Annabel Benny,Devika Vijayan,Rajeshkumar Thayalan et al.
Annabel Benny et al.
The synthesis, structure and Lewis acidic reactivity of a perfluoro-tert-butoxyaluminium dication stabilised by five aldehyde ligands [{(F3C)3CO}Al{4-MePhCHO}5]2+, and charge-balanced by two [Al{OC(CF3)3}4]- anions is presented here. Treati...
Fiber separators: optimizing bulk and interface behaviors in high energy batteries [0.03%]
纤维隔膜：高能量电池中电极内部和界面行为的优化
Tao Zhang,Xiao Li,Guiyin Xu
Tao Zhang
High energy density batteries represent a pivotal focus in the advancement of next-generation energy storage technologies, necessitating rigorous specifications for separators, which are critical inactive components. A significant technical...
Metal-organic framework adsorbents for selective divalent cation removal/recovery from water [0.03%]
用于从水中选择性去除/回收二价阳离子的金属有机骨架吸附剂
Harith Al-Rawe,Jue Hou,Huacheng Zhang
Harith Al-Rawe
Elevated levels of divalent metal ions in water pose significant risks to human health and the environment. Among various water treatment technologies, adsorption stands out for its high efficiency, simplicity, and versatility. Metal-organi...
A fluorogenic probe for screening aldehyde dehydrogenase 1A1 (ALDH1A1) inhibitors [0.03%]
一种用于筛选醛脱氢酶1A1(ALDH1A1)抑制剂的荧光探针
Shilpendu Ghosh,Sayar Ghosh,Aniket Majee et al.
Shilpendu Ghosh et al.
We report the first competitive aldehyde dehydrogenase 1A1 (ALDH1A1) inhibitor featuring a fluorogenic binding response and nanomolar affinity (KD), enabling real-time screening of non-fluorescent inhibitors with high cellular compatibility...
Dual nitrogen and oxygen vacancy-enhanced plasma catalysis for mild NH3 synthesis [0.03%]
低温合成氨的双氮空位和氧空位增强等离子体催化剂
Shijian Luo,Yongduo Liu,Yang Song et al.
Shijian Luo et al.
Plasma-assisted NH3 synthesis has recently emerged as a promising complementary approach to the Haber-Bosch process for decentralized and sustainable NH3 production. Here, we introduce an ingenious catalyst design strategy featuring "dual v...
PdS-modified ZnCdS nanorods for photocatalytic anaerobic oxidation of 5-hydroxymethylfurfural coupled with hydrogen evolution [0.03%]
PdS改性的ZnCdS纳米棒用于5-羟甲基糠醛的光催化厌氧氧化与产氢耦合反应
Ning Sha,Ming-Yu Qi,Yi Zhang et al.
Ning Sha et al.
This work reports a PdS-modified ZnCdS (PdS/ZCS) composite for the anaerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran along with hydrogen evolution. Compared to pristine ZCS, PdS/ZCS exhibits significantly enhanced photocat...
Mesoporous polyphosphamide catalyzed heterogeneous one-pot Wittig olefination [0.03%]
中空介孔聚磷酸盐催化 Wittig 烯基化的一锅法异相反应
Anup Mahata,Rassel Shaikh,Biswarup Chakraborty
Anup Mahata
Phosphamides comprising -{PV(O)NH}- linkages are used as ligand scaffolds to prepare pharmaceutical products, whereas their polymeric forms are employed as flame retardants. A mesoporous triazole-functionalized polyphosphamide (t-PPA) is re...
Yanqiu Du,Yujiong Yao,Pingfan Wang et al.
Yanqiu Du et al.
Surface functionalization of colloidal nanocrystals (NCs) with ion-specific polymeric ligands enables programmable modulation of ligand hydrophilicity-hydrophobicity via the Hofmeister effect. This control drives NC rearrangement and reorie...
A tetraphenylethylene-based dicyclophane with an o-carborane framework exhibiting dual-state emission [0.03%]
基于四苯基乙烯的二环环糊精型o-碳硼烷化合物的双发射态研究
Rongjian Chen,Yuxiao Qin,Shuai Yuan et al.
Rongjian Chen et al.
In this study, a tetraphenylethylene-based dicyclophane with an o-carborane framework was constructed. This material exhibits excellent dual-state emission in both solution and solid states, demonstrating solvent-dependent orange-to-blue fl...
Sustainable synthesis of hydrosilanes and alkoxysilanes in a sequential one-pot olefin hydrosilylation and dehydrogenative coupling with alcohol under phenoxyiminato cobalt(II) catalysis [0.03%]
在苯氧基酰亚胺酸盐钴(II)催化下烯烃连续单锅氢硅化和脱氢偶联醇合成杂硅烷的研究
Jakub Robaszkiewicz,Bartłomiej Szarłan,Piotr Pawluć et al.
Jakub Robaszkiewicz et al.
A simple, bench-stable cobalt complex catalyses alkene hydrosilylation, offering a green alternative to precious metals. The activator-free system shows olefin-dependent regioselectivity, yielding α-adducts from vinylarenes (in a solvent-f...