Layered double hydroxides in catalyzing the green hydrogen revolution: advancements and prospects [0.03%]
层状双氢氧化物催化的绿色氢能革命：进展与前景
Priyadarshi Roy Chowdhury,Himani Medhi,Krishna G Bhattacharyya et al.
Priyadarshi Roy Chowdhury et al.
Layered double hydroxides (LDHs) are emerging as critical materials for advancing the green hydrogen economy due to their versatility, cost-effectiveness, and tunable catalytic properties. Their layered structure allows for compositional fl...
Progress in porphyrin-based covalent organic frameworks for enhanced photodynamic antimicrobial therapy [0.03%]
基于卟啉的共价有机框架在增强光动力抗菌治疗方面的进展
Xinran Wang,Xiaohui Wang,Shanmei Wang et al.
Xinran Wang et al.
Bacterial infections that delay wound healing represent a substantial challenge to human health. The advancement and implementation of porphyrin-based phototherapy provide a critical solution for addressing bacterial resistance, which has b...
Structure revision of meroterpenoid natural products enabled by biomimetic total synthesis [0.03%]
生物启发的全合成驱动的船舱天然产物结构修订
Jonathan H George
Jonathan H George
Meroterpenoids constitute a vast and structurally diverse family of natural products with mixed biosynthetic origins, found across nearly all forms of life on Earth. Despite their often intricate architectures, meroterpenoid biosynthesis fo...
Bimetallic Al-M complexes derived from low-valent aluminium sources (M = s-/p-block metal) [0.03%]
由低价铝源衍生的二金属Al-M配合物(M=s-/p区金属)
Martyn P Coles
Martyn P Coles
Bimetallic complexes containing direct metal-metal bonds occupy an important position in many aspects of coordination chemistry and catalysis. The reactivity of these compounds often differs from that shown by their monometallic analogues a...
Fabricating stable quinoline-linked phenothiazine-based covalent organic frameworks for flexible supercapacitors [0.03%]
用于柔性超级电容器的稳定的喹啉连接茋基共价有机框架的构筑
Mengyu Yuan,Kaixuan Wang,Zhaoyang Zhang et al.
Mengyu Yuan et al.
A stable quinoline-linked phenothiazine-based covalent organic framework (QCOF) was constructed. The MXene/QCOF@CNT electrode was then fabricated for flexible supercapacitors. Notably, it achieves 11 Wh kg-1 at 250 W kg-1 and retains 100% o...
Lattice-distorted quasi-single-crystalline Cu-based nanoarrays for robust electrochemical methanol upgrading to produce formate [0.03%]
用于鲁棒电化学甲醇升级制备甲酸的晶格畸变准单晶Cu基纳米阵列
Xianghui Pang,Zhuangzhuang Ren,Ruihao Wang et al.
Xianghui Pang et al.
We report a phosphate-incorporated Cu(OH)2 nanoarray catalyst featuring lattice distortion and a quasi-single-crystalline structure. This unique design enriches local active sites and facilitates pre-oxidation, achieving 99.9% faradaic effi...
Reconciling color purity and redox potential in electrochromic materials via electronic-state-informed molecular design [0.03%]
基于分子设计的电致变色材料颜色纯度和氧化还原电位的协调研究
Daisuke Goto,Hirotoshi Mori
Daisuke Goto
Reconciling vivid coloration and low oxidation potential in electrochromic materials-essential for functional devices such as displays, sensors, and energy systems-remains a key challenge due to intrinsic electronic trade-offs. Here we esta...
The relative importance of contact-angle hysteresis and work of adhesion on droplet "roll-off" or sliding angles [0.03%]
接触角迟滞和附着力对液滴“滚落”或滑动角度的相对重要性
Fatema B Amin,Gregory S Ferguson
Fatema B Amin
A series of mixed monolayers formed by self-assembly of alkanethiols on gold exhibits complementary wetting behavior for hexadecane and water that allowed us to independently assess how strongly the contact-angle hysteresis and work of adhe...
An Fe(II) complex detects hydrogen peroxide with 1H and 19F magnetic resonance imaging responses [0.03%]
一个Fe(II)配合物可通过氢-1氢过氧化物和氟-19磁共振信号检测氢过氧化物
Sana Karbalaei,Alicja Franke,Achim Zahl et al.
Sana Karbalaei et al.
We report the fluorinated quinol-containing ligand, 1,8-bis(2,5-dihydroxy-4-fluorobenzyl)-1,4,8,11-tetraazacyclotetradecane (F2H4qp4), and its highly water- and air-stable Fe(II) complex. Upon oxidation by H2O2, the 19F MRI signal of the co...
[C(NH2)3]2[C2H5(C2O4)]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifs [0.03%]
[_CN(H_2)_3]^2_[C_2H_5(C_2O_4)]Cl：通过三种不同基元的协同组装理性设计金属自由UV双折射晶体
Yu-Ming Pan,Xin-You An,Zhi Fang
Yu-Ming Pan
Developing metal-free birefringent crystals is of great significance in laser technology. Herein, a metal-free birefringent crystal, [C(NH2)3]2[C2H5(C2O4)]Cl, was rationally obtained via a hydrogen-bond-directed assembly of three distinct m...