Bis-oxazoline derivatives as ancillary ligands for bis-cyclometalated iridium complexes [0.03%]
双噁唑啉衍生物作为双环金属化铱复合物的辅助配体
Savannah C Kapper,Aamani Ponnekanti,Jonas Schaab et al.
Savannah C Kapper et al.
Organometallic iridium complexes with two cyclometalated ligands (ĈN) and one bis-oxazoline derived ancillary ligand (L^X), i.e. (ĈN)2Ir(L^X), are reported. The ĈN ligands are 1-phenylpyrazoline (ppz), 2-(4,6-difluorophenyl)pyridine (F2p...
Preface: VSI ICOMC22 [0.03%]
前言：VSI ICOMC22
Petr Štěpnička
Petr Štěpnička
Binding a Meridional Ligand in a Facial Geometry: A Square Peg in a Round Hole [0.03%]
绑定边缘配体的面部几何形状：一个方形柱子放在圆形孔中
Briana R Schrage,Dominick Vitale,Kimberly A Kelly et al.
Briana R Schrage et al.
The bis(pyridylimino)isoindoline (BPI) ligand is a tridentate chelate that binds to metals via a meridional coordination mode. However, when this ligand forms a complex with Re(CO)3, an almost exclusively facial moiety, the BPI ligand defor...
Microwave-Assisted Synthesis of Organometallic Rhenium (I) Pentylcarbonato Complexes: New Synthon for Carboxylato, Sulfonato and Chlorido Complexes [0.03%]
微波辅助合成有机金属铼(I)碳酸盐络合物：羧酸盐、磺酸盐和氯化物络合物的新合成子
Angela J Winstead,Khayra Alabrash,Brent V Powell et al.
Angela J Winstead et al.
Tricarbonylrhenium(I)(α-diimine) complexes are of importance because of their strong cytotoxic and fluorescence properties. Syntheses of such complexes were achieved through a two-step process. First, the pentylcarbonato complexes, fac-(CO...
(8-Amino)quinoline and (4-Amino)phenanthridine Complexes of Re(CO)3 Halides [0.03%]
Re(CO)3卤化物的(8-氨基)喹啉和(4-氨基)苯并菲啶配合物
Sanjay Gaire,Robert J Ortiz,Briana R Schrage et al.
Sanjay Gaire et al.
In this report, we present a study on the synthesis, structure, and electronics of a series of (8-amino)quinoline and (4-amino)phenanthridine complexes of Re(CO)3X, where X = Cl and Br. In all cases, the (amino)heterocycles bind as bidentat...
Synthesis and Reactivity Studies of a [Cp*Rh] Complex Supported by a Methylene-Bridged Hybrid Phosphine-Imine Ligand [0.03%]
由亚甲基桥连的杂化膦-亚胺配体稳定的[Cp*Rh]配合物的合成及其反应性能研究
Julie A Hopkins,Davide Lionetti,Victor W Day et al.
Julie A Hopkins et al.
[Cp*Rh] complexes (Cp* = η 5-pentamethylcyclopentadienyl) supported by bidentate chelating ligands are useful in studies of redox chemistry and catalysis, but little information is available for derivatives bearing "hybrid" [P,N] chelates....
Synthesis, structure, photophysical and electrochemical properties of Ru(TFA)(CO)(PPh3)2(L) (L=2-phenylpyridine, 2- p-tolylpyridine) and Ru(CO)(PPhMe2)2(L)(L') (L= TFA, H) (L'= bipyridine, L'= 4,4'-dimethylbipyridine) relationships between ancillary ligand structure and luminescent properties [0.03%]
Ru(TFA)(CO)(PPh3)2(L) (L=2-苯基吡啶，2- 对甲基苯基吡啶)和 Ru(CO)(PPhMe2)2(L)(L')(L= TFA，H)(L'= bpy，4,4'-二甲基bpy) 配体结构与发光性质关系研究
Shyam Pohkrel,Dan Decato,Edward Rosenberg et al.
Shyam Pohkrel et al.
The synthesis, structure and photophysical properties of the complexes [Ru[(CO)(TFA) (PPh3)2(L)] [(L = ppy = 2-phenylpyridine, (1a); L = 2-(p-tolyl)pyridine] (1b), are reported. The complexes were characterized by UV-VIS, IR and NMR and by ...
Anticancer activity studies of novel metal complexes of ligands derived from polycyclic aromatic compound via greener route [0.03%]
通过绿色途径合成多环芳香化合物衍生物金属配合物的抗肿瘤研究
Mahantesh Kumbar,Sangamesh A Patil,Shivakumar S Toragalmath et al.
Mahantesh Kumbar et al.
Methoxy and tert-butyl substituted carboxamide, carboxylic acid and hydrazone Schiff base groups have been assembled into our newly designed fluorenone based ligands and prepared coordination compounds of some first row transition metals an...
K Chanawanno,T S Blesener,B R Schrage et al.
K Chanawanno et al.
This report presents the synthesis and characterization of mono- and bis(amino acid ester) ferrocene complexes generated using a sulfonamide linking strategy as an alternative to the more heavily explored amide linking strategy. These compo...
Tuning photophysical properties with ancillary ligands in Ru(II) mono-diimine complexes [0.03%]
利用辅助配体调节Ru(II)单双二胺配合物的光物理性质
Ayesha Sharmin,Reuben C Darlington,Kenneth I Hardcastle et al.
Ayesha Sharmin et al.
The series of complexes [XRu(CO)(L-L)(L')2][PF6] (X = H, TFA, Cl; L-L = 2,2'-bipyridyl, 1,10-phenanthroline, 5-amino-1,10-phenanthroline and 4,4'-dicarboxylic-2,2'-bipyridyl; L'2 = 2PPh3, Ph2 PC2H4PPh2, Ph2PCH═CHPPh2) have been synthesized...