Catalysis in the Service of Green Chemistry: Nobel Prize-Winning Palladium-Catalysed Cross-Couplings, Run in Water at Room Temperature: Heck, Suzuki-Miyaura and Negishi reactions carried out in the absence of organic solvents, enabled by micellar catalysis [0.03%]
绿色化学中的催化作用:诺贝尔奖得主室温下在水相中实现钯催化交叉偶联反应:无需有机溶剂的Heck、Suzuki- Miyaura和Negishi反应,可通过胶束催化的途径实现
Bruce H Lipshutz,Benjamin R Taft,Alexander R Abela et al.
Bruce H Lipshutz et al.
Palladium-catalysed cross-couplings, in particular Heck, Suzuki-Miyaura and Negishi reactions developed over three decades ago, are routinely carried out in organic solvents. However, alternative media are currently of considerable interest...