分解制氢反应
Andrea Muscatello,Giuseppina Iervolino,Vincenzo Vaiano et al.
Andrea Muscatello et al.
A supramolecular cerium-based metal-organic gel (MOG) was used as a soft precursor to prepare a defect-rich CeO2 photocatalyst. The resulting material exhibited enhanced visible-light-driven hydrogen evolution from glucose, outperforming co...
Siyi Luo,Chen-Chen Li,Zihang Qiu et al.
Siyi Luo et al.
A novel method for the deoxydehydration (DODH) of diols to alkenes has been developed by using hydrazine as a reductant via HOME (hydrazone as an organometallic equivalent) chemistry catalyzed by Ru-PNP complexes. This process avoids harsh ...
Distinct roles of tandem acyl carrier protein domains in the assembly of a macrocyclic polylactone [0.03%]
串联乙酰载体蛋白结构域在一个大环多聚内酯分子的生物合成中的不同作用
Thanakorn Deelee,Pakorn Wattana-Amorn
Thanakorn Deelee
Mutagenesis of the tandem acyl carrier protein (ACP1-ACP2) domains in the non-reducing polyketide synthase Men2 revealed their distinct roles in menisporopsin A biosynthesis. ACP1 is essential for multiple esterifications and cyclolactonisa...
Non-covalent interaction-controlled site-selective benzylic C(sp3)-H oxidation [0.03%]
可控非共价相互作用选择性氧化苄位C(sp3)氢原子
Reina Nonami,Honoka Toyama,Kanata Shiraishi et al.
Reina Nonami et al.
By leveraging the non-covalent interaction between a sulfonate group-containing anthraquinone-type catalyst and an anilinium salt, selective benzylic C(sp3)-H oxidation proceeds at the meta-position in substrates with two possible reaction ...
Enhanced second-harmonic generation response in a chiral lead iodide induced by amino acid coordination [0.03%]
氨基酸配位诱导的手性碘铅中增强的二次谐波生成响应
Juan Cheng,Gangji Yi,Qinglan Zhong et al.
Juan Cheng et al.
A chiral organic-inorganic hybrid lead iodide (l-pro)2PbI2 was synthesized using L-proline as a terminal ligand. This material exhibits a strong second-harmonic generation response of 4.0 times that of KH2PO4, which originates from distorte...
A carbon-based single-atom Cu electrocatalyst for efficient conversion of CO2 to carbon products [0.03%]
一种基于碳的单原子Cu电催化剂高效将CO2转化为碳产物
Bo Huang,Fang Zhao,Jiantao Fu et al.
Bo Huang et al.
The simultaneous and efficient electroreduction of CO2 to C1 and C2 different phase products is an extremely challenging task due to the competitive reaction of hydrogen evolution, high energy barrier of CO2 activation and C-C coupling. Her...
Remodelling of tricyclic carbon frameworks with a norbornene scaffold [0.03%]
具有norborne型支架的三环碳框架的改建
Akihiro Yoshitani,Tomonari Sasage,Ranmaru Kato et al.
Akihiro Yoshitani et al.
We describe a halogen/chalcogen-mediated skeletal rearrangement of tricyclo[4.3.0.03,7]non-8-ene derivatives that feature a norbornene framework with two hydroxy/silyloxy groups substituted on the bridgehead carbons, yielding a tricyclo[4.2...