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Chemical communications (Cambridge, England). 2004 Mar 7:(5):590-1. doi: 10.1039/b315781d Q24.22025

Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate

离子液体中模拟催化周转频率:在1-丁基-3-甲基咪唑六氟磷酸盐中确定[(C6H6)Cr(CO)2Solv]的双分子速率常数以置换溶剂 翻译改进

Konrad Swiderski  1, Andrew McLean, Charles M Gordon, D H Vaughan

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  • 1 Department of Chemistry & Chemical Engineering, University of Paisley, Paisley, Scotland, UK PA1 2BE.
  • DOI: 10.1039/b315781d PMID: 14973622

    摘要 Ai翻译

    The bimolecular rate constant for solvent displacement, k(2), from [(C(6)H(6))Cr(CO)(2)Solv] by an incoming ligand has been determined in the room temperature ionic liquid, [bmim][PF(6)], and is compared to that for the same process in cyclohexane and dichloroethane. 点击完成人机验证后继续浏览
    Copyright © Chemical communications (Cambridge, England). 中文内容为AI机器翻译,仅供参考!

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    期刊名:Chemical communications

    缩写:CHEM COMMUN

    ISSN:1359-7345

    e-ISSN:1364-548X

    IF/分区:4.2/Q2

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    Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate