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Dalton transactions (Cambridge, England : 2003). 2014 Jun 7;43(21):7687-90. doi: 10.1039/c4dt00990h Q13.52024

Overcoming NHCs neutrality: installing tetracarbenes on group 13 and 14 metals

打破NHCs的中性概念:在第13和14族金属上安装四卡宾 翻译改进

S Alan Cramer  1, Forrest L Sturgill, Preeti P Chandrachud, David M Jenkins

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  • 1 Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37996-1600, USA. jenkins@ion.chem.utk.edu.
  • DOI: 10.1039/c4dt00990h PMID: 24733683

    摘要 Ai翻译

    The first tetracarbene complexes of group 13 and 14 metals have been synthesized by employing dianionic macrocyclic tetracarbene ligands. The tin, indium, and aluminium tetracarbene complexes are structurally analogous to their porphyrin or salen analogues. The aluminium complex is the first example of multiple NHCs bound to this metal centre.

    Keywords:tetracarbenes; group 13 metals; group 14 metals

    Copyright © Dalton transactions (Cambridge, England : 2003). 中文内容为AI机器翻译,仅供参考!

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    期刊名:Dalton transactions

    缩写:DALTON T

    ISSN:1477-9226

    e-ISSN:1477-9234

    IF/分区:3.5/Q1

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    Overcoming NHCs neutrality: installing tetracarbenes on group 13 and 14 metals