Structural and Photophysical Modulation of Au(I)-Pb(II) Chains by Solvent Inclusion: A Study of Solvatopolymorphs [0.03%]
溶剂包含对Au(I)-Pb(II)链的结构和光物理性质调控：一个关于溶剂化多晶型物的研究
David Royo,Sonia Moreno,María Rodríguez-Castillo et al.
David Royo et al.
This work presents the synthesis, structural characterization, and photophysical studies of a new gold-(I)-lead-(II) heterometallic polymeric complex, [{Au-(C6F5)2}2{Pb-(S-Terpy)}] n , and its solvatopolymorphs incorporating acetone and die...
A Higher-Yielding Route for the Synthesis of Molecular Precursors to Thin Films of Gold by Atomic Layer Deposition [0.03%]
用于通过原子层沉积形成金薄膜的分子前体的合成的高产量路线
Ryan K Brown,Joseph N Bunyan,Ashi Agrawal et al.
Ryan K Brown et al.
A synthetically straightforward and high-yielding route to the series of complexes [AuMe2(dtc)] (dtc = dithiocarbamate) has been developed using dialkyl-, cyclic-dialkyl-, and diaryldithiocarbamate ligands. These compounds were screened by ...
Construction of Bimetallic and Trimetallic Aggregates with a [Y(COT)2]- Building Block: Solid-State Structures and Solution Behavior [0.03%]
基于[Y(COT)2]-构建单元的二金属和三金属聚集体的构筑及固体结构和溶液行为研究
Zheng Zhou,Aaron J Babson,Zheng Wei et al.
Zheng Zhou et al.
Several new bimetallic and trimetallic complexes containing the [Y-(COT)2]- unit in different coordination environments are synthesized and fully characterized using X-ray crystallography and NMR spectroscopy. These complexes include [K([2....
Addis Getahun,John S Wenger,Timothy C Johnstone
Addis Getahun
The characteristic electronic structure of the phosphoryl group in phosphine oxides confers great stability on the P+-O- bond, in part because of back-bonding from O-based lone pairs into the P-C antibonding orbitals. The partial nature of ...
Correction to "Half-Sandwich Ruthenium and Osmium Complexes with Hydrazinocurcuminoid-like Ligands" [0.03%]
“含类似羟基香豆素配体的半夹心型 ruth 和 osm 复合物”的勘误英文：Correction to "Half-Sandwich Ruthenium and Osmium Complexes with Hydrazinocurcuminoid-like Ligands" 中文：“含类似羟基香豆素配体的半夹心型 ruth 和 osm 复合物”的勘误
Noemi Pagliaricci,Riccardo Pettinari,Fabio Marchetti et al.
Noemi Pagliaricci et al.
[This corrects the article DOI: 10.1021/acs.organomet.5c00082.]. © 2025 The Authors. Published by American Chemical Society.
Published Erratum
Organometallics. 2025 Sep 5;44(18):2127-2128. DOI:10.1021/acs.organomet.5c00319 2025
Supramolecular perturbation of metal-metal bonding in cyclodextrin-encapsulated (NHC)Cu-FeCp(CO)2 complexes [0.03%]
包含环糊精包覆的(NHC)Cu-FeCp(CO)₂配合物中金属键的超分子扰动
Neal P Mankad,Sylvain Roland,Matthieu Sollogoub et al.
Neal P Mankad et al.
Although secondary coordination sphere effects on catalytic active sites are widely appreciated, the influence of such interactions on (hetero)binuclear active sites has not been examined comprehensively. Here, the influence of cyclodextrin...
Examination of Dianionic Diamide Ligand Structural Effects on Ti-Catalyzed Hydrohydrazination of Terminal Alkynes [0.03%]
研究二价钛催化剂上偶极链状炔烃氢氮化反应中二胺配体结构效应的影响
Partha Sarathi Karmakar,Ian A Tonks
Partha Sarathi Karmakar
Ti-catalyzed alkyne hydrohydrazination of terminal alkynes using 1,1-disubstituted hydrazines is reported. Here, a variety of bi- or tridentate dianionic diamide or diamidoamine ligated Ti=NNPh2 catalysts were examined, wherein fast and sel...
Flash Communication: Ti-Catalyzed "Interrupted" Cascading Hydroamination of 1,6- and 1,7-En-ynes [0.03%]
闪光合成：钛催化1,6-和1,7-烯炔的“中断”级联氢胺化反应
Kathryn J Rynders,Daniel N Huh,Zoe E Stuart et al.
Kathryn J Rynders et al.
Herein, we report a new hydroaminative cyclization for 1,6 and 1,7 en-ynes using a simple Ti imido precatalyst, [py2TiCl2(NPh)]2. The well-known Ti imido + alkyne [2+2] azatitanacyclobutadiene cycloadduct intermediate can be further interce...
Alkyne Carboamination with Imines Catalyzed by [py2TiCl2N(p-tol)]2 [0.03%]
[py₂TiCl₂N(p-tol)]₂催化下的炔烃与亚胺的加成氢化反应
Ross F Koby,Ian A Tonks
Ross F Koby
α,β-unsaturated imines are valuable functional groups that lack a general, reliable synthetic route. Here, we report that simple Ti imido halide precatalysts of the type [py2TiCl2N(Ar)]2 can catalyze alkyne carboamination with imines, yie...
Ti-Catalyzed Multicomponent Synthesis of Pyrroles Using Allene Coupling Partners [0.03%]
全烯偶联试剂参与的钛催化合成吡咯类化合物多组分反应
Tobias Kaper,Connor W Frye,Ian A Tonks
Tobias Kaper
There is significant interest in developing chemo- and regioselective intermolecular multicomponent syntheses of N-heterocycles, which are common motifs in pharmaceuticals and natural products. Herein, we examine the potential of allenes to...