N, N'-Diaryldihydrophenazines as a Sustainable and Cost-Effective Alternative to Precious Metal Complexes in the Photoredox-Catalyzed Alkylation of Aryl Alkyl Ketones [0.03%]
N,N'- diaryldihydrophenazines作为贵重金属配合物的可持续且经济有效的替代品，在光氧化还原催化芳基烷基酮的烷基化中的应用
Dmitry A Dulov,Alexey V Bogdanov,Sergey G Dorofeev et al.
Dmitry A Dulov et al.
An inexpensive and highly efficient metal-free alternative to commonly used Ru- and Ir-based catalysts was proposed. It was shown that the new 2,7-di-tert-butyl-5,10-bis(4-trifluoromethylphenyl)-5,10-dihydrophenazine outcompeted the iridium...
Sulfinyl-aminotroponiminates: alkali- (Li, Na, K) and heavy-metal (Bi) complexes [0.03%]
亚磺酰氨基氨叶立德：碱金属（锂、钠、钾）和重金属（铋）配合物
Anna Hanft,Dennis Rottschäfer,Victoria Müller et al.
Anna Hanft et al.
The installation of electron-withdrawing functional groups at the carbocyclic backbone of aminotroponiminate (ATI) ligands is a versatile method for influencing the electronic properties of the resulting ATI complexes. We report here Li, Na...
Precious metal complexes of bis(pyridyl)allenes: synthesis and catalytic and medicinal applications [0.03%]
双吡啶亚乙基贵重金属配合物：合成及催化和医药应用
Hanna K Maliszewska,Carla Arnau Del Valle,Ying Xia et al.
Hanna K Maliszewska et al.
The incorporation of donor-type substituents on the allene core opens up the possibility of coordination complexes in which the metal is bonded to the donor groups, with or without interaction with the double bond system. Despite the challe...
Enhancing NMR Quantum Computation by Exploring Heavy Metal Complexes as Multiqubit Systems: A Theoretical Investigation [0.03%]
基于重金属配合物的多量子位系统的NMR量子计算理论研究
Jéssica Boreli Dos Reis Lino,Stephan P A Sauer,Teodorico Castro Ramalho
Jéssica Boreli Dos Reis Lino
Assembled together with the most common qubits used in nuclear resonance magnetic (NMR) quantum computation experiments, spin-1/2 nuclei, such as 113Cd, 199Hg, 125Te, and 77Se, could leverage the prospective scalable quantum computer archit...
Synthesis and Photophysical Properties of T-Shaped Coinage-Metal Complexes [0.03%]
T形走马灯型铜簇的合成及光物理性质研究
George Kleinhans,Alan K-W Chan,Ming-Yi Leung et al.
George Kleinhans et al.
The photophysical properties of a series of T-shaped coinage d10 metal complexes, supported by a bis(mesoionic carbene)carbazolide (CNC) pincer ligand, are explored. The series includes a rare new example of a tridentate T-shaped AgI comple...
Density Functional Study of H-D Coupling Constants in Heavy Metal Dihydrogen and Dihydride Complexes: The Role of Geometry, Spin-Orbit Coupling, and Gradient Corrections in the Exchange-Correlation Kernel [0.03%]
重金属二氢和二氢化物配合物中H-D偶合常数的密度泛函研究：几何结构、自旋-轨道耦合及交换相关核梯度校正的作用
Boris Le Guennic,Serguei Patchkovskii,Jochen Autschbach
Boris Le Guennic
The H-D nuclear spin-spin coupling constants J(H-D) of 14 heavy transition-metal dihydrogen and dihydride complexes were calculated with density functional theory using the "zeroth-order regular approximation" (ZORA) for the one-electron op...
[Ultraviolet-visible spectrometry analysis of insoluble xanthate heavy metal complexes] [0.03%]
[不可溶性黄药金属复合物的紫外可见光谱分析]
Bo Qiu,Jin-Feng Liu,Yao-Chi Liu et al.
Bo Qiu et al.
A ultraviolet-visible spectrometry method of determining insoluble xanthate heavy metal complexes in flotation wastewater was the first time to be put forward. In this work, the changes of ultraviolet-visible spectra of xanthate solution af...
Yellow/orange emissive heavy-metal complexes as phosphors in monochromatic and white organic light-emitting devices [0.03%]
含重金属复合物黄/橙发光体在单色及白有机电致发光器件中的应用研究
Cong Fan,Chuluo Yang
Cong Fan
Owing to the electron spin-orbit coupling (SOC) and fast intersystem crossing (ISC), heavy-metal complexes (such as iridium(III), platinum(II) and osmium(II) complexes, etc.) are phosphorescent emitters at room temperature. Since 1998, heav...
Qiang Zhao,Chunhui Huang,Fuyou Li
Qiang Zhao
The application of phosphorescent heavy-metal complexes with d(6), d(8) and d(10) electron configurations for bioimaging is a new and promising research field and has been attracting increasing interest. In this critical review, we systemat...
Qiang Zhao,Fuyou Li,Chunhui Huang
Qiang Zhao
Recently, the use of phosphorescent heavy-metal complexes as chemosensors has attracted increasing interest due to their advantageous photophysical properties. This critical review focuses on the design principles and the recent development...
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