Toward a versatile toolbox for cucurbit[ n]uril-based supramolecular hydrogel networks through in situ polymerization [0.03%]
基于葫芦[n]脲的超分子水凝胶网络的通用工具箱研究及原位聚合
Ji Liu,Cindy Soo Yun Tan,Yang Lan et al.
Ji Liu et al.
The success of exploiting cucurbit[n]uril (CB[n])-based molecular recognition in self-assembled systems has sparked a tremendous interest in polymer and materials chemistry. In this study, polymerization in the presence of host-guest comple...
Supramolecular polymerization of a ureidopyrimidinone-based [2]catenane prepared via ring-closing metathesis [0.03%]
通过环闭化元合成的脲基并嘧啶酮类[2]索烃的超分子聚合
Abraham J P Teunissen,José Augusto Berrocal,Christiaan H W A Corbet et al.
Abraham J P Teunissen et al.
The synthesis and supramolecular polymerization of a ureidopyrimidinone-based Sauvage-type [2]catenane is reported. The monomer synthesis explores many routes using the elegant metathesis catalysts of Bob Grubbs, yielding a catenane with on...
C Orofino,C Foucher,F Farrell et al.
C Orofino et al.
A series of star-shaped oligofluorene molecules, each containing a TPE core, have been specifically designed and produced to show effective aggregation-induced emission (AIE). Each molecule differs either in the number of fluorene units wit...
Pyrene-cored covalent organic polymers by thiophene-based isomers, their gas adsorption, and photophysical properties [0.03%]
基于噻吩异构体的联苯核心共价有机聚合物的制备及其气体吸附和光物理性能研究
Changfeng Li,Peixian Li,Linjiang Chen et al.
Changfeng Li et al.
Two new pyrene-cored covalent organic polymers (COPs), CK-COP-1 and CK-COP-2, were synthesized via the one-step polymerization of two thiophene-based isomers, 1,3,6,8-tetra(thiophene-2-yl) pyrene (L1 ) and 1,3,6,8-tetra(thiophene-3-yl) pyre...
Properties of acyl modified poly(glycerol-adipate) comb-like polymers and their self-assembly into nanoparticles [0.03%]
酰基修饰的聚甘油腺酸酯梳状聚合物的性质及其自组装纳米粒子性能研究
Vincenzo Taresco,Jiraphong Suksiriworapong,Rhiannon Creasey et al.
Vincenzo Taresco et al.
There is an increasing need to develop bio-compatible polymers with an increased range of different physicochemical properties. Poly(glycerol-adipate) (PGA) is a biocompatible, biodegradable amphiphilic polyester routinely produced from div...
Recent approaches in designing bioadhesive materials inspired by mussel adhesive protein [0.03%]
受壳聚粘蛋白启发的生物粘合材料设计的新思路
Pegah Kord Forooshani,Bruce P Lee
Pegah Kord Forooshani
Marine mussels secret protein-based adhesives, which enable them to anchor to various surfaces in a saline, intertidal zone. Mussel foot proteins (Mfps) contain a large abundance of a unique, catecholic amino acid, Dopa, in their protein se...
Dynamic covalent polymers [0.03%]
动态共价聚合物
Fátima García,Maarten M J Smulders
Fátima García
This Highlight presents an overview of the rapidly growing field of dynamic covalent polymers. This class of polymers combines intrinsic reversibility with the robustness of covalent bonds, thus enabling formation of mechanically stable, po...
Synthesis and facile end-group quantification of functionalized PEG azides [0.03%]
功能化聚乙二醇叠氮的合成及末端基团的简易量化分析
J Edward Semple,Bradford Sullivan,Tomas Vojkovsky et al.
J Edward Semple et al.
Azido-functionalized poly(ethylene glycol) (PEG) derivatives are finding ever-increasing applications in the areas of conjugation chemistry and targeted drug delivery by their judicious incorporation into nanoparticle-forming polymeric syst...
One-pot inimer promoted ROCP synthesis of branched copolyesters using α-hydroxy-γ-butyrolactone as the branching reagent [0.03%]
基于α-羟基-γ-丁内酯支化单体的一锅ROCP法制备支化共聚酯
Geng Hua,Johan Franzén,Karin Odelius
Geng Hua
An array of branched poly(ɛ-caprolactone)s was successfully synthesized using an one-pot inimer promoted ring-opening multibranching copolymerization (ROCP) reaction. The biorenewable, commercially available yet unexploited comonomer and i...
Well-controlled ATRP of 2-(2-(2-Azidoethyoxy)ethoxy)ethyl Methacrylate for High-density Click Functionalization of Polymers and Metallic Substrates [0.03%]
N-羟基琥珀酰亚胺酯引发的2-(2-(2-叠氮乙氧基)乙氧基)乙基甲基丙烯酸酯原子转移自由基聚合及其高密度“点击”官能化研究
Pingsheng Liu,Jie Song
Pingsheng Liu
The combination of atom transfer radical polymerization (ATRP) and click chemistry has created unprecedented opportunities for controlled syntheses of functional polymers. ATRP of azido-bearing methacrylate monomers (e.g. 2-(2-(2-azidoethyo...