(CAAC)Pd(py) Catalysts Disproportionate to Pd(CAAC)2
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Palladium complexes with one N-heterocyclic carbene (NHC) and a pyridine ancillary ligand are powerful cross-coupling precatalysts. Herein, we report such complexes with a cyclic (alkyl)(amino)carbene (CAAC) ligand replacing the NHC. We find that the alleged r... ...
