Anion- and Water-facilitated Oxidative Carbon-Carbon Bond Cleavage and Diketonate Carboxylation in Cu(II) Chlorodiketonate Complexes [0.03%]
铜(II)氯代 diketonato络合物中阴离子和水促进的氧化碳碳键断裂和 diketonato羧基化反应
Josiah G D Elsberg,Tomasz Borowski,Eric W Reinheimer et al.
Josiah G D Elsberg et al.
The O2-dependent carbon-carbon (C-C) bond cleavage reactions of the mononuclear Cu(II) chlorodiketonate complexes [(6-Ph2TPA)Cu(PhC(O)CClC(O)Ph)]ClO4 (1-ClO 4 ) and [(bpy)Cu(PhC(O)CClC(O)Ph)(ClO4)] (3-ClO 4 ) have been further examined in t...
Alejandro Bugarin,Siddappa A Patil,Ryan Q Tran et al.
Alejandro Bugarin et al.
In this manuscript, literature reports on mono- and di-halogen (F, Cl, Br, and I) substituted at positions 4 or/and 4,5 imidazol-2-ylidene (NHC) metal complexes are discussed: particularly, their structural diversity with various metals (gr...
Stephen R Isbel,Siddappa A Patil,Alejandro Bugarin
Stephen R Isbel
NHCs (N-heterocyclic carbenes) are generally used as organic ligands that can coordinate with metal ions like silver to form stable complexes. These complexes have shown enhanced antimicrobial properties compared to silver alone. This docum...
A Comparison of In Vitro Studies between Cobalt(III) and Copper(II) Complexes with Thiosemicarbazone Ligands to Treat Triple Negative Breast Cancer [0.03%]
钴（III）和铜（II）与噻半卡腙配体的配合物用于治疗三阴性乳腺癌的体外研究比较
Duaa R Alajroush,Chloe B Smith,Brittney F Anderson et al.
Duaa R Alajroush et al.
Metal complexes have gained significant attention as potential anti-cancer agents. The anti-cancer activity of [Co(phen)2(MeATSC)](NO3)3•1.5H2O•C2H5OH 1 (where phen = 1,10-phenanthroline and MeATSC = 9-anthraldehyde-N(4)-methylthiosemicar...
pH-dependent concatenation of an inorganic complex results in solid state helix formation [0.03%]
pH依赖的无机复合物连接形成固态螺旋结构
Emily Hoffer,Brian P Niebuhr,Kristof Pota et al.
Emily Hoffer et al.
Growth of the library of tetraaza macrocyclic pyridinophane ligands is a result of the potential to treat neurodegenerative diseases by binding unregulated redox active metal-ions, scavenging radicals, and reducing oxidative stress. As part...
Sustaining a legacy in STEM the Prof. Tara Prasad Dasgupta way: The role of a mentor in our lives [0.03%]
以Tara Prasad Dasgupta教授的方式在STEM领域中延续遗产：导师在我们生命中的作用
Alvin A Holder
Alvin A Holder
A mentoring relationship is a close, individualized relationship that develops over time between a graduate student and his/her adviser, and that includes both caring and guidance. Although there is a connection between mentors and advisers...
Exploring six-coordinate germanium(IV)-diketonate complexes as anticancer agents [0.03%]
六配位的锗（IV）-二酮配合物作为抗肿瘤药物的研究
Randall T Mertens,Sean Parkin,Samuel G Awuah
Randall T Mertens
Cancer remains one of the leading causes of death worldwide and despite several attempts using chemotherapy to combat the deadly disease, toxic side effects and drug resistance temper efficacy [1]. Thus, drugs with potentially new mechanism...
Increasing reactivity by incorporating π-acceptor ligands into coordinatively unsaturated thiolate-ligated iron(II) complexes [0.03%]
通过引入π-配体使不饱和铁(ii)硫醇盐配合物的反应活性增强
Santiago Toledo,Penny Chaau Yan Poon,Morgan Gleaves et al.
Santiago Toledo et al.
Reported herein is the structural, spectroscopic, redox, and reactivity properties of a series of iron complexes containing both a π-donating thiolate, and π-accepting N-heterocycles in the coordination sphere, in which we systematically ...
Solid-state luminescence properties, Hirshfeld surface analysis and DFT calculations of mononuclear lanthanide complexes (Ln = EuIII, GdIII, TbIII, DyIII) containing 4'-phenyl-2,2':6',2″-terpyridine [0.03%]
含4'-苯基-2,2':6',2"-三吡啶配体单核稀土配合物的固态发光性质、Hirshfeld 表面分析及 DFT 计算（Ln = EuIII，GdIII，TbIII，DyIII）
Li Ling Cai,Ya Tao Hu,Yan Li et al.
Li Ling Cai et al.
Four mononuclear lanthanide complexes containing 4'-phenyl-2,2':6',2″-terpyridine (ptpy), [Ln(NO3)3(ptpy) (H2O)] (Ln = Eu (1), Gd (2), Tb (3), Dy (4)), were solvothermally synthesized and characterized via elemental analysis, infrared spec...
Structural, Spectroscopic, Electrochemical, and Magnetic Properties for Manganese(II) Triazamacrocyclic Complexes [0.03%]
锰(II)三氮杂大环类配合物的结构、谱学、电化学和磁性性质研究
Atanu Banerjee,Azam S Tolla,Slavica Stjepanovic et al.
Atanu Banerjee et al.
We report the synthesis of [Mn(tacud)2](OTf)2 (1) (tacud = 1,4,8-triazacycloundecane), [Mn(tacd)2](OTf)2 (2) (tacd = 1,4,7-triazacyclodecane), and [Mn(tacn)2](OTf)2 (3) (tacn = 1,4,7-triazacyclononane). Electrochemical measurements on the M...