Terrance J Hadlington
Terrance J Hadlington
Since the dawn of organometallic chemistry, transition metal complexes of unsaturated organic molecules, namely π-complexes, have remained a central focus: our thorough understanding of the electronic nature of such species, and their impo...
Britta Glowacki-Pallach,Michael Lutter,Dieter Schollmeyer et al.
Britta Glowacki-Pallach et al.
The syntheses of the racemic amino alcohol rac-N(CH2CMe2OH)(CMe2CH2OH)(CH2CHMeOH) (L22'1*H3, 2) and its representative N(CH2CMe2OH)(CMe2CH2OH)(CH2C(R)HMeOH) (L22'1RH3, 3) with the stereogenic carbon center being R-configured are reported. A...
Britta Glowacki,Michael Lutter,Hazem Alnasr et al.
Britta Glowacki et al.
The syntheses of the novel amino alcohols NH(CH2CMe2OH)2(CMe2CH2OH) (1) and N(CH2CMe2OH)(CMe2CH2OH)(CH2CH2OH) (2) as well as the stannatranes N(CH2CMe2O)(CMe2CH2O)(CH2CH2O)SnX (3, X = Ot-Bu), N(CH2CMe2O)3SnOC(O)C9H13O2, 4, and germatranes N...
Group 10-group 14 metal complexes [E-TM](IV): the role of the group 14 site as an L, X and Z-type ligand [0.03%]
第10族-第14族金属配合物[E-TM](IV): 第14族位点作为L、X和Z型配体的作用
Erik Wächtler,Robert Gericke,Erica Brendler et al.
Erik Wächtler et al.
A series of new complexes of a general motif [R2E(μ-N,S)2TM-L] (E: metalloid group 14 element; TM: group 10 metal; R: Cl, Ph, pyS, OH, (N,N,O)-chelating ligands; N,S: 1-methylimidazole-2-thiolate (methimazolyl, mt(-)), pyridine-2-thiolate ...
Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E-H Bonds by a Bis(boryl)stannylene [0.03%]
用于富勒烯脱氢的阴离子自由基𬭩催化剂：合成，结构和反应性研究
Andrey V Protchenko,Joshua I Bates,Liban M A Saleh et al.
Andrey V Protchenko et al.
By employing strongly σ-donating boryl ancillary ligands, the oxidative addition of H2 to a single site Sn(II) system has been achieved for the first time, generating (boryl)2SnH2. Similar chemistry can also be achieved for protic and hydr...
Synthesis, structures, and electronic properties of triple- and double-decker ruthenocenes incorporated by a group 14 metallole dianion ligand [0.03%]
包含第14族金属杂环二阴离子配体的三重和双重美勒西稀类配合物的合成、结构及电子性质研究
Takuya Kuwabara,Jing-Dong Guo,Shigeru Nagase et al.
Takuya Kuwabara et al.
The neutral triple-decker ruthenocenes and anionic ruthenocene bearing a stannole dianion were successfully synthesized by the reactions of dilithiostannoles with [Cp*RuCl]4. This is the first example of a transition-metal complex bearing a...
Thermally Stable Heterobinuclear Bivalent Group 14 Metal Complexes Ar2 M-Sn[1,8-(NR)2 C10 H6 ] (M=Ge, Sn; Ar=2,6-(Me2 N)2 C6 H3 ; R=CH2 tBu) [0.03%]
稳定的杂二核+2价第14族金属配合物Ar₂M-Sn[1,8-(NR)₂C₁₀H₆] (M=Ge, Sn; Ar=2,6-(Me₂N)₂C₆H₃; R=CH₂tBu)
C Drost,P B Hitchcock,M F Lappert
C Drost
The first thermally robust Ge(II) -Sn(II) compound 1 and the structurally characterized Sn(II) -Sn(II) analogue 2, which maintain their structural integrity in solution, were obtained by treating MAr2 (M=Ge, Sn; Ar=2,6-(Me2 N)2 C6 H3 ) with...
Overcoming NHCs neutrality: installing tetracarbenes on group 13 and 14 metals [0.03%]
打破NHCs的中性概念：在第13和14族金属上安装四卡宾
S Alan Cramer,Forrest L Sturgill,Preeti P Chandrachud et al.
S Alan Cramer et al.
The first tetracarbene complexes of group 13 and 14 metals have been synthesized by employing dianionic macrocyclic tetracarbene ligands. The tin, indium, and aluminium tetracarbene complexes are structurally analogous to their porphyrin or...
Oxidative addition versus substitution reactions of group 14 dialkylamino metalylenes with pentafluoropyridine [0.03%]
含氮烯基金属化合物与五氟吡啶的氧化加成和取代反应研究
Prinson P Samuel,Amit Pratap Singh,Sankaranarayana Pillai Sarish et al.
Prinson P Samuel et al.
Dialkylamino compounds of group 14 elements (Si, Ge, Sn) in the +2 oxidation state supported by benzamidinate ligands were synthesized and treated with pentafluoropyridine. Two different modes of reactivity were observed, depending on the m...
Expanding the coordination chemistry of donor-stabilized group-14 metalenes [0.03%]
供体稳定的第14族金属烯的配位化学研究取得进展
Javier A Cabeza,Pablo García-Álvarez,Diego Polo
Javier A Cabeza
The transformation of an amidinate germylene, equipped with just one accessible lone pair of electrons on the Ge atom, into a bidentate 4-electron donor κ(2)Ge,N-ligand, has been achieved for the first time, opening new doors to the non-ca...
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