Molecules (Basel, Switzerland). 2022 Nov 26;27(23):8256. doi: 10.3390/molecules27238256 Q24.22024

Synthetic Exploration of Bis(phenolate) Aza-BODIPYs and Heavier Group 13 Chelates

双(酚盐)氮杂-BODIPY及较重的第13族螯合物的合成探索翻译改进

Aiden M Lane¹, Ny T C Luong¹, Jordan C Kelly², Martin J Neal², Jeremiah Jamrom², Aaron J Bloomfield², Paul A Lummis², Thomas D Montgomery², Daniel T Chase¹

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作者单位

¹ Department of Chemistry and Biochemistry, St. Mary's College of Maryland, St. Mary's City, MD 20686, USA.

² Department of Chemistry and Biochemistry, Duquesne University, Pittsburg, PA 15282, USA.

DOI: 10.3390/molecules27238256 PMID: 36500349

摘要 Ai翻译

A series of boron, aluminum, gallium, and indium chelates containing the underexplored bis(phenolate) aza-dipyrromethene (aza-DIPY) core were prepared. These compounds were found to possess near-infrared absorption and emission profiles in the 710 to 770 nm domain and exhibit quantum yield values up to 14%. X-ray diffraction analysis revealed that heavier group 13 bis(phenolate) aza-DIPY chelates possessed octahedral geometries with either THF or pyridine groups occupying the axial positions as opposed to the tetrahedral geometry of the boron chelate.

Keywords: aza-ALDIPY; aza-BODIPY; aza-DIPY; aza-GADIPY; aza-INDIPY.

Keywords：Group 13 Chelates

关键词：双酚盐Aza-BODIPYs; 第13族螯合物