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Organic letters. 2006 May 25;8(11):2413-5. doi: 10.1021/ol060735u Q15.02025

Rh-catalyzed enantioselective hydrogenation of vinyl boronates for the construction of secondary boronic esters

铑催化烯烃硼酸酯的不对称氢化反应合成二级光学纯硼酸酯化合物 翻译改进

Wesley J Moran  1, James P Morken

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  • 1 Department of Chemistry, Venable and Kenan Laboratories, The University of North Carolina at Chapel Hill, 27599-3290, USA.

    • DOI: 10.1021/ol060735u PMID: 16706539

    摘要 Ai翻译

    [reaction: see text] Rh-catalyzed hydrogenation of prochiral vinyl boronates occurs in an enantioselective fashion in the presence of the chiral ligand Walphos 1. This transformation provides access to chiral secondary organoboronates that are not available from alkene hydroboration reactions. The chiral reaction products should be useful in organic synthesis, and preliminary experiments suggest that they may participate in one-pot amination and homologation reactions.

    Keywords：vinyl boronates; secondary boronic esters

    关键词：Rh催化enantioselective氢化; 乙烯硼酸酯; 二级硼酸酯

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    期刊名：Organic letters

    缩写：ORG LETT

    ISSN：1523-7060

    e-ISSN：1523-7052

    IF/分区：5.0/Q1

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    Rh-catalyzed enantioselective hydrogenation of vinyl boronates for the construction of secondary boronic esters