The first tetracarbene complexes of group 13 and 14 metals have been synthesized by employing dianionic macrocyclic tetracarbene ligands. The tin, indium, and aluminium tetracarbene complexes are structurally analogous to their porphyrin or salen analogues. The aluminium complex is the first example of multiple NHCs bound to this metal centre.
Dalton transactions (Cambridge, England : 2003). 2014 Jun 7;43(21):7687-90. doi: 10.1039/c4dt00990h Q13.52024
Overcoming NHCs neutrality: installing tetracarbenes on group 13 and 14 metals
打破NHCs的中性概念:在第13和14族金属上安装四卡宾 翻译改进
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DOI: 10.1039/c4dt00990h PMID: 24733683
摘要 Ai翻译
Keywords:tetracarbenes; group 13 metals; group 14 metals
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