Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes [0.03%]
手性铑(III)催化剂对未活化烯烃马尔科夫尼科夫氢硼化的面对映选择性控制
James R Smith,Beatrice S L Collins,Matthew J Hesse et al.
James R Smith et al.
Using a novel sp2-sp3 hybridized diboron reagent and water as a proton source, a broad range of alkenes undergo hydroboration to provide secondary boronic esters with high regio- and enantiocontrol.
Enantiospecific Synthesis of ortho-Substituted Benzylic Boronic Esters by a 1,2-Metalate Rearrangement/1,3-Borotropic Shift Sequence [0.03%]
对映选择性合成邻位取代苯甲基硼酸酯：通过1,2-阴离子迁移/1,3-硼氧转移异构化序列实现
Stefan Aichhorn,Raphael Bigler,Eddie L Myers et al.
Stefan Aichhorn et al.
The use of enantioenriched α-substituted benzylamines gave the corresponding secondary boronic esters with high ee.
Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds [0.03%]
secondary 和 tertiary 卤代烃与芳香化合物的对映选择性偶联反应的研究进展
Marcin Odachowski,Amadeu Bonet,Stephanie Essafi et al.
Marcin Odachowski et al.
The stereospecific cross-coupling of secondary boronic esters with sp(2) electrophiles (Suzuki-Miyaura reaction) is a long-standing problem in synthesis, but progress has been achieved in specific cases using palladium catalysis.
Synthesis of Enantioenriched Alkylfluorides by the Fluorination of Boronate Complexes [0.03%]
手性富集的烷基氟化物的硼酸酯复分解合成法
Christopher Sandford,Ramesh Rasappan,Varinder K Aggarwal
Christopher Sandford
The enantiospecific conversion of chiral secondary boronic esters into alkylfluorides is reported. Boronate complexes derived from boronic esters and PhLi were used as nucleophiles, with Selectfluor II as the electrophilic fluorinating agent, to afford alkylfluorides in short reaction times.
Structure and reactivity of boron-ate complexes derived from primary and secondary boronic esters [0.03%]
来自一级和二级硼酸酯的硼-酸盐复合物的结构与反应性研究
Kathryn Feeney,Guillaume Berionni,Herbert Mayr et al.
Kathryn Feeney et al.
Boron-ate complexes derived from primary and secondary boronic esters and aryllithiums have been isolated, and the kinetics of their reactions with carbenium ions studied.
Ate complexes of secondary boronic esters as chiral organometallic-type nucleophiles for asymmetric synthesis [0.03%]
手性杂环硼酯亚胺金属配合物作为不对称合成的手性亲核试剂
Robin Larouche-Gauthier,Tim G Elford,Varinder K Aggarwal
Robin Larouche-Gauthier
The addition of an aryllithium reagent to a secondary boronic ester leads to an intermediate boron-ate complex that behaves as a chiral nucleophile, reacting with a broad range of electrophiles with inversion of stereochemistry. Depending o...
Cross coupling reactions of chiral secondary organoboronic esters with retention of configuration [0.03%]
对映选择性交叉偶联反应中构型的保持
Daisuke Imao,Ben W Glasspoole,Véronique S Laberge et al.
Daisuke Imao et al.
We report the first example of a coupling reaction of chiral secondary boronic esters generated by the hydroboration of vinyl arenes.
Rh-catalyzed enantioselective hydrogenation of vinyl boronates for the construction of secondary boronic esters [0.03%]
铑催化烯烃硼酸酯的不对称氢化反应合成二级光学纯硼酸酯化合物
Wesley J Moran,James P Morken
Wesley J Moran
[reaction: see text] Rh-catalyzed hydrogenation of prochiral vinyl boronates occurs in an enantioselective fashion in the presence of the chiral ligand Walphos 1. This transformation provides access to chiral secondary organoboronates that ...
ChemInform Abstract: Preparation of Chiral Secondary Boronic Esters via Copper-Catalyzed Enantioselective Conjugate Reduction of β-Boronyl-β-alkyl α,β-Unsaturated Esters. [0.03%]
Jinyue Ding; Dennis G. Hall
Jinyue Ding; Dennis G. Hall
Imao, D.; Glasspoole, B.; Laberge et al.
Imao et al.
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