Comparing photodegradation model systems: measuring bimolecular rate constants between photochemically produced reactive intermediates and organic contaminants [0.03%]
光降解模型体系的比较：测量光化学产生的反应中间体与有机污染物之间的双分子速率常数
Luana de Brito Anton,Andrea I Silverman,Jennifer N Apell
Luana de Brito Anton
Predicting the environmental fate of anthropogenic chemicals remains a top priority for scientists and regulators; however, these efforts are hindered by the complexity of environmental systems. For example, in aquatic photodegradation, mul...
Pressure, Temperature, and Water Vapor Dependencies of the Bimolecular Rate Coefficients for the Reaction OH + NO + M → HONO + M [0.03%]
压力、温度和水蒸气对羟基自由基与一氧化氮反应双分子速率常数的影响
Megan Woods,Frank A F Winiberg,Charles R Markus et al.
Megan Woods et al.
OH+NO is an important termolecular association reaction in the troposphere and stratosphere that influences the atmospheric ozone budget. In this study, rate coefficients for the reaction of OH + NO + M → HONO + M were measured under condi...
Bimolecular Rate Constants for FAD-Dependent Glucose Dehydrogenase from Aspergillus terreus and Organic Electron Acceptors [0.03%]
基于FAD的枯草芽孢杆菌葡萄糖脱氢酶与有机电子受体的双分子反应速率常数
Nozomu Tsuruoka,Takuya Sadakane,Rika Hayashi et al.
Nozomu Tsuruoka et al.
The flavin adenine dinucleotide-dependent glucose dehydrogenase (FAD-GDH) from Aspergillus species require suitable redox mediators to transfer electrons from the enzyme to the electrode surface for the application of bioelectrical devices....
Bimolecular rate constant and product branching ratio measurements for the reaction of C2H with ethene and propene at 79 K [0.03%]
在79K下C2H与乙烯和丙烯反应的双分子速率常数和产物支链比的测量
Jordy Bouwman,Fabien Goulay,Stephen R Leone et al.
Jordy Bouwman et al.
The reactions of the ethynyl radical (C(2)H) with ethene (C(2)H(4)) and propene (C(3)H(6)) are studied under low temperature conditions (79 K) in a pulsed Laval nozzle apparatus. Ethynyl radicals are formed by 193 nm photolysis of acetylene...
Sweeping capillary electrophoresis: a non-stopped-flow method for measuring bimolecular rate constant of complex formation between protein and DNA [0.03%]
用于测定蛋白质和DNA复合物缔合反应双分子速率常数的扫动毛细管电泳法研究
Victor Okhonin,Maxim Berezovski,Sergey N Krylov
Victor Okhonin
We introduce sweeping capillary electrophoresis (SweepCE), a non-stopped-flow method for directly measuring the bimolecular rate constant of complex formation, and demonstrate its use for studying protein-DNA interaction. The capillary is p...
Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate [0.03%]
离子液体中模拟催化周转频率：在1-丁基-3-甲基咪唑六氟磷酸盐中确定[（C6H6）Cr（CO）2Solv]的双分子速率常数以置换溶剂
Konrad Swiderski,Andrew McLean,Charles M Gordon et al.
Konrad Swiderski et al.
The bimolecular rate constant for solvent displacement, k(2), from [(C(6)H(6))Cr(CO)(2)Solv] by an incoming ligand has been determined in the room temperature ionic liquid, [bmim][PF(6)], and is compared to that for the same process in cycl...
Andrew J McLean,Mark J Muldoon,Charles M Gordon et al.
Andrew J McLean et al.
The temperature dependence of the bimolecular rate constants for a diffusion controlled reaction involving neutral reactants have been directly determined in five commonly used ionic liquids over the temperature range 5-70 degrees C.
Kinetics of Formation of Ca(2+) Complexes of Acyclic and Macrocyclic Poly(amino carboxylate) Ligands: Bimolecular Rate Constants for the Fully-Deprotonated Ligands Reveal the Effect of Macrocyclic Ligand Constraints on the Rate-Determining Conversions of Rapidly-Formed Intermediates to the Final Complexes [0.03%]
无环和大环多氨基羧酸配体的钙离子配合物形成反应动力学：完全去质子化配体的双分子速率常数揭示了大环配体约束对快速形成的中间体最终配合物转化的控制作用
Shu Ling Wu,Kenneth A. Johnson,William DeW. Horrocks Jr
Shu Ling Wu
The apparent bimolecular rate constants, k(1) (M(-)(1) s(-)(1)), for the formation of Ca(2+) complexes of a series of acyclic (edta, egta, cdta) and macrocyclic (dota, teta, do3a) poly(amino carboxylate) ligands were determined in the pH ra...
A comparison of the affinity, phosphorylation and bimolecular rate constants of cholinesterases by organophosphates [0.03%]
有机磷化合物与胆碱酯酶亲和力、磷酸化及双分子反应速率常数的比较研究
K N Mehrotra,A Phokela
K N Mehrotra