Narrow-Line Width Emission and Room Temperature Amplified Spontaneous Emission in Three-Dimensional Ge Halide Perovskites [0.03%]
三维锗卤素钙钛矿的窄线宽发光及室温放大自发辐射现象
Marta Morana,Andera Olivati,Marco Moroni et al.
Marta Morana et al.
We report the structural and optoelectronic properties of lead-free CsGeI3 and CsGeBr3 perovskites, unveiling the critical role of local symmetry distortions in defining their emission properties. CsGeBr3 exhibits broad photoluminescence fr...
From Bifunctionality to Multifunctionality: Nitrogen-Doped Carbon Nanostructures (CN x ) for Electrocatalytic Applications in Fuel Cells and Beyond [0.03%]
从双功能到多功能：燃料电池及其它应用的氮掺杂碳纳米结构(CNx)电催化材料
Anant Sohale,Snehal Patil,Seval Gunduz et al.
Anant Sohale et al.
This article provides an overview of the studies performed in our laboratories for developing nitrogen-doped carbon nanostructures (CN x ) as precious-metal-free bifunctional oxygen reduction reaction (ORR) and oxygen evolution reaction (OE...
High Lithium Content and Site Disorder in the Transition Metal Oxide Argyrodites Li7TiO5X (X = Cl-, Br-) [0.03%]
富锂和过渡金属氧化物argyrodite型Li7TiO5X(X=Cl-,Br-)的位点无序现象
Alexandra Morscher,Lucia Corti,Samuel L Goodwin et al.
Alexandra Morscher et al.
Sulfide lithium argyrodites are a key materials family that are studied as solid electrolytes in commercial all-solid-state batteries (ASSBs), while their oxide analogues remain relatively unexplored. This study presents the discovery of Li...
Combining Anisotropic 119Sn NMR and Ab Initio Calculations to Probe the Stereoactive Lone Pair in Sn(II) Metal-Organic Frameworks [0.03%]
结合各向异性119Sn NMR与从头算计算探测Sn(II)金属有机框架中的参与成键的孤对电子性质
Helena R Loan,Ryan J Bragg,Caitlyn F Walton et al.
Helena R Loan et al.
The coordination environments of several Sn-(II) metal-organic frameworks (MOFs) have been investigated using 119Sn solid-state NMR in combination with density functional theory (DFT) calculations. The Sn-(II) nucleus exhibits high chemical...
Unraveling Thermally Regulated Gating Mechanisms in TPT Pore-Partitioned MOF-74: A Computational Endeavor [0.03%]
探究MOF-74中TPT孔分配的温度调控门机制：一种计算研究
Gavin A McCarver,Morgan J Kramer,Taner Yildirim et al.
Gavin A McCarver et al.
In the pursuit of advanced gas adsorption materials, we investigate the thermally activated gating mechanism of functionalized TPT (2,4,6-tri(4-pyridyl)-1,3,5-triazine) ligands within the one-dimensional channels of Mg-MOF-74. These ligands...
Structure-Optical Property Relationships in AMM'Q3 Chalcogenides [0.03%]
AMM'Q3 硝族化合物的结构与光学性质关系（A，M，M' = 金属；Q = 硫/硒/碲）
Ayat Tassanov,Huiju Lee,Daniel W Spainhour et al.
Ayat Tassanov et al.
Ten ACuHfQ3 (A = Na, K, Rb, Cs; Q = S, Se, Te) chalcogenides were prepared via high-temperature solid-state methods and structurally characterized using single-crystal X-ray diffraction. The type-I AMM'Q3 structures are defined by the arran...
Trends for Proton Transport Activity and Stability in Turnbull's Blue Analogues: Theory and Experiments [0.03%]
理论与实验结合揭示Turnbull's蓝类似物中的质子传导规律
Mengru Li,Rui Wang,Pen-Yeh Yen et al.
Mengru Li et al.
Prussian Blue analogues (PBAs) are promising materials for energy storage and conversion because their robust open-framework structures enable efficient ion intercalation. Among them, Turnbull's Blue analogues (TBAs), a subclass featuring f...
Step-by-Step Real-Time Electron Paramagnetic Resonance Monitored Protocol for Synthesizing a Nitroxide-Functionalized Periodic Mesoporous Organosilica [0.03%]
实时电子顺磁共振监测合成硝酮功能化周期性介孔有机硅的分步操作法
Tiago Morais,Satyaki Chatterjee,Mirtha A O Lourenço et al.
Tiago Morais et al.
This protocol describes a step-by-step approach for the synthesis of a periodic mesoporous organosilica (PMO) with wall-embedded nitroxide monoradicals. It starts with the synthesis of an isoindoline-based nitroxide monoradical and its sily...
Structure, Electrochemistry, and Phase Evolution of Al-Substituted Na2/3[Ni1/3‑yMn2/3‑zAl y+ z ]O2 as a Sodium-Ion Battery Cathode Material [0.03%]
铝代Na2/3[Ni1/3-yMn2/3-zAly+z]O2作为钠离子电池正极材料的结构、电化学性能及相变行为研究
Anthony T Pacileo,Patrick Deegan,Hao Liu
Anthony T Pacileo
Sodium layered transition metal oxide is a promising cathode material for Na-ion batteries. The P2-type structure and especially the Na2/3[Ni1/3Mn2/3]-O2 (NaNM) composition are desirable for their rate capability and energy density. Unfortu...
Michael A McGuire,Nabaraj Pokhrel,Matthew S Cook et al.
Michael A McGuire et al.
The crystal structure and properties of CrAu3Sb6 are presented, determined by measurements on single crystal and polycrystalline samples and first-principles calculations. The trigonal structure (space group P3̅1m) comprises a CdI2-like su...