Further Insight into the Mechanism of Poly(styrene-co-methyl methacrylate) Microsphere Formation [0.03%]
聚苯乙烯-甲基丙烯酸甲酯微球的形成机制研究
Samantha I Applin,Russell C Schmitz,Pacita I Tiemsin et al.
Samantha I Applin et al.
Polymeric microspheres have been utilized in a broad range of applications ranging from chromatographic separation techniques to analysis of air flow over aerodynamic surfaces. The preparation of microspheres from many different polymer fam...
Poly(N-acylethylenimine) copolymers containing pendant pentamethyldisiloxanyl groups. I. Synthesis [0.03%]
含 pendant 五甲基二硅氧烷基的聚（N-酰乙醇胺）共聚物．I．合成
Gangfeng Cai,Morton H Litt
Gangfeng Cai
10-(Pentamethyl disiloxanyl) decyl oxazoline (Si) was synthesized. It was copolymerized with either undecyl (U) or nonyl (N) oxazolines using methyl 4-nitrobenzenesulfonate as initiator. Two series of random poly(N-acylethylenimine) copolym...
Block copolymer composition drives function of self-assembled nanoparticles for delivery of small-molecule cargo [0.03%]
嵌段共聚物组成驱动小分子载体的自组装纳米粒子的功能性
Caitlin L Maikawa,Alex Sevit,Binhong Lin et al.
Caitlin L Maikawa et al.
Nanoparticles are useful for the delivery of small molecule therapeutics, increasing their solubility, in vivo residence time, and stability. Here, we used organocatalytic ring opening polymerization to produce amphiphilic block copolymers ...
Synthesis, physicochemical characterization, and self-assembly of linear, dibranched, and miktoarm semifluorinated triphilic polymers [0.03%]
线性、双支化和嵌段的半氟代三亲水聚合物的合成、理化表征及自组装
W B Tucker,A M McCoy,S M Fix et al.
W B Tucker et al.
Linear, dibranched and miktoarm amphiphiles containing both hydrophobic and fluorophilic moieties were synthesized and characterized in an attempt to elucidate the relationship between semi-fluorinated amphiphile structure and aggregate beh...
What happens in the dark? Assessing the temporal control of photo-mediated controlled radical polymerizations [0.03%]
黑暗中会发生什么？评估光介导的受控自由基聚合的时序控制
Neil D Dolinski,Zachariah A Page,Emre H Discekici et al.
Neil D Dolinski et al.
A signature of photo-mediated controlled polymerizations is the ability to modulate the rate of polymerization by turning the light source 'on' and 'off.' However, in many reported systems, growth can be reproducibly observed during dark pe...
Control of Cationic Nanogel PEGylation in Heterogeneous ARGET ATRP Emulsion Polymerization with PEG Macromonomers [0.03%]
PEG大分子单体在异质性ARGET ATRP乳液聚合中阳离子纳豆凝胶的PEG化控制
David S Spencer,Bryan C Luu,David W Beckman et al.
David S Spencer et al.
Crosslinked cationic nanoscale networks with hydrophobic cores are an environmentally robust alternative to self-assembled polymeric drug delivery carriers with respect to therapeutic encapsulation and stability to dilution. However, the ab...
Insights into post-polymerisation modification of bio-based unsaturated itaconate and fumarate polyesters via aza-michael addition: Understanding the effects of C=C isomerisation [0.03%]
通过aza-迈克尔加成反应探究生物基不饱和衣康酸酯和富马酸聚酯聚合后的改性：理解C=C异构化效应的影响
T J Farmer,D J Macquarrie,J W Comerford et al.
T J Farmer et al.
Development of renewable bio-based unsaturated polyesters is undergoing a renaissance, typified by the use of itaconate and fumarate monomers. The electron-deficient C=C bond found on the corresponding polyesters allows convenient post-poly...
Antimicrobial peptide modification of biomaterials using supramolecular additives [0.03%]
使用超分子添加剂修改生物材料上的抗菌肽
Sabrina Zaccaria,Ronald C van Gaal,Martijn Riool et al.
Sabrina Zaccaria et al.
Biomaterials based on non-active polymers functionalized with antimicrobial agents by covalent modification or mixing are currently regarded as high potential solutions to prevent biomaterial associated infections that are major causes of b...
Modular Synthesis of Polymers Containing 2,5-di(thiophenyl)-N-arylpyrrole [0.03%]
含2,5-二噻吩基-N-芳基吡咯聚合物的模块化合成
Tran N B Truong,Suchol Savagatrup,Intak Jeon et al.
Tran N B Truong et al.
A modular facile route has been developed to synthesize functionalized 2,5-di(thiophen-2-yl)-1-H-arylpyrroles from readily available starting materials. These units are compatible with various polymerization conditions and are versatile bui...
The effect of me-substituents of 1,4-butanediol analogues on the thermal properties of biobased polyesters [0.03%]
关于1,4-丁二醇类似物的Me取代基对生物基聚酯热性能的影响
Frits van der Klis,Rutger J I Knoop,Johannes H Bitter et al.
Frits van der Klis et al.
Biobased 1,4-butanediol analogues are used to tune the glass transition temperature and crystallization in a series of polyesters and allow for the formation of stereocomplexes. ...