Chenxing Guo,Adam C Sedgwick,Takehiro Hirao et al.
Chenxing Guo et al.
Since as early as 1867, molecular sensors have been recognized as being intelligent "devices" capable of addressing a variety of issues related to our environment and health (e.g., the detection of toxic pollutants or disease-related biomar...
Coordination chemistry of the CuZ site in nitrous oxide reductase and its synthetic mimics [0.03%]
一氧化氮还原酶中的铜锌位点的配位化学及其合成模拟物中的铜锌位点的配位化学
Suresh C Rathnayaka,Neal P Mankad
Suresh C Rathnayaka
Atmospheric nitrous oxide (N2O) has garnered significant attention recently due to its dual roles as an ozone depletion agent and a potent greenhouse gas. Anthropogenic N2O emissions occur primarily through agricultural disruption of nitrog...
A historical perspective on porphyrin-based metal-organic frameworks and their applications [0.03%]
基于卟啉的金属有机框架的历史及应用展望
Xuan Zhang,Megan C Wasson,Mohsen Shayan et al.
Xuan Zhang et al.
Porphyrins are important molecules widely found in nature in the form of enzyme active sites and visible light absorption units. Recent interest in using these functional molecules as building blocks for the construction of metal-organic fr...
Zero-, one-, two- and three-dimensional supramolecular architectures sustained by Se…O chalcogen bonding: A crystallographic survey [0.03%]
由Se…O环金属键维持的零、一、二和三维超分子体系结构:晶体学调查
Edward R T Tiekink
Edward R T Tiekink
The Cambridge Structural Database was evaluated for crystals containing Se…O chalcogen bonding interactions. These secondary bonding interactions are found to operate independently of complementary intermolecular interactions in about 13% ...
Fluorescent probes based on nucleophilic aromatic substitution reactions for reactive sulfur and selenium species: Recent progress, applications, and design strategies [0.03%]
基于亲核芳香取代反应的荧光探针在活性硫和硒物种中的应用: recent progress, applications, 和设计策略
Yuning Liu,Yanan Yu,Qingyu Zhao et al.
Yuning Liu et al.
Reactive sulfur species (RSS) and reactive selenium species (RSeS) are important substances for the maintenance of physiological balance. Imbalance of RSS and RSeS is closely related to a series of human diseases, so it is considered to be ...
Recent advances in process engineering and upcoming applications of metal-organic frameworks [0.03%]
过程工程的最新进展以及金属有机框架的即将应用
UnJin Ryu,Seohyeon Jee,Purna Chandra Rao et al.
UnJin Ryu et al.
Progress in metal-organic frameworks (MOFs) has advanced from fundamental chemistry to engineering processes and applications, resulting in new industrial opportunities. The unique features of MOFs, such as their permanent porosity, high su...
Olga P Ajsuvakova,Alexey A Tinkov,Michael Aschner et al.
Olga P Ajsuvakova et al.
The present study addresses existing data on the affinity and conjugation of sulfhydryl (thiol; -SH) groups of low- and high-molecular-weight biological ligands with mercury (Hg). The consequences of these interactions with special emphasis...
Reactivity of terminal imido complexes of group 4-6 metals: stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules [0.03%]
4-6族金属末端亚胺配合物的反应性:涉及与不饱和有机分子环加成的定量及催化反应
Kento Kawakita,Yuya Kakiuchi,Hayato Tsurugi et al.
Kento Kawakita et al.
Imido complexes of early transition metals are key intermediates in the synthesis of many nitrogen-containing organic compounds. The metal-nitrogen double bond of the imido moiety undergoes [2+2] cycloaddition reactions with various unsatur...
Engineering of Nanoscale Coordination Polymers with Biomolecules for Advanced Applications [0.03%]
工程设计纳米尺度的生物分子配位聚合物以实现高级应用
Jing Mu,Liangcan He,Peng Huang et al.
Jing Mu et al.
Nanoscale coordination polymers (NCPs) have shown extraordinary advantages in various research areas due to their structural diversity and multifunctionality. Recently, integration of biomolecules with NCPs received extensive attention and ...
Peter Junk,R Bruce King
Peter Junk