Synthesis of the unnatural amino acid N-N-(ferrocene-1-acetyl)-l-lysine: a novel organometallic nuclease [0.03%]
不对称合成不饱和脯氨酰胺衍生物及其环加成反应研究
Amanda M Gellett,Paul W Huber,Pamela J Higgins
Amanda M Gellett
Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes [0.03%]
用于过渡金属配合物的稳定双(二异丙基氨基)环丙烯亚胺(BAC)配体
Glenn Kuchenbeiser,Bruno Donnadieu,Guy Bertrand
Glenn Kuchenbeiser
Several nickel(0), palladium(II), and rhodium(I) complexes have been prepared using for the first time the stable bis(diisopropylamino)cyclopropenylidene (BAC). Based on single crystal X-ray diffraction studies and spectroscopic data, the s...
Synthesis of cyclopentadienyl ruthenium complexes bearing pendant chelating picolinates through an electrophilic precursor [0.03%]
通过亲电子前体合成带有 Pendant Chelating Picolinates 的环戊二烯钌配合物
Craig Streu,Patrick J Carroll,Rakesh K Kohli et al.
Craig Streu et al.
This note reports the facile synthesis of two ruthenium cyclopentadienyl half-sandwich complexes functionalized with coordinating alpha-picolinates. The synthetic approach involves the (eta(5)-chloromethylcyclopentadienyl)(eta(6)-benzene)ru...
Revisiting the Hirao Cross-coupling: Improved Synthesis of Aryl and Heteroaryl Phosphonates [0.03%]
重访Hirao交叉偶联反应：芳基和杂芳基磷酸酯合成的改进
Yamina Belabassi,Saeed Alzghari,Jean-Luc Montchamp
Yamina Belabassi
The palladium-catalyzed cross-coupling of dialkylphosphite with aromatic electrophiles (Hirao coupling) was re-investigated. Some limitations in terms of palladium loadings and substrate reactivity are alleviated with the use of Pd(OAc)(2) ...