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Chemistry (Weinheim an der Bergstrasse, Germany). 2015 Apr 7;21(15):5732-5. doi: 10.1002/chem.201500078 Q23.72025

From spherical to leaf-like morphologies: tunable supramolecular assembly of alkynylgold(I) complexes through variations of the alkyl chain length

从球形到叶片状结构:通过调节烷基链长度调控乙炔金(i)配合物超分子组装体的可变性研究 翻译改进

Eugene Yau-Hin Hong  1, Hok-Lai Wong, Vivian Wing-Wah Yam

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作者单位

  • 1 Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grant Committee (Hong Kong)) and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (P. R. China).
  • DOI: 10.1002/chem.201500078 PMID: 25707360

    摘要 Ai翻译

    A series of luminescent polynuclear alkynylgold(I) complexes with different lengths of alkyl chains attached at the N-heterocyclic carbene moieties has been synthesised and demonstrated to display intriguing self-assembly behaviours through a cooperative growth mechanism. Variation of the alkyl chain length was found to cause drastic morphological differences in the aggregates and to strongly affect the thermodynamic parameters as revealed by the nucleatio... ...点击完成人机验证后继续浏览
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    期刊名:Chemistry-a european journal

    缩写:CHEM-EUR J

    ISSN:0947-6539

    e-ISSN:1521-3765

    IF/分区:3.7/Q2

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    From spherical to leaf-like morphologies: tunable supramolecular assembly of alkynylgold(I) complexes through variations of the alkyl chain length