HUH endonuclease-mediated DNA-protein conjugates: sequence-specific tools and cellular applications [0.03%]
HUH内切酶介导的DNA-蛋白质连接物：序列特异性工具及细胞应用
Xiaowei Huang,Haokun Li,Jiajun Du et al.
Xiaowei Huang et al.
This highlight review article summarizes recent advances in employing HUH endonucleases as self-labeling protein tags for the sequence-specific covalent conjugation of unmodified ssDNA and examines their applications in cellular studies via...
Efficient synthetic approach to m-terphenyl derivatives via arylation of azolium salts [0.03%]
茋衍生物的合成方法研究
Subarna Kar,Arya Ramachandran,Arnab Rit
Subarna Kar
A series of m-terphenyl scaffolds connected to imidazolium salts have been obtained via Ru(II)-catalyzed arylation using haloarenes. The present approach offers structural flexibility, enabling effective access to diverse m-terphenyl based ...
Xenon adsorption-induced flexibility of the zeolitic imidazolate framework ZIF-4 observed by in situ129Xe NMR spectroscopy [0.03%]
采用原位129Xe固态核磁共振观察得到的吸附氙引起的咪唑化石油烯框架ZIF-4的柔性行为
Tobias Bode,Wen-Long Xue,Yutong Wang et al.
Tobias Bode et al.
In situ 129Xe NMR spectroscopy reveals an unexpected, xenon adsorption-induced flexibility of ZIF-4. Beyond a certain threshold pressure, xenon induces a structural transition at low temperature. This behaviour is in contrast to CO2, where ...
La/Ni dual-doping in carbon nanofiber-supported cobalt electrocatalysts toward high-efficiency biomass upgrading [0.03%]
用于高效生物质升级的碳纳米纤维负载钴电催化剂的La/Ni共掺杂作用研究
Yaqin Yu,Di Yan,Xin Liu et al.
Yaqin Yu et al.
Electrocatalytic oxidation of low-cost 5-hydroxymethylfurfural (HMF) into value-added chemicals like 2,5-furandicarboxylic acid (FDCA) is imperative for sustainable energy and environmental applications. Herein, La/Ni co-doped Co nanopartic...
Palladium-catalyzed Heck/polyfluoroarylation of alkene-tethered carbamoyl chlorides with polyfluoroarenes [0.03%]
钯催化内碳酰氯的烯烃与多氟芳烃的Heck/亲电 fluorination反应
Chen Chen,Zi-Yi Wang,Xin-Yu Hu et al.
Chen Chen et al.
We developed a Pd-catalyzed Heck/polyfluoroarylation cascade to synthesize polyfluoroarylated oxindoles with all-carbon quaternary centers from alkene-tethered carbamoyl chlorides. The reaction was extended to a three-component one-pot prot...
Sub-2 nm PtRu alloy embedded in carbon nanosheets for enhanced hydrogen evolution in acid and alkaline media [0.03%]
亚纳米PtRu合金嵌入碳纳米片以提升酸性和碱性介质中的氢演化性能
Zhijuan Li,Junjie Feng,Minghao Hou et al.
Zhijuan Li et al.
We report a salt-template-assisted pyrolysis strategy to synthesize sub-2 nm PtRu alloy nanoparticles embedded in ultrathin carbon nanosheets. The resulting Pt2Ru/C catalyst exhibits outstanding hydrogen evolution activity and stability in ...
Visible-light photoredox catalyzed thioesterification of sulfoxonium ylides with elemental sulfur and α-ketoacids [0.03%]
可见光催化下单线态硫化物亚胺离子与元素硫和α-酮酸的缩合反应
Juanjuan Wu,Leilei Wang,Huilan Yue et al.
Juanjuan Wu et al.
An efficient strategy for the construction of α-keto thioesters has been developed via photocatalytic one-pot three-component reaction of sulfoxonium ylides with elemental sulfur and α-ketoacids. The reaction proceeded smoothly at room te...
A high-spin Mn-tailored sodium hexacyanoferrate electronic structure enables efficient Mg2+ storage [0.03%]
高自旋Mn修饰的钠六氰合铁酸盐电子结构可实现高效的Mg2+存储
Yue Yang,Hui Li,Yusheng Zhang et al.
Yue Yang et al.
Sodium hexacyanoferrate (NaFeHCF) is a promising cathode material for aqueous magnesium-ion batteries (AMBs) but suffers from limited active site utilization. Here, high-spin Mn is incorporated into the Fe sites of NaFeHCF to modulate its e...
Wataru Tanaka,Chaiyanut Jirayupat,Haruka Honda et al.
Wataru Tanaka et al.
In response to growing demands for secure and user-friendly individual authentication methods, biometric technologies have seen widespread adoption, offering advantages over traditional password- or card-based systems. While current biometr...
Advances in metal-catalyzed strategies for carbohydrate functionalization [0.03%]
金属催化的碳水化合物衍生化反应研究进展
Ahmed El Rhaz,Lisa Bonin,Ameni Hadj Mohamed et al.
Ahmed El Rhaz et al.
Transition metal catalysis provides a versatile and powerful platform for the construction of structurally complex molecules. In recent years, its application has been successfully extended to the functionalization of carbohydrates, signifi...