Rhodium(III)-catalyzed arylation of arenes bearing a chelating group has been realized via a redox-economy process using 4-hydroxycyclohexa-2,5-dienones as the arylating reagents, leading to the synthesis of 3-arylated phenols. This redox-neutral process proceeds via a C-H activation pathway with rearomatization being the driving force.
Organic letters. 2014 Mar 21;16(6):1586-9. doi: 10.1021/ol500186j Q15.02025
Rhodium(III)-catalyzed redox-neutral C-H arylation via rearomatization
通过重新芳构化不涉及氧化还原的 Rh(III) 催化的C-H芳基化反应 翻译改进
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DOI: 10.1021/ol500186j PMID: 24588394
摘要 Ai翻译
Keywords：C-H arylation
关键词：C-H芳基化
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