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期刊名:Organometallics

缩写:ORGANOMETALLICS

ISSN:0276-7333

e-ISSN:1520-6041

IF/分区:2.9/Q1

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Clinical Trial Case Reports Meta-Analysis RCT Review Systematic Review
Classical Article Case Reports Clinical Study Clinical Trial Clinical Trial Protocol Comment Comparative Study Editorial Guideline Letter Meta-Analysis Multicenter Study Observational Study Randomized Controlled Trial Review Systematic Review
Matthew Allison,Pablo Caramés-Méndez,Benjamin J Hofmann et al. Matthew Allison et al.
The synthesis and characterization of 24 ruthenium(II) arene complexes of the type [(p-cym)RuCl(Fc-acac)] (where p-cym = p-cymene and Fc-acac = functionalized ferrocenyl β-diketonate ligands) are reported, including single-crystal X-ray di...
Joshua K Sailer,Jack C Sharland,John Bacsa et al. Joshua K Sailer et al.
A series of chiral bowl-shaped diruthenium(II,III) tetracarboxylate catalysts were prepared and evaluated in asymmetric cyclopropanations with donor/acceptor carbenes derived from aryldiazoacetates. The diruthenium catalysts self-assembled ...
M Angeles Alvarez,M Esther García,Daniel García-Vivó et al. M Angeles Alvarez et al.
Reactions of [MoReCp(μ-PMes*)(CO)6] with internal alkynes RC≡CR yielded the phosphapropenylidene-bridged complexes [MoReCp(μ-κ2P,C:η3-PMes*CRCR)(CO)5] (Mes* = 2,4,6-C6H2tBu3; R = CO2Me, Ph). Terminal alkynes HC≡CR1 gave mixtures of is...
Itxaso Bustos,Jose M Seco,Antonio Rodriguez-Dieguez et al. Itxaso Bustos et al.
Aliphatic diamines [(H2N(CH2)nNHR) (a-d) n = 2: R = H (a), R = CH3 (b), R = C2H5 (c), n = 3, R = H (d) or rac-2-(aminomethyl)piperidine (e)] react with [IrH(Cl){(PPh2(o-C6H4CO))2H}] in THF to afford ketoimine complexes [IrH(Cl){(PPh2(o-C6H4...
Jonathan B Eastwood,L Anders Hammarback,Thomas J Burden et al. Jonathan B Eastwood et al.
An investigation into species formed following precatalyst activation in Mn-catalyzed C-H bond functionalization reactions is reported. Time-resolved infrared spectroscopy demonstrates that light-induced CO dissociation from precatalysts [M...
Aleksa Radović,Nikki J Wolford,Hongze Li et al. Aleksa Radović et al.
Iron-catalyzed amino-oxygenation of olefins often uses discrete ligands to increase reactivity and broaden substrate scope. This work is focused on examining ligand effects on reactivity and in situ iron speciation in a system which utilize...
Alice C Phung,James C Fettinger,Philip P Power Alice C Phung
Two compounds containing a Sn(II) atom supported by a bidentate biscarborane ligand have been synthesized via salt metathesis. The synthetic procedures for (bc)Sn·THF (bc = 1,1' (ortho-carborane) (1) and K2[(bc)Sn]2 (2) involved the reacti...
Nicola Marigo,Bernd Morgenstern,Andrea Biffis et al. Nicola Marigo et al.
Palladium complexes with one N-heterocyclic carbene (NHC) and a pyridine ancillary ligand are powerful cross-coupling precatalysts. Herein, we report such complexes with a cyclic (alkyl)(amino)carbene (CAAC) ligand replacing the NHC. We fin...
Michael T Robo,Amie R Frank,Ellen Butler et al. Michael T Robo et al.
Nickel(0) catalysts of N-heterocyclic carbenes (NHCs) that are stabilized by electron-deficient alkenes possess desirable properties of air tolerance and ease of handling while also retaining high catalytic activities. Since catalyst stabil...